期刊
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
卷 22, 期 2, 页码 833-845出版社
SPRINGER HEIDELBERG
DOI: 10.1007/s11356-014-2767-1
关键词
Textile dyeing wastewater; Solar advanced oxidation processes; Solar photo-Fenton; SUNTEST simulator; Pilot plant with CPCs
资金
- FEDER through COMPETE - Programa Operacional Factores de Competitividade [PEst-C/EQB/LA0020/2013, NORTE-07-0162-FEDER-000050]
- FCT [SFRH/BD/73510/2010]
- QREN
- ON2
- FCT Investigator Programme [IF/01501/2013]
- CAPES [BEX 9794-11-5, 5512-10-7]
- CNPq
- CAPES
- Fundação para a Ciência e a Tecnologia [SFRH/BD/73510/2010] Funding Source: FCT
The performance of different solar-driven advanced oxidation processes (AOPs), such as TiO2/UV, TiO2/H2O2/UV, and Fe2+/H2O2/UV-visible in the treatment of a real textile effluent using a pilot plant with compound parabolic collectors (CPCs), was investigated. The influence of the main photo-Fenton reaction variables such as iron concentration (20-100 mg Fe2+ L-1), pH (2.4-4.5), temperature (10-50 degrees C), and irradiance (22-68 W-UV m(-2)) was evaluated in a lab-scale prototype using artificial solar radiation. The real textile wastewater presented a beige color, with a maximum absorbance peak at 641 nm, alkaline pH (8.1), moderate organic content (dissolved organic carbon (DOC)=129 mg C L-1 and chemical oxygen demand (COD) = 496 mg O-2 L-1), and high conductivity mainly associated to the high concentration of chloride (1.1 g Cl- L-1), sulfate (0.4 g SO42 -L-1), and sodium (1.2 g Na+L-1) ions. Although all the processes tested contributed to complete decolorization and effective mineralization, the most efficient process was the solar photo-Fenton with an optimum catalyst concentration of 60 mg Fe2+ L-1, leading to 70% mineralization (DOCfinal = 41 mg C L-1; CODfinal < 150 mg O-2 L-1) at pH 3.6, requiring a UV energy dose of 3.5 kJ(UV)L(-1) (t(30 W) = 22.4 min; <(T)over bar> = 30 degrees C (U) over bar (G,n) = 44 W m(-2)) consuming 18.5 mM of H2O2.
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