4.7 Article

Preparation and characterization of ZnO/polyethersulfone (PES) hybrid membranes

期刊

DESALINATION
卷 293, 期 -, 页码 21-29

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.desal.2012.02.019

关键词

Nano-ZnO; Polyethersulfone; Hybrid membrane

资金

  1. Shanghai Municipal Science and Technology Committee [08231200300]
  2. Knowledge Innovation Program of Chinese Academy of Sciences

向作者/读者索取更多资源

With nano-ZnO as an additive, polyethersulfone (PES) membranes and a series of ZnO/PES hybrid membranes were prepared by a phase-inversion method. Experimental results show that, with the increase of addition weight of nano-ZnO the contact angle decreases and the therm decomposition temperature increases. The porosity of ZnO/PES hybrid membrane is improved by adding nano-ZnO. The flux of ZnO/PES hybrid membrane exhibits an improvement of 254% relative to that of the PES membrane, whereas the rejection is changed a little. After 90 min of continuous filtrating of BSA solution (1 g/L, pH = 7.4), the flux decreased ratio of the ZnO/PES hybrid membrane (with 0.3 g of added nano-ZnO) is only 7.8%, which implies that the antifouling properties are significantly improved relative to those of the PES membrane. (c) 2012 Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Review Engineering, Environmental

Engineering metal-organic frameworks (MOFs) based thin-film nanocomposite (TFN) membranes for molecular separation

Die Ling Zhao, Fan Feng, Liguo Shen, Zhengyi Huang, Qipeng Zhao, Hongjun Lin, Tai-Shung Chung

Summary: Metal-organic frameworks (MOFs) are hybrid materials with well-defined porous structures, and they have shown great potential as nanofillers in membranes for molecular separation. Recent research has demonstrated promising results in membrane permeability and selectivity when incorporating MOFs in thin-film nanocomposite (TFN) membranes. Challenges in lab-scale research and barriers to commercialization of MOF-incorporated TFN membranes still need to be addressed. This review aims to highlight recent efforts and advances in overcoming these challenges and barriers, as well as to assess the potential applications of MOF-incorporated TFN membranes for molecular separation.

CHEMICAL ENGINEERING JOURNAL (2023)

Review Engineering, Environmental

The coupling of persulfate activation and membrane separation for the effective pollutant degradation and membrane fouling alleviation

Mingzhu Zhou, Junjie Chen, Shuning Yu, Binghong Chen, Cheng Chen, Liguo Shen, Bisheng Li, Hongjun Lin

Summary: This paper introduces a PS-activation catalysis-membrane system (PACMS) for wastewater treatment, including homogeneous and heterogeneous systems. The activation methods and mechanisms of PS in PACMS are discussed, and various preparation strategies of catalytic membrane are summarized. The applications of PACMS in wastewater treatment are highlighted.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Environmental Sciences

Mitigation of protein fouling by magnesium ions and the related mechanisms in ultrafiltration process

Hui Zou, Jiahui Huang, Meijia Zhang, Hongjun Lin, Jiaheng Teng, Zhengyi Huang

Summary: This study demonstrates that the addition of magnesium ions (Mg2+) can significantly reduce protein fouling on membranes, and an optimal concentration of Mg2+ exists for achieving the lowest fouling. This is attributed to the hydration repulsion effect of Mg2+ and the conformational change of protein molecules.

CHEMOSPHERE (2023)

Article Environmental Sciences

3D printing titanium dioxide-acrylonitrile-butadiene-styrene (TiO2-ABS) composite membrane for efficient oil/water separation

Lei Han, Liguo Shen, Hongjun Lin, Zhengyi Huang, Yanchao Xu, Renjie Li, Bisheng Li, Cheng Chen, Wei Yu, Jiaheng Teng

Summary: A functional TiO2-ABS composite membrane was generated through 3D printing for the first time and used for simulated oily water treatment. The membrane showed high hydrophilicity and oleophobicity, as well as high flux and oil rejection rate. The membrane demonstrated over 99% rejection for all five types of oil/water systems, indicating its broad development trend and application prospect.

