Article
Chemistry, Physical
Fen Zhang, Luyao Xi, Meiqi Zhao, Yaguang Du, Liying Ma, Shaohua Chen, Hengpeng Ye, Dongyun Du, Tian C. Zhang
Summary: In this study, a novel composite of PPy/NP was synthesized and applied for the efficient removal of hexavalent chromium from aqueous solutions. The results showed that the PPy/NP composites exhibited better Cr(VI) removal performance than PPy alone, and could be used as recyclable absorbents for multiple cycles.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Environmental Sciences
Ruiming Zhang, Rossana Napolano, Beidou Xi, Anne Millicent Salazar, Qiantao Shi, Ying Zhao, Xiaoguang Meng
Summary: Recent studies have found that the combination of zero-valent iron (ZVI) and pyrite (FeS2) can effectively remove Cr(VI) from water. This study discovered that dissolved oxygen (DO) plays a crucial role in enhancing the removal efficiency. The presence of DO led to the oxidation of pyrite, producing protons that promote ZVI corrosion and creating dissolved sulfide, which improves the removal of Cr(VI) by forming ferrous sulfide precipitates on the ZVI surface.
Article
Engineering, Environmental
Xin Nie, Guiying Li, Yun Wang, Yingmei Luo, Lei Song, Shuguang Yang, Quan Wan
Summary: Pyrite nanomaterials are effective in remediation of Cr(VI) contaminated wastewater, with hexapod-like pyrite nanosheet clusters showing higher removal efficiency than microspherulites. The enhanced removal rate of Cr(VI) is attributed to the increased dissolution of Fe(II) and S(-II) into the suspension. Additionally, the stability and longevity of hexapod-like pyrite nanosheet clusters make them promising for remediation of Cr(VI) contaminated environments.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Engineering, Chemical
Yang Li, Tao Huang, Xiaolu Liu, Zhongshan Chen, Hui Yang, Xiangke Wang
Summary: With the rapid development of industry, large amounts of wastewater containing metal ions are generated and released into natural ecosystems. Removing heavy metal ions from these ecosystems efficiently is a major challenge. This review summarizes and discusses the sorption-catalytic reduction-immobilization of U(VI) and Cr(VI) by porous frameworks materials such as MOFs, COFs, and g-C3N4. The interaction mechanisms were studied through macroscopic batch sorption/column experiments, microscopic spectroscopy characterization, and molecular-level computational simulation. The porous frameworks materials with tunable pore sizes, active sites, and functional groups have high sorption capacity for U(VI) and Cr(VI), and can immobilize or extract them from complex systems. Doping/co-doping with metals/nonmetals and incorporating other nanomaterials/metal oxides can enhance catalytic activity. The challenges for real applications are also discussed in this review.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Review
Engineering, Environmental
Yin Ye, Jian Jin, Fan Chen, Dionysios D. Dionysiou, Yanyue Feng, Bin Liang, Hao-Yi Cheng, Zemin Qin, Xin Tang, Hongwan Li, Doekle Yntema, Cui Li, Yanlong Chen, Yuheng Wang
Summary: With the expansion of nuclear power technology, uranium contamination of the aquatic environment has become a growing environmental issue. Photocatalytic reduction of hexavalent uranium (U(VI)) has emerged as a potential solution for this problem, sparking increased research interest. Future research efforts should focus on advancements in photocatalytic U(VI) removal technology and addressing key knowledge gaps in the field.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Environmental
Jingchun Tang, Beibei Zhao, Honghong Lyu, Ding Li
Summary: The FeS2@BC composite synthesized by ball milling technology showed enhanced removal capacity for Cr(VI), mainly through reduction, adsorption, and surface complexation mechanisms.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Environmental Sciences
Muqing Qiu, Zhixin Liu, Shuqin Wang, Baowei Hu
Summary: The study demonstrated that the ZIF-8/g-C3N4 photocatalyst showed high efficiency in the photoreduction of U(VI) and maintained stability under different water chemistry conditions. The role of H2O2 radicals and photo-generated electrons in U(VI) photoreduction was highlighted through quenching experiments.
