期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 80, 期 21, 页码 10431-10436出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b01929
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology of Japan [25410048]
- Grants-in-Aid for Scientific Research [25410048] Funding Source: KAKEN
Fluorination of styrene derivatives with a reagent system composed of mu-oxo-bis[trifluoroacetato(phenyl)iodine] and a pyridine.HF complex gave the corresponding (2,2-difluoroethyl)arenes in good yields. Similarly, the reagent of PhI(OCOCF3)(2) and the pyridine.HF complex acted as a fluorinating agent for styrene derivatives. The fluorination of styrene derivatives with the pyridine. HF complex underwent under catalytic conditions using 4-iodotoluene as a catalyst and m-CPBA as a terminal oxidant.
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