期刊
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
卷 301, 期 -, 页码 47-54出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2014.12.011
关键词
Indium phthalocyanine; Photodynamic antimicrobial chemotherapy; Singlet oxygen quantum yield; Triplet quantum yield; Escherichia coli
资金
- National Research Foundation through DST/NRF South Africa Research Chairs Initiative [62620]
- Rhodes University
- Department of Science and Technology, Republic of South Africa
The synthesis and photophysicochemical properties of mono- and tetra-pyridyloxy substituted indium (III) phthalocyanines (InPcs) are presented in this study. General trends are described for quantum yields of fluorescence, triplet, singlet oxygen and photodegradation as well as lifetimes of fluorescence and triplet state of these compounds. The complexes exhibited high singlet oxygen quantum yields (Phi(Delta)) ranging from 0.44 to 0.66 in DMF, and from 0.44 to 0.69 in DMSO and Phi(Delta) = 0.31 for the quartenized tetra substituted InPc which is soluble in water. The triplet quantum yields (Phi(T)) ranged from 0.77 to 0.95 in DMF and from 0.77 to 0.94) in DMSO. The tetra substituted photosensitizers do not differ in their inactivation of bacteria with over 8 log reduction of viable bacteria when compared with the mono substituted photosensitizer which could only manage a 1 log reduction. (C) 2014 Elsevier B.V. All rights reserved.
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