期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 80, 期 15, 页码 7456-7467出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b01024
关键词
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资金
- Program of China (973 Program) [2011CB808600]
- National Natural Science Foundation of China [21202046, 21472051]
- Guangdong Natural Science Foundation [10351064101000000]
- Fundamental Research Funds for the Central Universities [2014ZZ0046]
A highly regio- and stereoselective C-C double bond formation reaction via Pd-catalyzed Heck-type cascade process with N-tosylhydrazones has been developed. Various N-tosylhydrazones derived from both ketones and aldehydes are found to be efficient substrates to provide di- and trisubstituted olefins with high regio- and stereoselectivity. Furthermore, this reaction has a good functional group tolerance and different benzofuran-, dihydrobenzofuran-, and indoline-containing alkene products were obtained with high selectivity.
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