期刊
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY
卷 153, 期 -, 页码 289-295出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotobiol.2015.10.007
关键词
Zinc oxide nanoparticles; Humic acid; Adsorption; Stability; Toxicity
资金
- Science & Engineering Research Board (SERB), Department of Science & Technology, Government of India [SERB/LS-587/2012]
The present study investigated the stability of zinc oxide nanoparticles (ZnO NPs) by the adsorption of humic acid (HA) and the mechanism of adsorption. The effect of humic acid on NP toxicity was determined by Escherichia coli (ATCC 13534), E. coli (ATCC 25922), and Pseudomonas putida (MTCC 4910). The nanoparticles showed low zeta potential and were least stable in the absence of HA. However, the negative surface charge of the particles increased in the presence of HA (0-50 mg/L) that reduced the propensity of nanoparticles to aggregate in water. A decrease in absorbance of ZnO NPs at 375 nm (plasmon peak) was noted in the presence of HA by UV-visible spectrophotometric analysis. A blue shift towards 370 nm was noted when the concentration of HA was above 20 mg/L. The HA adsorbed ZnO NPs showed higher zeta potential (>-30 mV) and were highly stable. HA reduced the photocatalytic activity of ZnO and at the same time increased the photostability of ZnO. (C) 2015 Elsevier B.V. All rights reserved.
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