Article
Physics, Applied
L. Mehmel, R. Issaoui, O. Brinza, A. Tallaire, V. Mille, J. Delchevalrie, S. Saada, J. C. Arnault, F. Benedic, J. Achard
Summary: By employing a growth strategy based on micrometric laser-pierced hole arrays, the dislocation density in heteroepitaxial chemical vapor deposition diamond can be significantly reduced, reaching an average value equivalent to that typically measured for commercial type Ib single crystal diamonds.
APPLIED PHYSICS LETTERS
(2021)
Article
Materials Science, Multidisciplinary
Joshua Claes, Bart Partoens, Dirk Lamoen
Summary: The DFT-21 method is a band-gap correction with GW precision that allows for the calculation of optical transitions between defect levels. However, it fails when the atomic character of the occupied and unoccupied defect levels is similar. We propose the decoupled DFT-12 method to solve this problem.
Article
Multidisciplinary Sciences
Alexander Savvin, Alexander Dormidonov, Evgeniya Smetanina, Vladimir Mitrokhin, Evgeniy Lipatov, Dmitriy Genin, Sergey Potanin, Alexander Yelisseyev, Viktor Vins
Summary: The authors successfully demonstrated lasing in (NV-) centers in diamond, achieving improved laser efficiency by fine-tuning the pump conditions to reduce photoionization. Investigation into lasing conditions and gain saturation was conducted under high-power laser pulse pumping of diamond crystal.
NATURE COMMUNICATIONS
(2021)
Article
Materials Science, Ceramics
Juanli Zhao, Wai-Yim Ching, Mengling Lai, Yun Fan, Jiancheng Li, Yiran Li, Wenxian Li, Bin Liu
Summary: In this study, the stabilities of (1 0 0), (1 1 0), and (1 1 1) surfaces of rare-earth zirconate pyrochlores were investigated. It was found that the (1 1 0) surface has the lowest surface formation energy and exhibits characteristics of oxygen vacancy segregation. These findings are important for understanding the surface structure and oxygen vacancy behavior, and can guide the optimization of surface properties for nanocrystalline rare-earth zirconates.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Si-Mian Liu, Shi-Hao Zhang, Shigenobu Ogata, Hui-Long Yang, Sho Kano, Hiroaki Abe, Wei-Zhong Han
Summary: This study provides experimental evidence to show that vacancy clusters promote heterogeneous nucleation in zirconium and cause an anomalous precipitation memory effect. Atomistic simulations reveal that hydrogen atoms preferentially segregate at vacancy sites and clusters, assisting hydride nucleation and stimulating the unusual memory effect. This finding challenges traditional views on the sequence of nucleation sites and provides insights into solid phase transformations related to vacancy-sensitive alloying elements.
Article
Engineering, Mechanical
Kaitao Wu, Guisen Liu, Ping Yu, Changqing Ye, Jiaqing Shi, Yao Shen
Summary: The article discusses the importance of developing irradiation hardening models for nuclear materials and proposes a VC-dislocation interaction model based on the dislocation dynamics method. The model is implemented in open-source software and used to investigate the hardening effect of varying size and number density of vacancy clusters. The simulation results show that the hardening effect is proportional to the 2/3 power of the total number density, and a modified hardening model is proposed to improve the accuracy of predicting VC-induced hardening in tungsten.
INTERNATIONAL JOURNAL OF PLASTICITY
(2022)
Article
Physics, Applied
Si Gao, Si-Yu Yin, Zhao-Xin Liu, Zong-Da Zhang, Zhen-Nan Tian, Qi-Dai Chen, Nian-Ke Chen, Hong-Bo Sun
Summary: This study successfully prepared single NV color centers in diamonds with narrow optical linewidths and long coherence time using the femtosecond laser direct writing technique, which showed narrower linewidths compared to NV color centers prepared using ion implantation method. The density functional theory was used to explain the difference.
