期刊
DIAMOND AND RELATED MATERIALS
卷 19, 期 5-6, 页码 374-381出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.diamond.2009.11.018
关键词
Chemical modification; Carbon materials; Fluorine; Photochemistry
The photolysis of perfluoroazooctane in the presence of carbon materials, such as diamond powder, films, diamond-like carbon films, nanodiamond films and single-walled carbon nanotubes, led to the chemical modification of their surface by the introduction of perfluorooctyl functional groups, which was confirmed by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, time-of-flight secondary ionization mass spectrometry, Raman spectroscopy and mass spectroscopy measurements. The carbon materials modified with fluorine moieties exhibited a reduced friction coefficient and a reduction of their surface energy, evaluated by the contact angle with water, compared with those of pristine carbon materials. (C) 2009 Elsevier B.V. All rights reserved.
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