4.7 Article

Adsorption of vanadate(V) on Fe(III)/Cr(III) hydroxide waste

期刊

ENVIRONMENTAL CHEMISTRY LETTERS
卷 8, 期 4, 页码 363-371

出版社

SPRINGER HEIDELBERG
DOI: 10.1007/s10311-009-0234-x

关键词

Vanadate; Adsorption; Kinetics; Isotherms; Temperature

资金

  1. DAAD, Germany

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Adsorption of vanadate(V) from aqueous solution onto industrial solid 'waste' Fe(III)/Cr(III) hydroxide was investigated. HCl treated Fe(III)/Cr(III) hydroxide was found to be more efficient for the removal of vanadate(V) compared to untreated adsorbent. The adsorption follows second-order kinetics. Langmuir and Freundlich isotherms have been studied. The Langmuir adsorption capacity (Q (0)) of the treated and untreated adsorbents was found to be 11.43 and 4.67 mg g(-1), respectively. Thermodynamic parameters showed that the adsorption process was spontaneous and endothermic in the temperature range 32-60A degrees C. Maximum adsorption was found at system pH 4.0. The adsorption mechanism was predominantly ion exchange. Effect of other anions such as phosphate, selenite, molybdate, nitrate, chloride, and sulfate on adsorption of vanadium has been examined.

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