期刊
ELECTROCHEMICAL AND SOLID STATE LETTERS
卷 15, 期 2, 页码 A15-A18出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.001202esl
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-
资金
- National Natural Science Foundation of China [50872090, 51072130]
Carbon coated LiFePO4 was modified with Sr0.85Ce0.15CoO3-delta via a suspension mixing process followed by heat treatment. An integrate network formed by Sr0.85Ce0.15CoO3-delta and carbon was found on the surface of LiFePO4 particles by high resolution transmission electron microscopy. The co-coating layers alleviated the charge-transfer impedance and facilitated the lithium-ion diffusion. Consequently, the discharge capacity was significantly improved especially at high rates. The sample coated with 3 wt% Sr0.85Ce0.15CoO3-delta showed a high capacity of 94 mAh g(-1) compared with that of uncoated sample (65 mAh g(-1)) at 5C. (C) 2011 The Electrochemical Society. [DOI: 10.1149/2.001202esl] All rights reserved.
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