APPLIED PHYSICS LETTERS
(2022)
Article
Chemistry, Physical
Biao Zhang, Yaolin Guo, Zhen Liu, Meie Li, Diwei Shi, Yifan Li, Jiexi Song, Moran Bu, Shiyu Du
Summary: The study focuses on the diffusion and segregation properties of vacancies near < 111 > edge or screw dislocations in bcc iron, using diffusive molecular dynamics method. The interaction effects on vacancy segregation, dislocation motion, and crystal plasticity are discussed, providing insights on the vacancy transport mechanisms essential for understanding metallic materials.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Multidisciplinary
Erin S. Grant, Liam T. Hall, Lloyd C. L. Hollenberg, Gawain McColl, David A. Simpson
Summary: In this study, the magnetic properties of ferritin, the primary storage protein in the body, were systematically studied using diamond-based quantum spin relaxometry. An anomalous magnetic behavior was observed at relatively low iron loads due to a morphological change in the iron core of ferritin. The inclusion of this morphological change in a theoretical model was supported by electron microscopy studies and provided evidence for the magnetic consequence of the morphological change.
Article
Physics, Applied
P. Raecke, L. Pietzonka, J. Meijer, D. Spemann, R. Wunderlich
Summary: NV centers in diamond were engineered by introducing vacancies locally through argon ion implantation in type Ib diamond with subsequent annealing. The number of NV centers created from vacancies of a single implanted argon ion ranges from 0.04 to 0.79 depending on the ion energy. The diffusion of vacancies during annealing plays a significant role in NV yield behavior.
APPLIED PHYSICS LETTERS
(2021)
Article
Materials Science, Multidisciplinary
Shigeo Saimoto, Bradley J. Diak, Anna Kula, Marek Niewczas
Summary: The new assimilated work-hardening model explains the formation of slipped areas due to dislocations and work hardening operation of multiple slip systems. The minimum slip plane spacing is determined geometrically and compared with the lattice spacing allowed for dislocation passage. This spacing is larger than the imposed strain and is attributed to dynamic dislocation annihilation. The coordination of strain and stress criteria is self-organized by evolving internal stress.
MATERIALS TODAY COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Umberto Celano, Hai Zhong, Florin Ciubotaru, Laurentiu Stoleriu, Alexander Stark, Peter Rickhaus, Felipe Favaro de Oliveira, Mathieu Munsch, Paola Favia, Maxim Korytov, Patricia Van Marcke, Patrick Maletinsky, Christoph Adelmann, Paul van der Heide
Summary: In this study, nonperturbative field distribution mapping in ultra-scaled magnetic nanowires with diameters down to 6 nm was achieved using scanning nitrogen-vacancy magnetometry, enabling localized, minimally invasive magnetic imaging with sensitivity down to 3 μT Hz(-1/2). The imaging revealed the presence of weak magnetic inhomogeneities inside in-plane magnetized nanowires, largely undetectable with standard metrology. The strong magnetic field confinement in the nanowires allowed for the study of the interaction between the stray magnetic field and the nitrogen-vacancy sensor, clarifying the formation mechanisms for technologically relevant magnetic nanostructures.
Article
Chemistry, Multidisciplinary
Tianqi Zhu, Jan Rhensius, Konstantin Herb, Viraj Damle, Gabriel Puebla-Hellmann, Christian L. Degen, Erika Janitz
Summary: The research team addressed the poor signal-to-noise ratio (SNR) issue of optical spin-readout techniques by coupling individual NV centers to optimized diamond nanopillars, leading to improved collection efficiency of fluorescence. The optimized devices showed increased SNR and were compatible with low-numerical-aperture collection optics and a reduced tip radius, reducing experimental overhead and improving spatial resolution for scanning applications.
Article
Multidisciplinary Sciences
Chu-Feng Liu, Weng-Hang Leong, Kangwei Xia, Xi Feng, Amit Finkler, Andrej Denisenko, Jorg Wrachtrup, Quan Li, Ren-Bao Liu
Summary: The article presents an improved design of a hybrid nanothermometer using NV centers and magnetic nanoparticles, demonstrating enhanced temperature sensitivity. This design enables detection of small temperature changes and offers a new tool for studying thermal processes in nanoscale systems.
NATIONAL SCIENCE REVIEW
(2021)
Article
Optics
Zong-Da Zhang, Si-Yu Yin, Li-Cheng Wang, Ying-De Wang, Yun-Fei Li, Zhen-Nan Tian, Qi-Dai Chen
Summary: An array of single NV centers was prepared using the femtosecond laser direct writing method to address the accuracy and consistency issues in static magnetic field detection. The prepared NV centers have fewer defects and good stress uniformity, with an average spatial positioning error of only 0.2 μm. This array enables high accuracy measurement of magnetic field vector and gradient.