CHEMOSPHERE (2023)

Article Environmental Sciences

Efficient oil-water emulsion treatment via novel composite membranes fabricated by CaCO3-based biomineralization and TA-Ti(IV) coating strategy

Hongli Xie, Binghong Chen, Hongjun Lin, Renjie Li, Liguo Shen, Genying Yu, Lining Yang

Summary: Continuous discharge of industrial oily wastewater and frequent oil spill accidents have caused significant damage to the global environment and human health. A new strategy utilizing tannic acid (TA)-Ti(IV) coating and CaCO3-based biomineralization through inkjet printing process has been proposed to modify PVDF membranes, resulting in high hydrophilicity and underwater superoleophobicity. The optimized TA-Ti(IV)-CaCO3 modified membrane demonstrated excellent water permeation and separation efficiency for various oil/water emulsions, with high flux recovery and low fouling. This simple and cost-effective modification process shows great potential for oil/water emulsion separation/treatment.

SCIENCE OF THE TOTAL ENVIRONMENT (2023)

Article Chemistry, Multidisciplinary

Embedding Plasmonic Metal into Heterointerface of MOFs-Encapsulated Semiconductor Hollow Architecture for Boosting CO2 Photoreduction

Weihao Mo, Zhixin Fan, Shuxian Zhong, Wenbin Chen, Lingxuan Hu, Hao Zhou, Wei Zhao, Hongjun Lin, Jing Ge, Jianrong Chen, Song Bai

Summary: Coupling hollow semiconductor with metal-organic frameworks (MOFs) is promising for high-efficient CO2 photoreduction. To overcome the energy band mismatch, a stacked semiconductor/metal@MOF photocatalyst is developed, where embedded Au plays critical roles in charge separation/transfer and CO2 activation. The as-prepared H-CdS/Au@ZIF-8 exhibits boosted activity and selectivity in CO production. This work provides protocols to enhance solar-to-chemical energy conversion efficiency through harnessing charge transfer.
Review Chemistry, Multidisciplinary

Covalent Organic Frameworks: The Rising-Star Platforms for the Design of CO2 Separation Membranes

Binghong Chen, Hongli Xie, Liguo Shen, Yanchao Xu, Meijia Zhang, Mingzhu Zhou, Bisheng Li, Renjie Li, Hongjun Lin

Summary: Membrane-based carbon dioxide (CO2) capture and separation technologies have attracted significant interest for their potential in combatting global warming, reducing energy consumption, and achieving carbon neutrality. Covalent organic frameworks (COFs), composed of reversible covalent bonds, offer high porosity, tunable functionality, and excellent stability, making them promising alternatives for CO2 separation membranes. This review summarizes the advantages of COFs in CO2 separation, discusses preparation approaches for COF-based membranes, and highlights their advances in separating various CO2 mixed gases. Future research directions and current challenges in this field are also proposed.
Article Engineering, Environmental

High propensity of membrane fouling and the underlying mechanisms in a membrane bioreactor during occurrence of sludge bulking

Mengfei Wu, Meijia Zhang, Liguo Shen, Xinhua Wang, Deng Ying, Hongjun Lin, Renjie Li, Yanchao Xu, Huachang Hong

Summary: This study compared the fouling behaviors of a membrane bioreactor (MBR) operated at normal and sludge bulking stages, and explored the different mechanisms behind these behaviors. The results showed that the MBR could be stably operated for about 60 days without membrane cleaning in the normal stage, while daily membrane cleaning was required in the sludge bulking stage. Further characterizations revealed that the bulking sludge had lower dewaterability, smaller particle size, higher fractal dimension, higher viscosity, abundant filamentous bacteria, and different types of extracellular polymer substances (EPS). It was suggested that microbial community transition was responsible for the occurrence of sludge bulking, which in turn affected membrane fouling. Based on these findings, it was proposed that providing extra force to offset a chemical potential gap caused by foulant layer structure transition during sludge bulking is necessary to sustain filtration and prevent extremely high specific filtration resistance (SFR).

