期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 80, 期 12, 页码 6456-6466出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b00907
关键词
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资金
- Portland State University
- National Institute of Environmental Health Sciences (NIEHS), National Institutes of Health (NIH) [P30ES000210]
The base mediated coupling of aliphatic alcohol pronudeophiles with unsymmetric diaryliodonium salt electrophiles is described. This metal-free reaction is operationally simple, proceeds at mild temperature, and displays broad substrate scope to generate industrially important alkyl-aryl ethers in moderate to excellent yield. The synthetic utility of these reactions is demonstrated, and aspects of sustainability are highlighted by the use of unsymmetric aryl(mesityl)iodonium arylating reagents.
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