Article
Thermodynamics
Son Ich Ngo, Young-Il Lim, Doyeon Lee, Myung Won Seo, Sungwon Kim
Summary: This study investigated the hydrodynamics, reaction kinetics, and heat transfer of a bench-scale bubbling fluidized bed reactor for CO2 methanation. The study successfully identified the effects of hydrodynamics and reaction kinetics on heat transfer coefficient in the reactor.
ENERGY CONVERSION AND MANAGEMENT
(2021)
Article
Engineering, Environmental
Fardin Sattari, Maryam Tahmasebpoor, Jose Manuel Valverde, Carlos Ortiz, Mousa Mohammadpourfard
Summary: The manuscript presents a general model for a fluidized bed carbonator reactor based on bed hydrodynamics, kinetics, and sorbent properties in the Calcium Looping (CaL) process. The study identifies key operational and hydrodynamic factors affecting CO2 capture efficiency, and highlights important model parameters. The model predictions are in agreement with experimental results and may be relevant for optimizing CaL operation conditions in power plants.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Engineering, Environmental
Jiliang Ma, Jian Zhong, Xuebing Bao, Xiaoping Chen, Ye Wu, Tianyi Cai, Daoyin Liu, Cai Liang
Summary: A novel two-stage integrated bubbling-transport bed reactor was proposed for post-combustion CO2 capture using K2CO3/Al2O3 sorbents. The optimal adsorption temperature range was found to be between 60 degrees C and 100 degrees C, with wider range than traditional reactors. CO2 capture efficiency increased with sorbent circulation rate and desorption temperature, while better performance was observed with air desorption gas. Water vapor step-feeding enhanced maximum CO2 capture efficiency from 87% to 96% and showed strong anti-interference ability.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Engineering, Environmental
M. Mateen Shahid, Syed Zaheer Abbas, Fahad Maqbool, Sergio Ramirez-Solis, Valerie Dupont, Tariq Mahmud
Summary: The study investigated the impact of three different types of sorbents on sorption-enhanced steam methane reforming (SE-SMR) process and found the optimum operating conditions. CaO sorbent showed the best performance at 900K and 3 bar, with 82% CH4 conversion and 85% H-2 purity; LZC and HTC sorbents performed well at 773K and 5 bar.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Chemistry, Applied
Zhenghui Zhao, Kumar Patchigolla, Yinghai Wu, John Oakey, E. J. Anthony, Hongwei Chen
Summary: The study found that the SO2 absorption capacity of natural limestone after 20 cycles of CO2 capture was slightly lower than that of synthetic composite pellets. Abrasion was observed to be the main mode of attrition during the capture process, but some agglomeration was also found with increasing number of cycles, potentially posing a concern for the use of Ca-based sorbents in CO2 or SO2 fluidised bed capture.
FUEL PROCESSING TECHNOLOGY
(2021)
Article
Energy & Fuels
Faustyna Wieronska-Wisniewska, Dorota Makowska, Andrzej Strugala
Summary: This study analyzed the removal efficiency of gaseous forms of arsenic on selected Ca-based materials, including sorbents based on waste materials and traditionally used sorbents. It was found that calcined limestone, calcined dolomite, Fe2O3, Mg(OH)2, and Ca(OH)2 were the most effective sorbents. The study also showed that an increased Ca concentration in the sorbent may promote As-gas adsorption.
Article
Engineering, Environmental
Fumihiko Kosaka, Tomone Sasayama, Yanyong Liu, Shih-Yuan Chen, Takehisa Mochizuki, Koichi Matsuoka, Atsushi Urakawa, Koji Kuramoto
Summary: This study demonstrates a circulating fluidized bed (CFB) approach for continuous CO2 capture and reduction. Using dual function materials and steady-state cyclic operation, low-concentration CO2 can be directly converted into high-concentration CH4 or CO.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Chemical
Miriam Diaz, Monica Alonso, Gemma Grasa, Jose Ramon Fernandez
Summary: This study proposes a novel strategy for packed-bed Ca-Cu looping processes, which involves loading a sufficient amount of CuO to calcine only a specific fraction of CaCO3 during each cycle until the limestone reaches a residual conversion of 0.06. This strategy ensures temperatures below 900°C during operation, and the excess CaCO3 in the bed can adsorb CO2. The feasibility of this strategy is simulated for the conversion of blast furnace gas into a H2-rich product and a separated CO2 rich gas.
