期刊
ELECTROCHEMISTRY
卷 79, 期 10, 页码 790-792出版社
ELECTROCHEMICAL SOC JAPAN
DOI: 10.5796/electrochemistry.79.790
关键词
Semiconductor Nanoparticles; Water Compatibility; ZnS-AgInS2 Solid Solution; Photoluminescence
资金
- Japan Society for the Promotion of Science [20245031]
- Ministry of Education, Culture, Sports, Science and Technology of Japan
- Grants-in-Aid for Scientific Research [20245031] Funding Source: KAKEN
Nanoparticles of ZnS-AgInS2 solid solution (ZAIS) were prepared in 3-amino-1-propanol (APP) solution by thermolysis of (AgIn)(x)Zn2(1-x)(S2CN(C2H5)(2))(4) (x = 0.4-1.0). The resulting APP-modified ZAIS nanoparticles of ca. 3 nm in diameter were dissolved in water. The band gap energy was enlarged by an increase in the x value of the precursor used. An intense photoluminescence was observed, the color of which was tunable from green to red by changing the kind of precursor used. The present nanoparticles with x = 1.0 exhibited an optimal quantum yield of ca. 20%, being higher than that of the conventional thiol-modified ZAIS (x = 1.0) in water prepared by a ligand exchange technique.
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