期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 80, 期 17, 页码 8694-8704出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b01248
关键词
-
资金
- Iran National Science Foundation (INSF)
- University of Kurdistan Research Councils
In this article, we report three odorless methods for the thioarylation and thioalkylation of different nitroarenes using alkyl halides (Br, Cl), triphenyltin chloride, and arylboronic acids as the coupling partners. Triphenyltin chloride is capable of delivering all of its phenyl groups to the product. Depending on the reaction, sodium thiosulfate pentahydrate (Na2S2O3 center dot 5H(2)O), S-8/KF, and S-8/NaOH systems are found to be effective sources of sulfur in the presence of copper salts. The use of green solvents, inexpensive catalysts, and user-friendly starting materials has made these methods interesting from a green chemistry standpoint.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据