WATER RESEARCH (2023)

Article Environmental Sciences

Algae extract delamination of molybdenum disulfide and surface modification with glycidyl methacrylate and polyaniline for the elimination of metal ions from wastewater

Saleem Raza, Muhammad Usman Hameed, Ehsan Ghasali, Asif Hayat, Yasin Orooji, Hongjun Lin, Ceren Karaman, Fatemeh Karimi, Nevin Erk

Summary: A special type of two-dimensional material based conducting polymer was constructed by green synthesis and in-situ polymerization techniques. The resulting material showed excellent adsorption performance towards Cu2+ and Cd2+ ions and can be easily regenerated. This method has potential for various applications in different fields.

ENVIRONMENTAL RESEARCH (2023)

Article Environmental Sciences

Novel thermodynamic mechanisms of co-conditioning with polymeric aluminum chloride and polyacrylamide for improved sludge dewatering: A paradigm shift in the field

Yansha Zeng, Zhe Wang, Zhenxiang Pan, Liguo Shen, Jiaheng Teng, Hongjun Lin, Jianzhen Zhang

Summary: This study investigated the combined effects of polymeric aluminum chloride (PAC) and polyacrylamide (PAM) on sludge dewatering, aiming to uncover the underlying mechanisms. The co-conditioning of 15 mg g-1 PAC and 1 mg g-1 PAM achieved optimal dewatering performance, significantly reducing the specific filtration resistance (SFR) of the co-conditioned sludge. The findings provide insights into the improved dewatering performance and the thermodynamic mechanisms of sludge dewatering with different chemical conditioning.

ENVIRONMENTAL RESEARCH (2023)

Article Green & Sustainable Science & Technology

Comparation of mesophilic and thermophilic anaerobic co-digestion of food waste and waste activated sludge driven by biochar derived from kitchen waste

Rong Zhang, Min Zhang, Huaqian Mou, Zijing An, Hailu Fu, Xiaomei Su, Chongjun Chen, Jianrong Chen, Hongjun Lin, Faqian Sun

Summary: Kitchen waste biochar showed better performance in thermophilic co-digestion, reducing the digestion time and increasing methane production. It also improved the microbial community structure and enhanced the acetoclastic methanogenesis in thermophilic co-digestion.

JOURNAL OF CLEANER PRODUCTION (2023)

Article Chemistry, Physical

Quantifying interfacial interactions for improved membrane antifouling: A novel approach using triangulation and surface element integration method

Xiujia You, Liguo Shen, Ying Zhao, Die Ling Zhao, Jiaheng Teng, Hongjun Lin, Renjie Li, Yanchao Xu, Meijia Zhang

Summary: In order to understand the interfacial behaviors controlling membrane fouling, a new method was proposed to simulate the actual membrane surface morphology and quantify interfacial interactions. This method precisely mimics the real membrane surface in terms of roughness and shape, achieving a precise description of the interactions between sludge foulants and the real membrane surface. Application of this method confirmed the significant antifouling propensity of the modified PVDF-NZPs membrane, which is highly consistent with experimental findings, suggesting the high feasibility and reliability of the proposed method.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

Article Environmental Sciences

Efficient oily wastewater treatment by a novel electroflotation-membrane separation system consisting a Ni-Cu-P membrane prepared by electroless nickel plating

Jing Wang, Binghong Chen, Hongjun Lin, Renjie Li

Summary: Recently, an electroflotation-membrane separation system with a conductive membrane has emerged as a promising technology for oily wastewater treatment. However, the conductive membrane prepared by electroless plating often lacks stability and has high activation cost. To solve these problems, this study proposed a new strategy of surface metallization using surface nickel-catalyzed electroless nickel plating of nickel-copper-phosphorus alloys on polymeric membranes.

SCIENCE OF THE TOTAL ENVIRONMENT (2023)

Article Chemistry, Physical

A Numerical Study of Lossy Multipole Debye Dispersive Media Using a Recursive Integral-FDTD Method

Hongjun Lin, Qilin Wei, Bao Ke, Wenchao Lin, Hualin Zhao, Bingsuo Zou

Summary: By introducing Sb3+ ions into lead-free perovskite derivative (NH4)2SnCl6, the excitation-dependent perovskite with dynamically tunable fluorescence from yellow to near-infrared emission was synthesized for the first time. This study provides guidance for the design of perovskite phosphors with high efficiency and excitation-dependent properties.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2023)

