Article
Engineering, Environmental
Wanpeng Chen, Jiaming Xiong, Juchao Liu, Hainan Wang, Jinni Yao, Hongxia Liu, Xiaoliu Huangfu, Qiang He, Jun Ma, Caihong Liu, Yao Chen
Summary: The transformations of monovalent thallium (Tl) in an aqueous environment are significantly affected by Tl(I) partitioning at the solid-water interface during sorption. Two unified adsorption models, diffuse layer modeling and kinetics modeling, accurately predict the environmental fate of thallium by quantifying the kinetics of Tl (I) adsorption on heterogeneous adsorbents and the formation of multiple complexes under a wide range of water chemistry conditions. The characteristics of different Tl(I) complexes have influence on the adsorption and desorption processes.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Chemistry, Physical
Sunwook Kim, Sungmin Na, Joonchul Kim, Tae Hwan Jun, Myoung Hwan Oh, Kyoungmin Min, Kwangjin Park
Summary: This study focuses on finding a coating material to replace cobalt in order to address the issues of Ni-rich cathode materials. The Ni/Hf coated sample shows higher initial capacity, improved rate capability, higher Li-ion diffusion coefficient, reduced charge-transfer resistance, enhanced cycle retention, and the ability to suppress side reactions and large volume change compared to other coatings and the pristine sample.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Materials Science, Multidisciplinary
Liang He, Jimmy Wu, Derwin Lau, Charles Hall, Yu Jiang, Bharat Thapa, Yijun Gao, Tracey Yeung, Alexander Wotton, Alison Lennon, Neeraj Sharma, Robert J. Patterson
Summary: Amorphous materials, such as MnO2-x doped with Ag and Cu, show improved cyclability as electrodes in Li-ion batteries, with the Ag0.004Cu0.002MnO2-x nanomaterial composition demonstrating the best performance after 100 charge-discharge cycles. This work contributes to the development of high capacity Li-ion battery electrodes with excellent cyclability and low series impedance.
Article
Chemistry, Physical
Sadjad Sabzalian, Mansour Soltanieh, Saeed Rastegari
Summary: Buckling damage and spallation are significant challenges in electroplated Cu-Mn oxide spinel coatings used for SOFC interconnects. The formation mechanism of (Cu,Mn)3O4 spinel coating on AISI-430 stainless steel during oxidation at 750 degrees C has been investigated. It was found that nickel strike deposition can effectively reduce coating spallation. The spinel coating inhibits chromium migration and improves the oxidation behavior of the alloy. The oxidation process involves the initial formation of MnO, Mn2O3, and Mn3O4, followed by the oxidation of copper to CuO and the replacement of MnO and Mn3O4 by Mn2O3. (c) 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Engineering, Environmental
Zhijing Wu, Xiangping Li, Huosheng Li, Gaosheng Zhang
Summary: Phosphorus is essential for biological growth, but its excessive presence can lead to eutrophication. The novel zero-valent manganese sorbent Mn-0@Mn2O3 shows exceptional phosphate removal performance, making it promising for phosphate removal from real municipal wastewater.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Multidisciplinary Sciences
Adewumi O. Dada, Folahan A. Adekola, Ezekiel O. Odebunmi, Adeniyi S. Ogunlaja, Olugbenga S. Bello
Summary: This study investigated the adsorption of problematic copper ions from aqueous solution onto nanoscale zerovalent iron (nZVI). Results showed that nZVI exhibited high efficiency in removing heavy metals from synthetic wastewater. The study also revealed the kinetics and thermodynamic characteristics of the adsorption process.
SCIENTIFIC REPORTS
(2021)
Article
Chemistry, Physical
V Jayakumar, S. Govindaradjane, M. Rajasimman
Summary: The sorption efficiency of marine green macro algae Caulerpa scalpelliformis for heavy metal zinc from aqueous and industrial wastewater was explored in this study. The characteristics of the sorbent prepared, optimum operating conditions, and equilibrium studies were investigated. Results showed that the sorption mechanism followed pseudo-second order kinetics, with the Langmuir isotherm model fitting the data well and showing a maximum uptake of 83.3 mg/g of zinc. Overall, the sorption of zinc on green biomass was found to be feasible, spontaneous, and endothermic.
