期刊
ELECTROCHEMISTRY COMMUNICATIONS
卷 11, 期 4, 页码 921-924出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2009.02.029
关键词
TiO2 anode; Photoelectrocatalysis; MOCVD; Organic pollutants degradation; Deposition temperature
资金
- NSF of China [20306027, 20676121]
- NSF of Zhejiang Province [Y504129]
Nanosized TiO2/Ti photoanodes fabricated by metalorganic chemical vapor deposition (MOCVD) under different deposition temperatures were characterized and applied to the photoelectrocatalytic degradation of model pollutant of phenol. The anode prepared at 773 K was verified in anatase phase with a size about 60 nm and achieved the best photoelectrocatalytic activity, where IPCE could reach as high as 89% and the photoconversion efficiency peaked at 8.4%. The photoelectrocatalytic degradation of phenol was found well fit a pseudo-first-order kinetics, and kept stable performance in five continuous runs, confirming potential application of the electrode prepared by MOCVD for organic pollutants abatement. (C) 2009 Elsevier B.V. All rights reserved.
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