期刊
ELECTROCHEMISTRY COMMUNICATIONS
卷 49, 期 -, 页码 65-69出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2014.09.018
关键词
1,2-Bis(bromomethyl)benzene; o-Quinodimethane; Cyclic voltammetry; Diels-Alder reactions; 1,4-Hydroquinone; Constant-current electrolysis
资金
- Bu-Ali Sina University, Hamedan, Iran [6517838683]
The electrochemical reduction of 1,2-bis(bromomethyl)benzene (2a) has been studied in the presence of 1,4-hydroquinone (1a) in an undivided cell in water/ethanol solution (40/60) by means of cyclic voltammetry (CV) and constant-current electrolysis. Through the paired green electro-synthesis, 1a and 2a are separately oxidized and reduced. The results revealed that the dienophile derived from the oxidation of 1a participates in two successive Diels-Alder reactions with cathodically generated o-quinodimethane (2b) to produce 5,5a,6a,7,12,12a,13a,14-octahydropentacene-6,13-dione (4b) as a final product with high yield, selectivity, purity and low waste. (C) 2014 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据