ENVIRONMENTAL RESEARCH
(2021)
Review
Environmental Sciences
Wenbo You, Wanting Peng, Zhichao Tian, Maosheng Zheng
Summary: This review systematically summarizes the remediation of U(VI) contamination using microbial reduction, including mechanisms and influencing factors. In situ remediation is shown to be more effective for large-scale degradation of uranium contaminants, but reduction products can be reoxidized when exposed to oxygen and nitrate, compromising the remediation effects.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)
Article
Materials Science, Ceramics
Yubing Sun, Xinshui Huang, Yanxue Yue, Weiyu Zhu, Bo Zhang, Rongbo Hou, Ahadi Ishag
Summary: The effect of Cr(VI) and TC on the photocatalytic reduction of U(VI) by MoS2/g-C3N4 was investigated. The presence of TC and Cr(VI) improved the photoreduction of U(VI), while their own photocatalytic removal was not significantly influenced. The re-oxidation of U(VI) into U(VI) was observed under increasing irradiation.
CERAMICS INTERNATIONAL
(2023)
Article
Engineering, Environmental
Xiaomei Zhang, Nina Yan, Min Wang, Xizhi Jiang, Rui Xu, Min Feng, Lei Xu, Shaochun Tang
Summary: In this study, a novel Cu2O@ZIF-8 particle was designed and synthesized using a fast microwave-assisted scalable synthesis method. The Cu2O@ZIF-8 particles exhibited high efficiency in reducing U(VI) ions to U(IV) and separating them from aqueous solutions for the treatment of radioactive wastewater. The particles with octahedral Cu2O crystals showed the best performance among different facet shapes. The optimized octahedral Cu2O@ZIF-8 particles demonstrated remarkable adsorption capability, reaching 330.87 mg/g, which is much higher than previously reported values for other adsorption materials. The mechanism of adsorption was investigated, and the adsorption behavior followed Freundlich isotherm and pseudo-second-order kinetic models. This work provides a new approach to improve U(VI) adsorption capability for highly efficient treatment of radioactive wastewater.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
E. Zuniga-Puelles, R. Cardoso-Gil, M. Bobnar, I Veremchuk, G. Heide, R. Gumeniuk
Summary: The analysis of natural pyrite crystals from the Erzgebirge region in Germany revealed that arsenic doping leads to smaller semiconductor energy gaps and a switch in conduction type mechanism from n-type to p-type. The electrical resistivity and Seebeck coefficient measurements of synthetic FeAsxS2-x solid solutions supported these findings. Additionally, the study showed that impurities of insulating metal oxides in sintered FeS2 + MO2 composites have less influence on the electrical transport properties of pyrite.
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
(2021)
Article
Engineering, Environmental
Siyi Wang, Lin Wang, Zijie Li, Pengcheng Zhang, Ke Du, Liyong Yuan, Shunyan Ning, Yuezhou Wei, Weiqun Shi
Summary: In this study, a novel composite material nZVI/Alk-Ti3C2Tx was developed for the simultaneous adsorption and reduction of U(VI) in anoxic conditions, showing efficient removal efficiency and high uptake capacity. The composites exhibited high U(VI) removal rates in different environmental media. The study also clarified the different pathways for U(VI) elimination based on the reaction mechanisms between U(VI) and nZVI/Alk-Ti3C2Tx.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Engineering, Environmental
Limin Zhang, Hailiang Dong, Runjie Li, Dong Liu, Liang Bian, Yu Chen, Zezhen Pan, Maxim I. Boyanov, Kenneth M. Kemner, Jianguo Wen, Qingyin Xia, Hongyu Chen, Edward J. O'Loughlin, Guanyu Wang, Ying Huang
Summary: Previous studies focused on bioreduction of uranium (VI) as a remediation method, but uranium (IV) can be reoxidized and remobilized. In this study, a combination of adsorption and bioreduction of U (VI) in the presence of an organic ligand and a Fe-rich clay mineral was found to partially solve this problem. The results provide novel insights into the mechanisms of U(VI) bioreduction and the stability of U.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2022)
Article
Engineering, Environmental
Fenglei Liu, Shanshan Wang, Baowei Hu
Summary: MXenes-decorated nanoscale FeS composites were prepared via electrostatic self-assembly strategy for efficient U(VI)/Cr(VI) adsorption-reduction. Different analytical techniques characterized the materials and confirmed the desired morphology and properties. MXenes improved the dispersion of FeS nano-particles and suppressed aggregation. The adsorption data followed the Langmuir isotherm and Pseudo-second-order equation, with maximum removal efficiencies of 88.5 and 107.2 mg/g for uranium(VI) and chromium(VI). The presence of other cations and anions had no significant influence on U(VI)/Cr(VI) removal, and the elimination process was spontaneous and endothermic. The work demonstrated the potential of MXenes-based materials for wastewater decontamination.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Chemical
S. Ramakrishna Reddy, S. V. N. Ayyappa, Satyabrata Mishra, T. Sreepriya, N. Desigan, K. A. Venkatesan, N. Sivaraman, K. Ananthasivan
Summary: The kinetics of catalytic reduction of U(VI) by H2 over Pt/SiO2 was investigated by studying various parameters including agitation speed, particle size, catalyst loading, concentration of U(VI), HNO3, N2H4, H2 pressure, and temperature. The Langmuir-Hinshelwood-Hougen-Watson (LHHW) approach was utilized to derive the kinetic model equations and understand the reaction mechanism. Among the various models, model-IX, which corresponds to the adsorption of nitric acid on the catalyst surface, was found to be suitable for explaining the concentration profiles of U(VI) and HNO3. The activation energy of the reaction was determined to be around 22.6 kJ mol-1, indicating a chemical and diffusion controlled regime for the reduction of U(VI) with H2.
