期刊
DYES AND PIGMENTS
卷 111, 期 -, 页码 45-51出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2014.05.035
关键词
Fluorescence; Solvatochromism; Lippert-Mataga model; Dipole moment; Fluorene derivative; Prodan
资金
- COLCIENCIAS
- Universidad del Valle
Fluorophores based in triphenylamine and fluorene (1-3) were synthetized and the effects of pi-conjugated linkers (vinyl, ethynyl and 1,3-diynyl) on the solvatochromic properties were studied. The fluorescence emission spectra of the dyes were studied using solvents of different polarities, and the influence of specific solvent solute interactions over emission properties was investigated through Lippert-Mataga model. In particular, we found that compound 2 (with an ethynyl group) exhibits significant advantages over compounds 1 and 3 with vinyl and 1,3-dynyl groups, respectively. It shows a better solvatochromism (140 nm from hexane to CH3CN), higher Stokes shifts (178 nm in CH3CN) and more sensitive quantum yields toward solvent polarity (0.09(DMF)-0.98(THF)), when compared with those to the reference probe (Prodan). Furthermore, this linker exhibits higher resistance against photo-degratation under same conditions. The geometrical and electronic transitions were analyzed by DFT and TD-DFT, and the results are consistent with the experimental observations. (C) 2014 Elsevier Ltd. All rights reserved.
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