Article
Materials Science, Multidisciplinary
Shuanghui Zeng, Xue Wang, Yunqian Zhang, Jiaojing Shao, Zhao Ding, Jie Zhao
Summary: A free-standing 3D core/shell composite material CNTs@Co9S8 on nickel mesh has been prepared using a simple two-step method. The composite material exhibits excellent conductivity and charge storage capability, making it a promising candidate for supercapacitor applications.
DIAMOND AND RELATED MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Marieta Belcheva, Georgi Georgiev, Boyko Tsyntsarski, Urszula Szeluga, Lyudmila Kabaivanova
Summary: This study successfully prepared new antibacterial materials by combining activated carbon with metal nanoparticles, taking advantage of the well-known antibacterial activity of metal nanoparticles. The obtained composites exhibited strong antibacterial effects against E. coli and S. aureus, with the antibacterial activity depending on the contact time, bacterial species, nature of the metal, and metal concentration. The findings provide novel materials with antibacterial properties for further development and potential application in hygiene devices.
DIAMOND AND RELATED MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
V. P. Madhurima, Kusum Kumari, P. K. Jain
Summary: In this study, carbon nanomaterials were synthesized using the arc discharge technique, with a focus on optimizing process parameters to improve yield and quality. The materials were characterized using various analytical tools, and their dye adsorption capabilities were evaluated. The results showed that carbon soot had better adsorption performance compared to carbon nanotubes, indicating the potential of these carbon nanomaterials for environmental remediation applications.
DIAMOND AND RELATED MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Zhaolong Sun, Bo Cui, Pingping Liang, Qimeng Liu, Nan Gao, Hongdong Li
Summary: This study explores the potential of hafnium (Hf) terminated diamond surfaces in achieving negative electron affinity (NEA). By using swarm-intelligence structural search and first-principles calculations, the researchers found that Hf-terminated diamond surfaces exhibit stable NEA properties and high thermal stability, making them promising candidate materials for electron emission applications.
DIAMOND AND RELATED MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
N. Soltani, N. Tavakkoli, E. Eslami, L. S. Mirmohammadi
Summary: In this project, a carbon paste electrode modified with graphene and ZnFe2O4 spinel nanoparticles (Gr/ZnFe2O4/CPE) was used to measure naproxen, and various electrochemical methods were used to investigate its behavior. By optimizing the parameters, good measurement results were obtained.
DIAMOND AND RELATED MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Xiwei Cui, Yue Qin, Xin Han, Huanyi Chen, Xinxin Ruan, Hui Zhang, Chengcheng Jiao, Rongqi Mao, Jinglin Hao, Sizhuang Zhao, Shuai Hou, Xiaoxuan Pian, Yandong Wang, Kazuhito Nishimura, Lifen Deng, Nan Jiang
Summary: This paper investigates the friction and wear behaviors of two types of polycrystalline diamonds against different materials. The results show that increasing surface roughness leads to an increase in coefficient of friction. The coefficient of friction and wear rate of ceramic Si3N4 balls are generally lower than those of steel GCr15 balls, except for one type of polycrystalline diamond. Transfer films of SiO2 and its hydrate are observed at the friction interface, which contribute to smoother friction and wear. Carbon-based transfer films are also identified, mainly catalyzed by residual cobalt in the polycrystalline diamonds, leading to a phase transformation.
DIAMOND AND RELATED MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Menglei Sun, Pengjun Li, Mao Wang, Yidan Liang, Xudong Yang, Shujie Pang
Summary: In this study, carbonized polymer dots were synthesized by a one-step hydrothermal method, and silver nanoclusters were synthesized by UV lamp irradiation. They were then self-assembled by electrostatic force to prepare a dual-emission fluorescent nanocomposite that responds to temperature changes. The nanocomposite showed two emission peaks and exhibited excellent linearity between 20°C and 80°C.
DIAMOND AND RELATED MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Mohamed J. Saadh, Durgesh Singh, Diego Mayorga, Anjan Kumar, Maria Albuja, Ahmad Ismael Saber, Mohammed Ahmed Mustafa, Yasser Elmasry, Noubu Sun
Summary: Based on density functional theory, it is found that the C3N monolayer has good adsorption capability for Hg0 and a short recovery time. This study suggests that the C3N monolayer is a promising adsorbent material for efficient control of gaseous mercury.