CHEMICAL ENGINEERING RESEARCH & DESIGN
(2023)
Article
Construction & Building Technology
Zhenguo Shi, Bin Ma, Barbara Lothenbach
Summary: Aluminum plays a role in the formation and structure of ASR products, with concentrations lower than 0.1 mM not preventing or altering the structure of ASR products formed at 40 degrees C. However, the formation of crystalline ASR products at 80 degrees C is reduced at higher aluminum content due to the formation of a zeolitic precursor.
CEMENT AND CONCRETE RESEARCH
(2021)
Article
Construction & Building Technology
Bin Ma, Alejandro Fernandez-Martinez, Andrea Mancini, Barbara Lothenbach
Summary: The study found that introducing Fe3+ ions or iron oxide during zeolite nucleation does not result in Fe-III incorporation into the zeolites, but different forms of Fe-III can affect the type of zeolite formed. Introducing Fe-III into the cage of faujasite-Y, followed by a phase transformation to chabazite, provides a feasible pathway for incorporating tetrahedral Fe-III into the zeolite framework.
CEMENT AND CONCRETE RESEARCH
(2021)
Review
Engineering, Environmental
Yuying Zhang, Lei Wang, Liang Chen, Bin Ma, Yike Zhang, Wen Ni, Daniel C. W. Tsang
Summary: Municipal solid waste incineration (MSWI) fly ash is considered hazardous waste that requires specific treatment. In recent years, there has been interest in developing low carbon and sustainable treatment technologies for MSWI fly ash to maximize benefits. This review highlights innovative technologies, resource utilization approaches, and future perspectives for MSWI fly ash management.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Construction & Building Technology
Bin Ma, Barbara Lothenbach
Summary: The study focused on the thermodynamic properties of potassium-rich zeolites in cementitious systems, including stability and predominance diagrams. Analysis of experimental data on 14 types of K-based zeolites revealed their typically low solubility between 0 and 100 degrees Celsius.
CEMENT AND CONCRETE RESEARCH
(2021)
Article
Environmental Sciences
Hanyu Wu, Jie Chen, Zengbo Su, Bin Ma, Yizhe Ji, Shuhan Lin, Dingfang Xu, Mingliang Kang
Summary: Eu(III) adsorption on muscovite and phlogopite was investigated under different conditions, showing pH dependency and Na+ independent for both micas, with interlayer sites only available on phlogopite under Na+ and Ca2+ electrolytes. Adsorption of Eu(III) on phlogopite led to interlayer expansion, and the addition of fulvic acid affected both the adsorption behavior of Eu(III) and the structural alteration of phlogopite.
Article
Biochemistry & Molecular Biology
Laurene Sonzogni, Melanie L. Ferlazzo, Adeline Granzotto, Beatrice Fervers, Laurent Charlet, Nicolas Foray
Summary: The mechanistic model RIANS from radiobiology is crucial for understanding the recognition, repair and genotoxic stress response of DNA double-strand breaks induced by radiation. This model also applies to exposure to metal ions. Our study found that the induction of DSB by pesticides depends on their concentration and the RIANS status of cells. Impaired DSB recognition and repair, leading to toxicity, can occur when the nucleo-shuttling of ATM is delayed. Additionally, the combination of certain metal ions and pesticides can have additive or supra-additive effects on DSB recognition and/or repair.
