期刊
ENVIRONMENTAL SCIENCE & TECHNOLOGY
卷 42, 期 22, 页码 8419-8425出版社
AMER CHEMICAL SOC
DOI: 10.1021/es8008908
关键词
-
资金
- Norwegian Research Council [153444/S30]
Chemical methods to assess bioavailability in soil and sediment often use synthetic polymers that mimic uptake of organic compounds in organisms or microbial degradation. In this paper we have assessed a biomimetic extraction method using hydroxyl-beta-cyclodextrin (HP-beta-CD) to estimate uptake of the two insecticides alpha-cypermethrin (alpha-CYP) and chlorfen-vinphos (CFVP) in the earthworm Eisenia fetida. Additionally, a novel approach was developed to estimate the efficiency of biomimetic extractions. The study revealed that HP-beta-CD is a suitable surrogate for estimating the bioaccessibility of hydrophobic chemicals in soil. If one uses a 3.5 times higher amount of HP-beta-CD than soil, effective and reproducible extractions can be achieved within 48h. At these conditions, inclusion of dissolved chemicals by HP-beta-CD mimics uptake of a given compound into earthworms and takes into account sorption-related aspects that control biological uptake. The data indicate that, with increasing hydrophobicity, the affinity of organic chemicals to HP-beta-CD does not increase to the same degree as to soil organic matter. Therefore, a high surplus of HP-beta-CD is necessary to provide a sufficient extraction capacity in biomimetic extractions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据