SURFACES AND INTERFACES
(2021)
Article
Materials Science, Ceramics
Ban K. Mohammed, Mustafa K. A. Mohammed, Duha S. Ahmed
Summary: This paper investigates the structural, optical, and electrical properties of undoped and copper-incorporated nickel oxide films. The Cu-doped NiO films exhibit smooth, hole-free, crack-free, and homogeneous surfaces. These films show high optical transparency and potential application as window layers in solar cells.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
(2021)
Article
Materials Science, Ceramics
Hamed Abdeyazdan, Maksym Shevchenko, Evgueni Jak
Summary: An integrated experimental and thermodynamic modeling investigation was conducted to characterize the phase equilibria in the PbO-NiO-SiO2 system, providing new experimental data and developing a thermodynamic database for a better understanding of the chemical reactions in Ni-containing Pb processing slags.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2023)
Article
Engineering, Environmental
Saima Farooq, Alhajaj Hamood Al Maani, Zakira Naureen, Javid Hussain, Asma Siddiqa, Ahmed Al Harrasi
Summary: This study investigated the adsorption of methylene blue from aqueous solution by activated carbon-loaded copper oxide nanocomposites (CuO@AC). The CuO@AC nanocomposites were prepared using an environmentally-friendly and green synthesis approach, and characterized by various techniques. The results showed that CuO@AC achieved over 97% methylene blue removal within 15 minutes. The findings suggest that CuO@AC can be utilized as an excellent adsorbent for wastewater treatment.
JOURNAL OF WATER PROCESS ENGINEERING
(2022)
Article
Materials Science, Multidisciplinary
Artur S. C. Rego, Rogerio C. S. Navarro, Eduardo A. Brocchi, Rodrigo F. M. Souza
Summary: The thermal decomposition of zinc sulfate is an important process that produces zinc oxide, which has various applications. This study presents a modeling approach using particle swarm optimization to estimate kinetic parameters. The results show that the decomposition occurs in two stages and the model fits well with experimental data.
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE
(2022)
Article
Biochemistry & Molecular Biology
Umme Kalsoom, Zainab Ahsan, Haq Nawaz Bhatti, Faiza Amin, Raziya Nadeem, Kiran Aftab, Muhammad Bilal
Summary: Manganese peroxidase (MnP) has the ability to oxidize and detoxify a wide range of recalcitrant xenobiotics, including synthetic dyes. In this study, MnP was successfully isolated from Aspergillus flavus and immobilized on iron oxide nanoparticles, leading to improved catalytic performance. The immobilized MnP showed good degradation efficiency towards textile dye pollutants.
PROCESS BIOCHEMISTRY
(2022)
Article
Engineering, Chemical
Badr M. Thamer, Faiz A. Al-aizari, Meera Moydeen Abdul Hameed
Summary: In this study, a novel composite material ZVNiNiO@Gr was successfully fabricated by a single-step method and used for the removal of crystal violet dye (CV) from contaminated water. The unique structure of the composite, with two-dimensional core-shell nanosheets supported on graphene layers, limited the agglomeration effect and enhanced the adsorption sites. The adsorption capacity of the composite was found to increase with temperature and exhibited better performance in alkaline media. The adsorption data was well fitted by the Freundlich isotherm model and pseudo-second-order kinetic model. Thermodynamic analysis indicated that the adsorption process was spontaneous, endothermic, and physical. The research shows promising potential for the treatment of wastewater from the textile industry.
CHEMICAL ENGINEERING RESEARCH & DESIGN
(2023)
Article
Environmental Sciences
Yusuf Azmi Akbas, Sabriye Yusan, Senol Sert, Sule Aytas
Summary: In this study, magnetite and magnetic olive pomace nanocomposite were prepared by a partial reduction co-precipitation method for the removal of Ce3+ ions from aqueous solution. Various parameters affecting sorption efficiency were investigated, showing high sorption capacities for Ce(III) ions. These materials were found to be effective and sustainable adsorbents for cerium ion removal.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Chemistry, Physical
Poshan Kumar Reddy Kuppam, K. M. M. D. K. Kimbulapitiya, Srikanth Vuppala, Kuangye Wang, G. Phaneendra Reddy, Krishna P. Pande, Po-Tsung Lee, Yun-Lun Chueh
Summary: Replacing precious metals with low-cost metals is the best solution for large scale production. In this study, a simple method of depositing nickel-molybdenum oxide and nickel on copper substrates was used to reduce corrosion and improve performance. The alloying of copper with nickel shows great potential as a hydrogen evolution reaction (HER) catalyst.