Article
Engineering, Environmental
Kaifeng Wang, Alejandro Fernandez Martinez, Laura Simonelli, Benoit Made, Pierre Henocq, Bin Ma, Laurent Charlet
Summary: In this study, the interaction process between selenite and mackinawite under hyperalkaline conditions was successfully monitored. The results showed that selenite was reduced to solid species, while mackinawite went through oxidation and released some sulfide into the solution. This study provides valuable data about the retardation mechanisms of redox-sensitive radionuclides by soluble iron sulfides, which is critical for advancing our understanding of reactive concrete barriers used in nuclear waste disposal systems.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2022)
Article
Engineering, Environmental
Yuying Zhang, Zhonghao Wan, Lei Wang, Binglin Guo, Bin Ma, Liang Chen, Daniel C. W. Tsang
Summary: The interaction between magnesium phosphate cement (MPC) and zinc oxide (ZnO) in the stabilization/solidification (S/S) process of Zn-rich electroplating sludge was investigated, revealing changes in precipitate chemistry and microstructure transition. The formation of amorphous Zn-3(PO4)(2)center dot 2H(2)O/Zn-3(PO4)(2)center dot 4H(2)O inhibited the formation of Mg-phosphate precipitates.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2022)
Article
Construction & Building Technology
Y. Yan, B. Ma, G. D. Miron, D. A. Kulik, K. Scrivener, B. Lothenbach
Summary: The effect of Al and pH on the structure of calcium silicate hydrate (C-S-H) was studied. The presence of Al led to changes in the secondary phases, interlayer distances, silicate chains, and concentrations of dissolved Al and Si. pH values also affected the structure, with different secondary phases dominating at low and high pH values.
CEMENT AND CONCRETE RESEARCH
(2022)
Review
Materials Science, Multidisciplinary
Laurent Charlet, Christophe Tournassat, Jean-Marc Greneche, Paul Wersin, Antoine Gehin, Jebril Hadi
Summary: Rates and mechanisms of important reactions in the cycling of electrons via the geochemical transformations of iron have been identified using Mossbauer spectrometry. The cycling of iron through various reservoirs depends on high surface-area-to-volume ratios of Fe-bearing solids. Fe-bearing solids surfaces can interact chemically with reductants and oxidants, facilitating electron transfer as well as dissolution and precipitation.
JOURNAL OF MATERIALS RESEARCH
(2023)
Article
Materials Science, Multidisciplinary
Sudipta Chakraborty, Dipanjan Banerjee, Andreas C. Scheinost, Jean-Marc Greneche, Fabienne Favre, Antoine Gehin, Laurent Charlet
Summary: The reactivity of Fe(II) sorbed on different types of clay towards U(VI) reduction was investigated. U(VI) reduction only occurred on Fe-free synthetic montmorillonite (MONT), and a hydrated uranyl silicate (soddyite)-like phase was formed. The lack of reactivity on Fe-poor natural montmorillonite (Fe-MONT) and Fe-rich natural nontronite (NAu-2) is likely due to inter-valence charge transfer (IVCT) between surface Fe(II) and structural Fe(III). This study highlights the dependence of clay sorbed Fe2+ reactivity on the nature of clay and the oxidation state of sorbed Fe.
JOURNAL OF MATERIALS RESEARCH
(2023)
Article
Environmental Sciences
Evgenia-Maria Papaslioti, Philippe Le Bouteiller, Hugo Carreira, Jean -Marc Greneche, Alejandro Fernandez-Martinez, Laurent Charlet
Summary: Magnetite can effectively remove contaminants from wastewater, especially arsenic, antimony, and uranium present in the acidic phospho-gypsum leachates derived from the phosphate fertilizer industry. However, the presence of phosphate limits the removal of antimony and arsenic by magnetite. Therefore, a three-step design involving oxidation, precipitation, and reaction with magnetite can achieve high contaminant uptake in field applications.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2023)
Review
Environmental Sciences
Yuying Zhang, Mingjing He, Lei Wang, Jianhua Yan, Bin Ma, Xiaohong Zhu, Yong Sik Ok, Viktor Mechtcherine, Daniel C. W. Tsang
Summary: Biochar is a waste-derived material that can be compatible with cement, asphalt, and polymer materials due to its porous nature and functionalized surface. This study critically reviewed the latest research on biochar-enhanced construction materials, discussing their effectiveness, mechanisms, and additional value in the construction industry.
Article
Chemistry, Physical
Vivien Ramothe, Laurent Charlet, Benjamin Gilbert, Pauline Simonnin, Michel Sassi, Kevin M. Rosso
Summary: Using density functional theory (DFT) calculations, the process of H2S sorption and reaction on Ag(100) surfaces relevant to Ag nanowires (AgNWs) was examined, revealing the mechanism of dissociative chemisorption and the influence of complex environmental media.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2022)