4.5 Article

Novel Amperometric Sensor Based on Rigid Near-Percolation Composite

期刊

ELECTROANALYSIS
卷 21, 期 8, 页码 931-938

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/elan.200804494

关键词

Near-percolation composite; Amperometric sensor; FIA; Swimming-pool water; Chlorine analysis

资金

  1. Universitat Autonoma de Barcelona (UAB)
  2. [CTQ2006-15681-C02-01 BQU]

向作者/读者索取更多资源

A novel amperometric sensor based on a rigid graphite-epoxy composite of which composition is near to the percolation is reported. The electrochemical response of the novel transducer material was evaluated in terms of reproducibility of the fabrication process and reproducibility and repeatability of the analytical signal. The signal to noise ration was improved, atomic force microscopy (AFM) technique was use to obtain qualitatively information. Amperometric detection of chlorine in water was carried on at a set potential of 250 mV vs. Ag/AgCl. The developed flow injection analysis (FIA) system responded linearly to chlorine concentration between 0.15 mg L (1) and 4 mg L (1) with a sensitivity of -0.20 mu A L mg (1). The proposed system was applied to real samples from swimming-pool water. No significant difference difference was observed regarding the standard method.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.5
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Analytical

Versatile Three-Dimensional-Printed Platform for Nitrite Ion Analyses Using a Smartphone with Real-Time Location

Roberto Pol, Laura Diez, David Gabriel, Mireia Baeza

ANALYTICAL CHEMISTRY (2019)

Article Chemistry, Analytical

Stable Full-Inkjet-Printed Solid-State Ag/AgCl Reference Electrode

Ana Moya, Roberto Pol, Alfonso Martinez-Cuadrado, Rosa Villa, Gemma Gabriel, Mireia Baeza

ANALYTICAL CHEMISTRY (2019)

Article Entomology

Lethal and sub-lethal effects of nanosized titanium dioxide particles on Hydropsyche exocellata Dufour, 1841

Daniel Torres-Garcia, Melissa Faria, Amadeu M. V. M. Soares, Carlos Barata, Raquel Montes, Mireia Baeza, Sergio Ponsa, Miguel Sala, Miguel Canedo-Arguelles

AQUATIC INSECTS (2020)

Article Biotechnology & Applied Microbiology

Repeatability of low scan rate cyclic voltammetry in bioelectrochemical systems and effects on their performance

Yolanda Ruiz, Juan A. Baeza, Nuria Montpart, Javier Moral-Vico, Mireia Baeza, Albert Guisasola

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY (2020)

Article Environmental Sciences

A closer look at anthropogenic fiber ingestion in Aristeus antennatus in the NW Mediterranean Sea: Differences among years and locations and impact on health condition

Ester Carreras-Colom, Maria Constenla, Anna Soler-Membrives, Joan E. Cartes, Mireia Baeza, Maite Carrasson

ENVIRONMENTAL POLLUTION (2020)

Article Chemistry, Multidisciplinary

Customized In Situ Functionalization of Nanodiamonds with Nanoparticles for Composite Carbon-Paste Electrodes

Raquel Montes, Gerard Sanchez, Jingjing Zhao, Cristina Palet, Mireia Baeza, Julio Bastos-Arrieta

NANOMATERIALS (2020)

Article Materials Science, Composites

0D polymer nanocomposite carbon-paste electrodes using carbon nanohorns: Percolating networks, electrochemical achievements and filler comparison

R. Montes, M. Baeza, J. Munoz

COMPOSITES SCIENCE AND TECHNOLOGY (2020)

Article Electrochemistry

Less is More: A Comprehensive Study on the Effects of the Number of Gas Diffusion Layers on Air-Cathode Microbial Fuel Cells

Pilar Sanchez-Pena, Jesus Rodriguez, Raquel Montes, Juan Antonio Baeza, David Gabriel, Mireia Baeza, Albert Guisasola

Summary: The study explores the interaction between the number of GDL coatings and MFC performance. The coating had a significant impact on cathode performance under low resistance, with electron transfer being the limiting process. Impedance spectroscopy measurements showed an increase in charge resistance with more GDL layers, affecting electron flow.