Review Environmental Sciences

Recent advances in application of heterogeneous electro-Fenton catalysts for degrading organic contaminants in water

Wenjing Chen, Danlian Huang, Cui Lai, Yukui Fu, Wenfang Chen, Haoyang Ye, Huan Yi, Bisheng Li, Ling Li, Fanzhi Qin, Hong Qin, Lei Qin

Summary: Advanced oxidation processes (AOPs), especially the heterogeneous electro-Fenton (EF) process, have been widely used for surface and groundwater pollution control. EF process has shown high catalytic performance, no generation of iron sludge, and good recyclability of catalyst. This review focuses on the current studies and applications of heterogeneous catalysts in EF process, with emphasis on the period from 2012 to 2022. The review covers two typical heterogeneous EF systems (solid catalysts and functionalized cathode catalysts) and their applications in organic contaminants degradation in water.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2023)

Article Engineering, Chemical

Comparative analysis of integrating standalone renewable energy sources with brackish water reverse osmosis plants: Technical and economic perspectives

Arvin Sohrabi, Mousa Meratizaman, Shuli Liu

Summary: This paper simulates and discusses possible solutions to improve the economic and technical performances of a battery-less renewable energy-powered BWRO system under real climate conditions. The study finds that the photovoltaic-based system performs better in terms of specific energy consumption and unused energy ratio.

DESALINATION (2024)

Article Engineering, Chemical

An innovative process design of seawater desalination toward hydrogen liquefaction applied to a ship's engine: An economic analysis and intelligent data-driven learning study/optimization

Chunlan Pan, Xiaoyin Hu, Vishal Goyal, Theyab R. Alsenani, Salem Alkhalaf, Tamim Alkhalifah, Fahad Alturise, Hamad Almujibah, H. Elhosiny Ali

Summary: This paper introduces a novel waste heat recovery method using the hot flue gas from a ship's engine to produce liquefied hydrogen while meeting the ship's air-conditioning requirement. A comprehensive feasibility assessment is conducted and an artificial neural network with a multiobjective grey wolf optimization method is used for optimization. The findings indicate the highest mean sensitivity index of the flash temperature and the best optimization scenario for exergy efficiency, CO2 emission reduction, and liquefied hydrogen cost.

DESALINATION (2024)

Article Engineering, Chemical

Selective separation of nitrate from chloride using PVDF-based anion-exchange membranes

Daniele Chinello, Jan Post, Louis C. P. M. de Smet

Summary: In this study, PVDF-based anion-exchange membranes were designed to selectively separate nitrate from chloride. Experimental data showed that increasing the concentration of PVDF enhanced nitrate transport but also increased the membrane electrical resistance. The selectivity of nitrate was found to be independent of the membrane thickness and mainly driven by the increased affinity between the anion and the membrane.

DESALINATION (2024)

Article Engineering, Chemical

Functionalized carbon 1D/2D nanomaterials for effective water desalination: Synthesis, applications and cost issues. An overview

Umar Noor, Muhammad Fayyaz Farid, Ammara Sharif, Amna Saleem, Zubair Nabi, Muhammad Furqan Mughal, Kiran Abbas, Toheed Ahmed

Summary: Global water scarcity is increasing, and water desalination is an important solution. Multifunctional advanced materials, such as membrane materials and solar-driven desalination, play a crucial role in water desalination. Additionally, these materials can be used for water purification, wastewater treatment, and pollutant elimination.

DESALINATION (2024)

Article Engineering, Chemical

sCO2 power cycle/reverse osmosis distillation system for water-electricity cogeneration in nuclear powered ships and submarines

Emrah Gumus

Summary: With growing global concerns about climate change and environmental impacts, the use of nuclear energy in naval vessels offers a cleaner and more efficient solution to reduce emissions and address water and energy supply challenges. This study explores a novel system that combines a nuclear-driven supercritical carbon dioxide power cycle with reverse osmosis cogeneration to meet the water and electricity demands in maritime operations, enhancing the sustainability, efficiency, and self-sufficiency of naval vessels. The results indicate that the system has the potential to be a viable and effective solution for naval operations.