CHEMICAL ENGINEERING SCIENCE
(2023)
Article
Engineering, Environmental
Maite Michaud, Frederic Bornette, Eduard Rautu, Shahaji H. More, Miguel Leonardo Martinez Mendez, Loc Jierry, David Edouard
Summary: An elastic foam-bed reactor based on open-cell polymer foams was designed to enhance gas-liquid mass transfer of CO2 through compression/decompression cycles. The cycles, ensured by a crankshaft, require low additional electric power (<50 Watts) but significantly improve the mass transfer by one order of magnitude compared to fixed foam-bed reactor. Carbonic anhydrase-supported foam, using a supramolecular hydrogel for continuous applications, improves CO2 capture.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Energy & Fuels
Nassim Bouchoul, Houcine Touati, Elodie Fourre, Jean-Marc Clacens, Catherine Batiot-Dupeyrat
Summary: The study investigated the transformation of methane and carbon dioxide by coupling plasma and catalysis using a fluidized bed reactor. It was found that there is a correlation between the surface area of alumina and reactant conversion, with the highest surface area alumina achieving the best conversions in the plasma-fluidized bed. This indicates that an efficient coupling of plasma and catalysis can be achieved with solid particles moving in the gas flow.
Article
Energy & Fuels
Semie Kim, Young-Il Lim, Doyeon Lee, Myung Won Seo, Tae-Young Mun, Jae-Goo Lee
Summary: This study conducted 4E analyses on a 500-MWe oxy-coal ultra-supercritical circulating fluidized-bed (CFB) power plant with CO2 capture, exploring the effect of flue-gas recirculation (FGR) location on energy, exergy, environment, and economic values. Results showed that dry FGR was more advantageous than wet FGR, while the wdFGR plant demonstrated intermediate performance between the two.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2021)
Article
Engineering, Environmental
Helena Moreno, Francisco Pontiga, Jose M. Valverde
Summary: This paper investigates CO2 capture at room temperature and atmospheric pressure using a fluidized bed of Ca(OH)(2) powder, finding that an increase in relative humidity promotes CO2 capture, especially at near 100% RH. Quantitative analyses using X-ray powder diffractometry reveal that CaCO3 content in samples stored under high humidity originates from carbonation.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Engineering, Environmental
Youngsan Ju, Hyun-Taek Oh, Jae-Cheol Lee, Chang-Ha Lee
Summary: A multi-scale dynamic model was developed for a sorption-enhanced water-gas shift (SE-WGS) fluidized bed reactor, analyzing the reactor performance with K2CO3-promoted hydrotalcite sorbent under different operating conditions. The study demonstrated that increasing the sorption capacity and rate of the CO2 sorbent could enhance the CO conversion rate and carbon capture efficiency of the SE-WGS fluidized bed reactor at 30 bar pressure.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Engineering, Environmental
Shuoyang Liang, Aikelaimu Aihemaiti, Yingying Cai, Yiping Su, Rui Li, Zewei Quan, Zuotai Zhang
Summary: Developing calcium-based sorbents for capturing and separating CO2 from high-temperature flue gas is a potential route to alleviate environmental problems caused by excessive CO2 emissions. However, the anti-deactivation mechanism of stable CaO materials during the cyclic adsorption-desorption process is not well-understood, making it difficult to design Ca-based materials.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Green & Sustainable Science & Technology
Giuseppe Cristian Piso, Piero Bareschino, Paola Brachi, Claudio Tregambi, Giovanna Ruoppolo, Francesco Pepe, Erasmo Mancusi
Summary: In this study, the Chemical Looping Reforming of biogas was proposed and numerically investigated to achieve the clean, efficient, and cost-effective utilization of renewable carbonaceous fuels. The effects of biogas composition and process parameters on the reaction performances were assessed and discussed, including the conversion degree, syngas yield, and syngas composition.