CHEMELECTROCHEM (2021)

Article Chemistry, Physical

Graphene functionalization with metallic Pt nanoparticles: A path to cost-efficient H2 production in microbial electrolysis cells

Pilar Sanchez-Pena, Jordi Rodriguez, David Gabriel, Juan Antonio Baeza, Albert Guisasola, Mireia Baeza

Summary: This study develops two novel Pt-functionalized inks based on reduced graphene oxide and a home-made material named Graphitene, which shows improved performance at a lower cost. Experimental results demonstrate higher intensity and increased functionalization using these materials.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Analytical

Composite Electrodes Based on Carbon Materials Decorated with Hg Nanoparticles for the Simultaneous Detection of Cd(II), Pb(II) and Cu(II)

Laia L. Fernandez, Julio Bastos-Arrieta, Cristina Palet, Mireia Baeza

Summary: This study describes the implementation of customized graphite electrodes decorated with Hg-NPs for the electrochemical detection of Cd, Pb, and Cu. The results show improved responses towards these analytes compared to bare graphite electrodes. The analytical performance of the sensors was evaluated using square-wave anodic stripping voltammetry and showed good agreement with ICP-MS measurements.

CHEMOSENSORS (2022)

Review Chemistry, Analytical

Screen-Printed Electrodes: Fabrication, Modification, and Biosensing Applications

Giti Paimard, Ehsan Ghasali, Mireia Baeza

Summary: As electrochemical measuring instruments, screen-printed electrodes (SPEs) are simple, inexpensive, and rapid to analyze substances with high reproducibility, sensitivity, and accuracy. The latest research has focused on expanding SPE electrochemical biosensors, such as aptasensors, immunosensors, DNA sensors, and enzymatic biosensors, to identify, distinguish, and quantify various biocompounds. This review discusses the use of different nanomaterials in manufacturing on-screen electrode methods and strategies for stable diagnosis of biorecognition elements in the future.

CHEMOSENSORS (2023)

Article Biotechnology & Applied Microbiology

Systematic screening of carbon-based anode materials for bioelectrochemical systems

Zainab Ul, Pilar Sanchez-Pena, Mireia Baeza, Mira Sulonen, David Gabriel, Juan Antonio Baeza, Albert Guisasola

Summary: This study evaluates the performance of different anode materials in bioelectrochemical systems (BES) and finds that carbon brush (CB) and high-active-area carbon felt (CF3) electrodes have the best overall performance, allowing for shorter start-up time and improved performance.

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY (2023)

Article Chemistry, Analytical

Novel Nitrate Ion-Selective Microsensor Fabricated by Means of Direct Ink Writing

Franc Pare, Aida Visus, Gemma Gabriel, Mireia Baeza

Summary: This work successfully fabricated a nitrate potentiometric sensor by utilizing the stability, electrical conductivity, and versatility of graphite-based inks. The hydrophobicity of graphite was also exploited to design an ion-selective electrode, preventing the formation of a water layer. The use of printing technologies allowed for easy miniaturization and lower fabrication costs. The printed sensor, composed of a graphite working electrode and a Ag/AgCl reference electrode, showed excellent sensitivity, stability, and selectivity, making it a great alternative for environmental and industrial applications.

CHEMOSENSORS (2023)

Article Environmental Sciences

Feasible H2S Sensing in Water with a Printed Amperometric Microsensor

Franc Pare, Rebeca Castro, David Gabriel, Xavier Guimera, Gemma Gabriel, Mireia Baeza

Summary: Concern over pollution has led to an increase in wastewater treatment systems, and the need for constant monitorization. Electrochemical sensors, such as a 2 mm2 graphite (Gr) electrode modified with single-walled carbon nanotubes (SWCNTs) and polymeric dispersions, are presented as an efficient and reliable method for H2S detection. This microsensor demonstrates high sensitivity, a wide pH range, and the ability to operate in complex matrices.

ACS ES&T WATER (2023)

Review Engineering, Environmental

Bioelectrochemical ammonium recovery from wastewater: A review

Mariella Belen Galeano, Mira Sulonen, Zainab Ul, Mireia Baeza, Juan Antonio Baeza, Albert Guisasola

Summary: Due to the anticipated rise in demand for ammonia, there has been increased research on viable methods for its recovery, with a focus on reducing the high energy demand associated with traditional ammonia production. Bioelectrochemical systems (BESs) offer a promising alternative for ammonia recovery, with lower energy demand compared to other methods at the lab-scale. This paper explores the fundamentals and opportunities of bioelectrochemical ammonia recovery in various BES devices and discusses the challenges in scaling up for industrial adoption.

CHEMICAL ENGINEERING JOURNAL (2023)

暂无数据