期刊
ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY
卷 32, 期 3, 页码 564-568出版社
WILEY
DOI: 10.1002/ep.11658
关键词
absorption; kinetics; NO; KMnO4; (NH4)(2)CO3
类别
资金
- Scientific Problem Tackling Program of Science and Technology Commission of Shanghai Municipality [10dz1201401, 10dz1201402, 11dz2281700]
- Absorption and Innovation Program of Introduced Technology of Shanghai [Product-40- orientation-28]
- Innovation Program of Shanghai Municipal Education Commission [10YZ155]
- Choose and Cultivation of Excellent Young Teachers Program of Shanghai Municipal Education Commission [sdl09008]
The absorption process of NO into KMnO4/(NH4)(2)CO3 solutions was studied in a stirred tank reactor. The experimental results showed that the reaction process was a fast pseudo-m reaction. The reaction between NO and aqueous solutions of KMnO4/(NH4)(2)CO3 was found to be first-order with respect to NO and with respect to KMnO4. The frequency factor and the average activation energy of this reaction were 2.3 x 10(9) m(3)/(mol s) and 36.77 kJ/mol, respectively. (c) 2012 American Institute of Chemical Engineers Environ Prog, 32: 564-568, 2013
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