期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 14, 页码 2084-2087出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200900668
关键词
Nanostructures; Cluster compounds; Silver; Halides
资金
- National Natural Science Foundation of China [20871100, 20721001, 20925103]
- Natural Science Foundation of Fujian [2009J06005]
- Key Scientific Project of Fujian Province [2009HZ0002-1]
Owing to its good affinity with Ag+, Br- is able to truncate a silver thiolate polymer and induce the formation of a high-nuclearity silver thiolate nanocluster, [Br@Ag-36(SC(6)H(4)tBu-4)(36)](-) The nanocluster has a disc-like structure with one Br- anion trapped at the center of the cluster in an octahedral coordination.
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