DIAMOND AND RELATED MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Rajendra Kumar Nare, Sivalingam Ramesh, Vijay Kakani, Yuvaraj Haldorai, Chandrasekaran Karthikeyan, Basivi Praveen Kumar, Nadavala Siva Kumar, Mohammad Asif, S. Naresh Kumar, D. Prakash Babu, K. Ramakrishna Reddy, Visweswara Rao Pasupuleti
Summary: This study examines the latest advancements in carbon nanotube (CNT) supercapacitors and related composites, aiming to identify strategies for enhancing their performance. The researchers used ultrasonication aided hydrothermal technique to synthesize a composite made of nitrogen doped carbon nanotubes and porous NiCo2O4 nanomaterial. The composite electrode exhibited excellent cycling stability and a rising specific capacitance, making it appealing for high-performance supercapacitor applications.
DIAMOND AND RELATED MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
D. Mary Deena, S. Arockia Anushya, A. Dhanusha, T. C. Sabari Girisun, A. Philominal
Summary: A single-beam Z-Scan experiment was conducted to investigate the nonlinear optical absorption and optical limiting properties of Bi2O3, rGO/Bi2O3, Bi2O3/WO3, and rGO/Bi2O3/WO3 nanostructures. The results showed that the synthesized nanostructures exhibited varying levels of nonlinear absorption, with bismuth-based nanostructures showing the lowest optical limiting threshold and a higher two-photon absorption coefficient. The presence of rGO contributed to the extended conjugation for charge transfer, while the strong UV-Visible absorption of Bi2O3 and WO3 led to a unique nonlinear optical response.
DIAMOND AND RELATED MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Weibing Guo, Yiren Hu, Tao Wang, Xiaoguang Chen
Summary: This study investigated the microstructure and forming mechanism of graphite/copper joints that were brazed using Ti-containing filler. The results showed that increasing the brazing temperature improved the heat transfer and tensile properties of the composites. Additionally, the composites exhibited high heat flux and faster heating rate compared to copper and aluminum.
DIAMOND AND RELATED MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Ming Li, ZhiWen Wang, Yu Teng, Hongyu Zhao, Bowei Li, Yang Liu, Shengxue Wang, Zhenze Yang, Liangchao Chen, Hongan Ma, Xiaopeng Jia
Summary: In the experiment, different Ni-content catalysts were used to synthesize diamond crystals, and the properties of the synthesized diamonds were analyzed. The results revealed that the Ni content in the catalyst affects the crystallinity of diamond crystals and the nitrogen crystallinity. The photoluminescence spectroscopy also showed that the diamond synthesized by using Fe-containing catalyst has specific NV-color center structure.
DIAMOND AND RELATED MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Ling-Feng Mao
Summary: This study proposes an LSTM model to predict the work function of adsorbed metal atoms on graphene, which can quickly screen surface structures with target work function, saving computing and time costs, and improving device performance.
DIAMOND AND RELATED MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Runzhou Xu, Yinshui Liu, Qian Cheng, Zhenyao Wang, Kai Ma, Peiling Ke, Yipan Deng
Summary: The wear resistance of 17-4PH stainless steel was significantly improved by depositing multi-layered Cr/CrC/DLC coating at wide temperature range. The coating exhibited excellent lubrication and protective properties, and the wear mechanism changed with increasing temperature. The tribochemical reaction during the wear process played a crucial role in the graphitization transformation and friction properties of the coating.
DIAMOND AND RELATED MATERIALS
(2024)
Article
Materials Science, Multidisciplinary
Xilong Guo, Jiaxin Song, Shanling Wang, Li Lei, Omololu Odunmbaku, Ayoub Taallah, Yi He, Aiqun Gu, Filippo S. Boi
Summary: The recent observations of superconductive-ordering in carbon-based systems consisting of rhombohedral stacking-faults, trilayer graphene (ABC-stacks) or dislocation-rich interfaces (pyrolytic graphite) have attracted significant attention. In this study, an unusual nucleation of rhombohedral stacking-faults in low-dimensional systems comprising of multiwall carbon nanotube (CNT) buckypapers was reported. The presence of sulfur doping resulted in a broad-band at the Raman shift from 1800 to 2000 cm(-1), indicating contributions arising from disorder-rich regions with rhombohedral stacking-order (ABC-stacks). These observations were further supported by X-ray diffraction and Rietveld refinements.
DIAMOND AND RELATED MATERIALS
(2024)