4.8 Article

Examining Substrate-Induced Plasmon Mode Splitting and Localization in Truncated Silver Nanospheres with Electron Energy Loss Spectroscopy

期刊

JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 6, 期 13, 页码 2569-2576

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.5b00961

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资金

  1. U.S. National Science Foundation [CHE-1253775]
  2. U.S. National Science Foundation through XSEDE [PHY-130045]
  3. National Science Foundation [CBET-1235651]
  4. U.S. Department of Energy, Basic Energy Sciences [DE-SC0010536]
  5. Notre Dame Energy postdoctoral fellowship
  6. U.S. Department of Energy (DOE) [DE-SC0010536] Funding Source: U.S. Department of Energy (DOE)
  7. Directorate For Engineering
  8. Div Of Chem, Bioeng, Env, & Transp Sys [1235651] Funding Source: National Science Foundation
  9. Division Of Chemistry
  10. Direct For Mathematical & Physical Scien [1253775] Funding Source: National Science Foundation

向作者/读者索取更多资源

Motivated by the need to study the size dependence of nanoparticle-substrate systems, we present a combined experimental and theoretical electron energy loss spectroscopy (EELS) study of the plasmonic spectrum of substrate-supported truncated silver nanospheres. This work spans the entire classical range of plasmonic behavior probing particles of 20-1000 nm in diameter, allowing us to map the evolution of localized surface plasmons into surface plasmon polaritons and study the size dependence of substrate-induced mode splitting. This work constitutes the first nanoscopic characterization and imaging of these effects in truncated nanospheres, setting the stage for the systematic study of plasmon-mediated energy transfer in nanoparticle-substrate systems.

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