Article
Optics
M. A. Mora-Ramirez, M. Chavez Portillo, A. Reyes Diaz, O. Portillo Moreno
Summary: In this study, PbS nanocrystalline thin films were systematically doped with Co2+ ions using the green Chemical Bath Deposition technique, and various physicochemical parameters were investigated using a first-order chemical kinetic reaction model. X-ray Diffraction analysis revealed a cubic phase in all samples, with a decrease in grain size and an increase in dislocation density observed after doping. Absorbance and bandgap studies in the Vis-UV region showed electronic transitions and excitonic bands due to higher energy transitions in nanocrystals. Three theoretical models were applied to elucidate the correlation between crystal radius and bandgap energy.
Article
Chemistry, Multidisciplinary
Tien Anh Nguyen, Thanh Le Pham, Irina Yakovlevna Mittova, Valentina Olegovna Mittova, Truc Linh Thi Nguyen, Hung Van Nguyen, Vuong Xuan Bui
Summary: In this study, single-phase nanostructured NdFe1-xCoxO3 perovskite materials were obtained by annealing mixtures of their component hydroxides at a certain temperature for a specific duration. Substitution of Fe by Co in the crystal lattice significantly changes the structural characteristics, subsequently altering the magnetic and optical properties of the materials for potential applications.
Article
Chemistry, Multidisciplinary
Denis Pluta, Henning Kuper, Rebecca T. Graf, Christoph Wesemann, Pascal Rusch, Joerg August Becker, Nadja C. Bigall
Summary: In this study, a novel gel formation method using trivalent ions was used to optimize the gelation route of NIR emitting PbS and PbS/CdS quantum dots. The influence of surface ligand affinity on network formation was investigated and their optical properties were characterized.
NANOSCALE ADVANCES
(2023)
Article
Polymer Science
G. Kadim, R. Masrour
Summary: In this work, the structural, electronic, magneto-optic, magnetocaloric and thermoelectric properties of Mn-doped PbS were investigated using first-principles density functional calculations and Monte Carlo simulation. The results showed that Mn doping slightly decreased the band gap of PbS and Pb0.5Mn0.5S exhibited antiferromagnetic behavior. The optical and thermoelectric properties were also analyzed in detail.
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
(2023)
Article
Chemistry, Physical
Doris Cadavid, Kaya Wei, Yu Liu, Yu Zhang, Mengyao Li, Aziz Genc, Taisiia Berestok, Maria Ibanez, Alexey Shavel, George S. Nolas, Andreu Cabot
Summary: The study demonstrates a synthetic route to produce Sb-doped PbS colloidal nanoparticles and consolidate them into nanocrystalline PbS:Sb using spark plasma sintering. The introduction of Sb significantly influences the properties of PbS, leading to a two-fold increase in the thermoelectric figures of merit for PbS:Sb compared to undoped PbS.
Article
Chemistry, Physical
Long Lin, Yujin Chen, Hualong Tao, Linwei Yao, Jingtao Huang, Linghao Zhu, Mengsi Lou, Ruixin Chen, Longbin Yan, Zhanying Zhang
Summary: The magnetic and optical properties of Fe and Cr doped SnS2 were studied, revealing spin polarization and ferromagnetic coupling in the doped system. The introduction of Fe and Cr atoms resulted in higher absorption coefficients in the long-wavelength infrared region, making them potential candidates for spintronic devices.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2021)
Article
Chemistry, Physical
Benoit Sklenard, Gabriel Mugny, Bilal Chehaibou, Christophe Delerue, Arthur Arnaud, Jing Li
Summary: The study investigates the electronic structure and optical bandgap of PbS quantum dots in different solvents, emphasizing the significant influence of the dielectric environment on their properties, particularly the electronic structure and electronic bandgap, providing guidance for the design of optoelectronic devices based on PbS quantum dots.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2022)
Article
Chemistry, Physical
Carolyn L. Hartley, Melody L. Kessler, Christian Y. Dones Lassalle, Andrew M. Camp, Jillian L. Dempsey
Summary: Quantum dots (QDs) are semiconductor nanocrystals with tunable optical properties through postsynthetic ligand exchanges. The stability of QD surfaces in optoelectronic devices is influenced by the composition of the ligand shell. Surface reduction of QDs is highly sensitive to the composition of the ligand shell.
CHEMISTRY OF MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Adrian Ionut Nicoara, Mihai Eftimie, Mihail Elisa, Ileana Cristina Vasiliu, Cristina Bartha, Monica Enculescu, Mihaela Filipescu, Cesar Elosua Aguado, Diego Lopez, Bogdan Alexandru Sava, Mihai Oane
Summary: This study investigates the properties of a novel PbS quantum dots-doped inorganic thin film and demonstrates its potential application in temperature sensor systems. The film was synthesized using the sol-gel method and characterized using various techniques. The results show that the PbS-doped film exhibits luminescence in the near infrared region, which makes it suitable for temperature sensing.
