Article
Chemistry, Applied
Jun Feng, Sumin Gu, Rong Zhang, Xuan Qu, Jicheng Bi
Summary: The effect of steam in crude gas on Co-Ca bimetal catalyzed coal hydrogasification was investigated using H2 and steam mixtures. The presence of steam significantly inhibited Co-Ca activity toward hydrogasification. This study provides insights for developing an inexpensive and effective process for coal to clean fuels.
FUEL PROCESSING TECHNOLOGY
(2023)
Article
Computer Science, Interdisciplinary Applications
Oytun Oner, Ibrahim Dincer
Summary: In this study, a kinetic model is developed for steam plasma and two-dimensional microwave steam plasma is modeled for the first time using COMSOL Multiphysics software. The numerical study shows that at a microwave power of 800 W, the maximum electron density reaches 5 1017 m-3 at a time of 10-4s, and 16.8% of the water molecules dissociate to form various species. The conversion rate of water molecules to hydrogen is calculated as 24%. The proposed system's energy and exergy efficiencies are 10.31% and 10.14%, respectively, with a hydrogen production rate of 0.68 mu g/ s. The effect of the applied microwave power on plasma properties and hydrogen production is also studied.
COMPUTERS & CHEMICAL ENGINEERING
(2023)
Article
Energy & Fuels
Chen Liang, Xiaofang Wang, Qinggang Lyu
Summary: Using oxygen and steam as gasifying agent in a Circulating Fluidized Bed (CFB) preheater can enhance the gasification reactivity of coal; replacing air by O-2-steam in the gasifying agent and controlling the modification temperature and steam to coal ratio can improve the gasification reactivity of modified char; the gasification reactivity of modified char increases and then decreases with the highest value at a steam to coal ratio of 0.87.
Article
Thermodynamics
Katarzyna Spiewak, Piotr Soprych, Grzegorz Czerski
Summary: Dry deshaling is a modern technique that enhances coal quality by removing impurities and improving its heat value. This process is considered more environmentally friendly and cost-effective than traditional washing methods. The study showed that dry deshaling positively affects the gasification process by improving the formation rates and yields of key gases. However, the effect on calculated kinetic parameters remains unclear. Overall, the FGX technology shows potential in preparing coal for gasification, but further research is needed.
THERMOCHIMICA ACTA
(2022)
Article
Thermodynamics
Ying Wang, Shuai Tan, David A. Bell
Summary: The study investigated steam gasification kinetics in a modified drop tube fixed bed reactor, with a focus on temperature and pressure effects on surface chemical reactions. The random pore model closely matched experimental results, and mass transfer resistances were analyzed using the Thiele modulus based on particle sizes, temperature, total pressure, and steam partial pressure.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2021)
Article
Thermodynamics
Shirish Kumar Sharma, Anand M. Shivapuji, S. Dasappa
Summary: The high ash content of coal presents two challenges in conventional gasifiers: ash agglomeration and low-quality syngas. In this study, a novel two-stage gasification system is developed to address these challenges by strategically segregating oxidative pyrolysis and oxy-steam char gasification. This system allows for a wide range of ash content handling and provides explicit control over parameters like local temperatures.
APPLIED THERMAL ENGINEERING
(2024)
Article
Energy & Fuels
Wen-gang Huang, Zuo-tang Wang, Tian-hong Duan, Lin Xin
Summary: The pilot project integrating UCG with power generation in the abandoned mine Ankou aimed to optimize the gasification process, with industrial tests revealing that changes in oxygen concentration significantly affected syngas production. Increasing oxygen concentration led to higher H-2 content, combustible components, calorific value of syngas, and gasification efficiency after an initial drop. Additionally, oxygen-enriched gasification trials showed advantages in air consumption, coal consumption, and calorific value compared to oxygen-enriched steam gasification tests.
Article
Energy & Fuels
Candice Ellison, Victor Abdelsayed, Mark Smith, Dushyant Shekhawat
Summary: The effects of gasifier conditions on the gasification characteristics of different types of coal were evaluated, showing higher syngas yields and selectivity under microwave heating compared to conventional heating. Carbon conversion efficiency and cold gas efficiency were found to be highest for coals gasified under microwave irradiation, indicating a dependence of gasification reactivity on coal type.
Article
Thermodynamics
Deepak Kumar Singh, Jeewan Vachan Tirkey
Summary: The study aims to determine the optimal operating condition of dual fuel engines for improved performance and reduced emissions. Through response surface methodology, the optimal values of gasifier equivalence ratio, compression ratio, and engine load were optimized.
Article
Energy & Fuels
Chengdong Ying, Qinhui Wang, Yunjin Yang, Zhimin Huang, Yao Zhu, Jianmeng Cen
Summary: In this study, the effects of temperature, CaO absorbent, and atmosphere on sulfur transformation in coal steam gasification were investigated. It was found that an increase in temperature enhanced the formation of organic sulfur while reducing the amount of sulfur in the absorbent. CaO promoted sulfur conversion and acted as a sulfur absorbent and removal agent. The presence of CaO also decreased the release of H2S. In addition, the sulfur conversion was influenced by the atmosphere, with steam atmosphere leading to higher H2S-S but lower absorbent-S compared to inert atmosphere.
Article
Agricultural Engineering
Simon Vecten, Michael Wilkinson, Nuno Bimbo, Richard Dawson, Ben M. J. Herbert
Summary: The study effectively converted biomass into combustible gas using pure steam in a microwave-induced plasma reactor, achieving a carbon conversion efficiency of over 98% and producing syngas with high calorific value and rich hydrogen content.
BIORESOURCE TECHNOLOGY
(2021)
Article
Energy & Fuels
Fa-qiang Su, Tao Zhang, Jun-bo Wu, Qi-chao Deng, Akihiro Hamanaka, Yi-he Yu, Meng-jia Dai, Xiao-long He, Jun-nan Yang
Summary: In this paper, UCG simulation experiments were conducted to investigate the effects of the gasification agent ratio on the composition and calorific value of the product gas. An energy recovery evaluation method and an evaluation model of the underground coal gasification temperature field were established. The results showed that increasing the oxygen concentration improved the calorific value of the produced gas and the energy recovery rate.
Article
Energy & Fuels
M. Shahabuddin, Sankar Bhattacharya
Summary: The study investigated the gasification behavior of bituminous coal using different reactants at varying temperatures, finding that steam gasification achieved higher carbon conversion rates and lower heating values compared to CO2 gasification. Additionally, a mixture of CO2 and steam resulted in increased yields of H-2, CO and CH4 compared to pure CO2 gasification.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2021)
Article
Metallurgy & Metallurgical Engineering
Ya-jie Wang, Hai-bin Zuo, Jun Zhao, Guang-wei Wang
Summary: The study showed that the gasification reactivity of coal chars is influenced by coal rank and carbonaceous structure, with higher coal ranks leading to lower gasification reactivity and higher reaction orders.
JOURNAL OF IRON AND STEEL RESEARCH INTERNATIONAL
(2021)
Article
Thermodynamics
Maifan Dong, Lele Feng, Botao Qin
Summary: This study investigates the effect of microwave irradiation time on coal gasification and finds that microwave irradiation can enhance the gasification reaction rate of coal and affect its chemical composition, promoting the gasification reaction. However, when the microwave irradiation time exceeds a certain threshold, the reaction rate starts to decrease.