期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 21, 页码 3155-3164出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201100379
关键词
ATRA reactions; Homogeneous catalysis; Transition metals; Radicals; Olefins
资金
- Ministerio de Ciencia e Innovacion [CTQ2008-00042BQU, CTQ2008-06866-CO2-02/BQU]
- Consolider Ingenio 2010 [CSD2006-0003]
- Junta de Andalucia [P07-FQM-02794]
Transition-metal-catalyzed atom transfer radical reactions of halogenated compounds with olefins constitute a versatile tool in organic synthesis within the area of C-C bond forming transformations. The inter-or intramolecular versions, atom transfer radical addition (ATRA) or cyclization (ATRC), respectively, lead to the atom-economic, useful synthesis of compounds that can be further functionalized. This contribution summarizes the recent developments in this area in terms of catalyst design as well as the applicability of this methodology in sequential, domino, or tandem reactions.
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