Article
Materials Science, Multidisciplinary
Kamlesh Chandekar, T. Alshahrani, A. Ben Gouider Trabelsi, F. H. Alkallas, Mohd Shkir, S. AlFaify
Summary: The dielectric properties of pure and yttrium-doped PbS nanoparticles were studied using various characterizations. Yttrium doping in PbS resulted in enhanced optical band gap, dielectric, and electrical properties, making them suitable for optoelectronic applications.
JOURNAL OF MATERIALS SCIENCE
(2021)
Article
Materials Science, Multidisciplinary
J. Pawlow, M. Zdonczyk, M. Guzik, G. Boulon, Y. Guyot, M. Wilk-Kozubek, A. -v. Mudring, J. Cybinska
Summary: We conducted a detailed analysis of Nd3+-doped GdPO4 nano-powders obtained through various wet synthesis methods, studying their structural and spectroscopic properties. These materials have potential applications in optoelectronics, bioimaging, and biomedicine. Different concentrations of Nd3+ were used in the synthesis, and the obtained nano-materials were characterized using techniques such as powder X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. The spectroscopic properties were found to be influenced by the morphology and grain size of the materials. The presence of Nd3+ in the GdPO4 crystal lattice did not cause structural distortion, and abnormal behavior was observed in the excited state dynamics.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Materials Science, Ceramics
Luu Huu Nguyen, Le The Tam, Nguyen Hoai Nam, Do Khanh Tung, Nguyen Xuan Truong, Dinh Van Tuan, Nguyen Van Quynh, Nguyen Le Minh Tri, Pham Thanh Phong, Pham Hong Nam
Summary: In this study, MnFe2O4 doped Gd (MnGdxFe2-xO4 with x = 0, 0.125, 0.25, and 0.5) magnetic nanoparticles were successfully synthesized, and the effect of Gd content on the structural, optical, and magnetic properties was investigated. The replacement of Fe3+ ions with Gd3+ ions resulted in a change in crystallite size and band gap. The saturation magnetization and magnetic anisotropy decreased with increasing Gd3+ ion concentration. The substantial reliance of magnetic anisotropy on the doping concentration was demonstrated.
CERAMICS INTERNATIONAL
(2023)
Article
Engineering, Electrical & Electronic
M. Mohanraj, S. Aejitha, T. Govindaraj, Theophile Niyitanga, Haekyoung Kim, Mohd Shkir
Summary: By using jet nebulizer spray pyrolysis (JNSP), we have successfully created a highly sensitive P-N junction diode using nanostructured Ag-PbS films as the junction layer. The Ag-PbS films exhibited single-crystalline hexagonal phases and distinctive surface morphology with square-shaped grain structures at 3 wt% Ag content. The optical band-gap energy of the films increased with Ag concentration. We reported the photodiode features of nanostructure p-Si/n-Ag:PbS diodes, which showed positive photoresponse current under illumination. The diode with 3 wt% Ag content achieved high responsivity, minimum ideality factor, and maximum barrier, making it suitable for photo-detector applications.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2023)
Article
Energy & Fuels
Thirumala Rao Gurugubelli, Bathula Babu, Kisoo Yoo
Summary: Nanomaterials with collective optical and magnetic properties, known as smart or functional materials, have diverse applications in science and technology. This study focused on the effects of cobalt ions at different concentrations on the structural, optical, and magnetic properties of Co-doped ZnAl2O4. The research revealed a decrease in bandgap and ferromagnetic behavior in the Co-doped ZnAl2O4 samples, showing potential for energy storage applications.
Article
Chemistry, Multidisciplinary
Dmitry N. Dirin, Anna Vivani, Marios Zacharias, Taras V. Sekh, Ihor Cherniukh, Sergii Yakunin, Federica Bertolotti, Marcel Aebli, Richard D. Schaller, Alexander Wieczorek, Sebastian Siol, Claudia Cancellieri, Lars P. H. Jeurgens, Norberto Masciocchi, Antonietta Guagliardi, Laurent Pedesseau, Jacky Even, Maksym V. Kovalenko, Maryna I. Bodnarchuk
Summary: The search for nontoxic alternatives to lead halide perovskites (LHPs) has revealed that the properties of LHPs can only be achieved in their closest Sn(II) and Ge(II) analogues, despite their tendency to oxidize. A judicious choice of chemistry led to the development of formamidinium tin iodide (FASnI3) with a power conversion efficiency of 14.81% in photovoltaic devices. The synthesis of colloidal FASnI3 NCs with reduced Sn(IV) concentration allowed for the investigation of their intrinsic structural and optical properties, showing characteristics distinct from bulk FASnI3.