期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 7, 页码 1197-1206出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201201104
关键词
Platinum; P ligands; HF reactions; Structure elucidation
资金
- graduate school Fluorine as a Key Element
- Deutsche Forschungsgemeinschaft
[(CO)(2)Pt(CH3)(2)], [(PF3)(2)Pt(CH3)(2)], and [(CF3)(2)PC2H4P(CH3)(2)-Pt(CH3)(2)] [dfmpe = (CF3)(2)PC2H4P(CF3)(2)] are obtained by ligand exchange reactions. The thermal stability of the complexes increases in the given sequence, whereas their volatility decreases. Demethylation reactions with anhydrous HF cleave one methyl group. The addition of AsF5 and SbF5 often cleaves both methyl groups. The resulting L2Pt2+ compounds are obtained in crystalline form with the corresponding [A(5)F(6)](-), [SbF6](-), [Sb2F11](-), and [B12F12](2-) anions. Bridged dimeric or trimeric platinum complexes are also formed.
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