期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 80, 期 10, 页码 5369-5376出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b00739
关键词
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资金
- Council of Scientific and Industrial Research (CSIR), New Delhi
- CSIR network project THUNDER [BSC0102]
- CSIR network project HOPE [BSC0114]
A transition-metal-free C-3-arylation of quinolin-4-ones in the presence of base has been achieved by using arylhydrazines as aryl radical source and air as oxidant. The reaction proceeds smoothly at room temperature and does not require any prefunctionalization and N-protection of quinoline-4-ones. The utility of this methodology is further demonstrated in synthesis of quinoline quinolone hybrid as well as 6-aryl-benzofuro[3,2-c]quinoline scaffold.
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