期刊
ELECTROCHEMISTRY COMMUNICATIONS
卷 12, 期 9, 页码 1170-1173出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2010.06.009
关键词
EE mechanisms; Fast kinetics; Simulation
资金
- CNRS [UMR 8640]
- Ecole Normale Superieure (ENS)
- Universite Pierre et Marie Curie (UPMC)
- French Ministry of Research
- Foreign Ministry of France
- Embassy of France in Ukraine
The main issue in classical simulations of electrochemical reactions concerns the correct description of concentration profiles when their gradients experience abrupt variations over a narrow space range (kinetic layers). Exponentially expanding grids are particularly useful under these conditions when the kinetic layers are adjacent to the electrode surface. Here we show that a new computing strategy can be devised to automatically adapt to this difficulty and solve this problem even when the kinetic layer position propagates within the solution at an a priori unknown speed as it does in EE mechanisms. (C) 2010 Elsevier B.V. All rights reserved.
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