期刊
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS
卷 48, 期 21, 页码 -出版社
IOP PUBLISHING LTD
DOI: 10.1088/0953-4075/48/21/214001
关键词
femtosecond; x-ray spectroscopy; wavepacket dynamics; x-ray free electron lasers; excited state dynamics
资金
- Swiss National Science Foundation [200021-137717]
- NCCR MUST
- Swiss National Science Foundation (SNF) [200021_137717] Funding Source: Swiss National Science Foundation (SNF)
The advent of x-ray free electron lasers is providing new opportunities for probing the ultrafast excited state dynamics using structurally sensitive techniques. Herein we use excited state wavepacket dynamics of a prototypical Cu(I)-phenanthroline complex, [Cu(dmp)(2)](+) (dmp = 2, 9-dimethyl-1, 10-phenanthroline) to investigate how femtosecond vibrational and electronic relaxation is translated into transient x-ray absorption and emission. Using realistic experimental parameters we also derive the anticipated signal strengths for these transient features. This indicates that although recording a signal capturing the strongest transient (i.e. excited state-ground state) changes will be possible for all cases, only with x-ray absorption near-edge structure and extended x-ray absorption fine structure will it be possible to resolve the fine details associated with the wavepacket dynamics within realistic experimental acquisition times.
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