期刊
ELECTROCHEMICAL AND SOLID STATE LETTERS
卷 12, 期 8, 页码 A155-A158出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.3134462
关键词
electrical conductivity; electrochemical electrodes; electrochemical impedance spectroscopy; electrolytes; lithium compounds; organic compounds; secondary cells; stability
资金
- U.S. Army Research Laboratory [W911QX-07-C-0026]
- URI Foundation Prototype Development Fund
- U. S. Department of Energy Office of Vehicles Technologies
- China Scholarship Council (CSC)
- National Natural Science Foundation of China [NSFC20873046]
- Specialized Research Fund for the Doctoral Program of Higher Education [200805740004]
A lithium tetrafluorooxalatophosphate [LiPF4(C2O4)] salt, was prepared and its properties as a lithium-ion battery electrolyte were investigated. The conductivity, electrochemical stability, and cycling performance of 1.0 M LiPF4(C2O4) in 1:1:1 ethylene carbonate/dimethyl carbonate/diethyl carbonate are comparable to the industry standard LiPF6 electrolyte. While the reversible capacity of the first cycle is lower than LiPF6-based electrolytes, the reversible cycling efficiency is equivalent. Electrochemical impedance spectroscopy and electrode surface analysis provide insight into the differences between LiPF6 and LiPF4(C2O4).
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