4.7 Article

Preparation of nanocavity-contained thin film composite nanofiltration membranes with enhanced permeability and divalent to monovalent ion selectivity

期刊

DESALINATION
卷 445, 期 -, 页码 115-122

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.desal.2018.07.023

关键词

Nanofiltration; Thin film composite; Interfacial polymerization; beta-Cyclodextrin; Desalination pretreatment

资金

  1. General Research Fund [17207514]
  2. Research Grants Council of Hong Kong
  3. Strategic Research Theme (Clean Energy)
  4. Seed Grant for Basic Research of the University of Hong Kong [201511159141]

向作者/读者索取更多资源

Using hydroxypropyl-beta-cyclodextrins (OH-beta-CD) as aqueous phase additive, nanocavity-contained thin film composite (TFC) nanofiltration (NF) membranes were prepared by interfacial polymerization of piperazine (PIP) and trimesoyl chloride (TMC). Attenuated total reflectance Fourier transform infrared and X-ray photoelectron spectroscopy analysis confirmed the successful incorporation of OH-beta-CDs into the thin polyamide rejection layers. The rejection layer morphologies and structures, surface properties and separation performances of the prepared TFC membranes were greatly influenced by the OH-beta-CD mass ratio in aqueous phase during interfacial polymerization. With appropriate OH-beta-CD mass ratios (20-60%), the prepared TFC membranes showed enhanced water flux, reduced R-NaCl, increased R-Na2SO4 and R-MgSO4, which led to highly improved divalent to monovalent ions selectivity. These nanocavity-contained TFC membranes exhibited the potential to apply in desalination pretreatment.

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