期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 3, 页码 485-489出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201100780
关键词
Electronic effects; Cobalt; C-H arylation; Rate-determining step; Ligand effects; Steric hindrance
资金
- Grants Council of Hong Kong [400308]
- Special Equipment Grant (SEG) of the People's Republic of China [CUHK09]
- National Science Council [NSC-100-2113-M002-001-MY3]
The electronic effects of the porphyrin ligand on the cobalt(II)-porphyrin-catalyzed direct C-H arylation of benzene with 4-iodotoluene were explored. The investigation was facilitated by the easy preparation of various substituted porphyrin ligands. The reaction rates were found to be dependent on the electron richness of the cobalt(II)-porphyrins. Such effects are consistent with the electronic influences on the rate-determining aryl iodide bond cleavage.
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