4.8 Article

Methanol from CO2 by Organo-Cocatalysis: CO2 Capture and Hydrogenation in One Process Step

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ENVIRONMENTAL SCIENCE & TECHNOLOGY
卷 48, 期 24, 页码 14799-14804

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AMER CHEMICAL SOC
DOI: 10.1021/es503914d

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Carbon dioxide chemically bound to alcohol-amines was hydrogenated to methanol under retrieval of these industrially used CO2 capturing reagents. The energetics of the process can be seen as a partial cancellation of the exothermic heat of reaction of the hydrogenation with the endothermic one of the CO2 release from the capturing reagent. The process provides a means to significantly improve the energy efficiency of CO2 to methanol conversions.

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