期刊
ELECTROANALYSIS
卷 24, 期 11, 页码 2085-2093出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/elan.201200474
关键词
Nitroaromatic explosives; TNT-based nitroaromatic explosives; Hofmann method; Staudenmaier method; Hummers method; Graphene; Biosensors
资金
- MINDEF-NTV [JPP-11-02-06]
The detection of TNT and related nitroaromatic compounds in seawater is of great interest. Electrochemical techniques can be applied for detection purposes since nitroaromatic compounds contain easily reducible nitro groups. In this study, we investigate the performance of thermally reduced graphenes prepared by three different oxidative methods: Hummers, Staudenmaier and Hofmann methods with consequent thermal exfoliation. The Hofmann method-based graphene was found to exhibit the highest sensitivity in detecting TNT electrochemically. Extended study on the detection of TNT in seawater using the graphene material provided significant improvements in the detection sensitivity. These findings will have profound impacts on the detection of nitroaromatic explosives in seawater.
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