期刊
DYES AND PIGMENTS
卷 94, 期 2, 页码 233-238出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2012.01.016
关键词
Dye-surfactant interaction; Binding constant; Partition coefficient; Micelle; Spectrophotometry; Thermodynamic parameter
资金
- Akdeniz University
The interactions between C.I. Basic Yellow 2 (BY2) and sodium dioctylsulfosuccinate (NaDS) have been investigated in the premicellar and micellar region using spectrophotometric method at 288.15, 298.15, 308.15 and 31815 K. Absorption spectra of dye-surfactant mixtures show that dye surfactant aggregates occur in the premicellar region. The addition of excess NaDS to the BY2 solution enhances the solubility of dye molecules due to the micelle formation. Moreover, the presence of excess surfactant micelles in the dye solution causes an increase in the absorption intensity of BY2 and leads to a bathochromic shift in the maximum absorption wavelength of dye. The values of binding constants, partition coefficients between the micellar and the bulk water phases and thermodynamic parameters have been calculated for the BY2-NaDS system at different temperatures. The binding of BY2 to surfactant micelles decreases with increasing temperature. The binding and partition processes are exothermic and occur spontaneously. (C) 2012 Elsevier Ltd. All rights reserved.
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