DESALINATION (2024)

Article Engineering, Chemical

Zwitterionic material for construction of an antifouling polyamide thin film composite membrane

Dao Thi Thanh Huyen, Saikat Sinha Ray, Young -Nam Kwon

Summary: This study focuses on the modification of a commercially available polyamide thin-film composite membrane with a zwitterionic material to enhance its fouling resistance. The modified membrane shows improved salt rejection and reduced permeability compared to the pristine membrane. Fouling tests demonstrate that the modified membrane has a lower fouling ratio and higher recovery ratio. The enhanced antifouling characteristics are attributed to the improved hydrophilicity resulting from the zwitterionic brushes and the salting-in effect.

DESALINATION (2024)

Article Engineering, Chemical

Towards pilot scale flow-electrode capacitive deionization

Niklas Koeller, Lukas Mankertz, Selina Finger, Christian J. Linnartz, Matthias Wessling

Summary: This study presents a methodology to scale up Flow-electrode Capacitive Deionization (FCDI) technology from lab-scale to pilot-scale systems. By increasing membrane area and using a stacking approach, the FCDI modules were successfully scaled up and achieved a salt transfer rate comparable to lab-scale systems. This provides a foundation for future assessments of energy demand and economics.

DESALINATION (2024)

Article Engineering, Chemical

Efficient lithium recovery from simulated brine using a hybrid system: Direct contact membrane distillation (DCMD) and electrically switched ion exchange (ESIX)

Mona Gulied, Sifani Zavahir, Tasneem Elmakki, Hyunwoong Park, Guillermo Hijos Gago, Ho Kyong Shon, Dong Suk Han

Summary: This study introduces a novel hybrid system that combines direct contact membrane distillation (DCMD) and electrically switched ion exchange (ESIX) to facilitate seawater reverse osmosis (SWRO) brine enrichment and selective lithium recovery.

DESALINATION (2024)

Article Engineering, Chemical

Enhanced ammonia recovery from strong ammonia wastewater via a transmembrane electro-chemisorption system with authigenic acid and base

Zhiqiang Zhang, Ruifeng Deng, Jiao Zhang, Lu She, Guangfeng Wei, Renyong Jia, Pengyu Xiang, Siqing Xia

Summary: A transmembrane electro-chemisorption system with authigenic acid and base was developed for enhancing ammonia recovery from strong ammonia wastewater. The system efficiently transformed ammonium into free ammonia, which was then adsorbed and recovered through transmembrane chemisorption. This system yielded pure (NH4)2SO4 product and produced valuable byproducts of pure hydrogen and oxygen. Higher applied voltage resulted in better ammonia recovery.

DESALINATION (2024)

Article Engineering, Chemical

Development of high-integrity reverse osmosis membranes for enhanced removal of microorganisms

Alena Popova, Sandrine Boivin, Takuji Shintani, Takahiro Fujioka

Summary: This study aimed to produce a high-integrity RO membrane by forming a polyamide skin layer on a TE support layer, in order to enhance the integrity of the membrane and improve the microbiological safety of potable water reuse.

DESALINATION (2024)

Article Engineering, Chemical

Reducing the specific energy use of seawater desalination with thermally enhanced reverse osmosis

Sanjana Yagnambhatt, Saber Khanmohammadi, Jonathan Maisonneuve

Summary: This study investigates the concept of using heat to enhance reverse osmosis (RO) desalination. The effect of temperature on water permeate flux, specific energy, permeate quality, and applied operating pressures is evaluated using an analytical model. The results suggest that under specific conditions, the tradeoff between savings in mechanical pump work and thermal energy input in thermally-enhanced RO can be favorable, leading to overall energy savings.

DESALINATION (2024)

Article Engineering, Chemical

Selective membrane capacitive deionization for superior lithium recovery

Jiangju Si, Chenrui Xue, Shun Li, Linchao Yang, Weiwei Li, Jie Yang, Jihong Lan, Ningbo Sun

Summary: To meet the huge demand for lithium resources, there is an urgent need to develop a new efficient technology for lithium recovery from salt-lake brines. In this study, a selective membrane capacitive deionization system is reported, which achieves high lithium recovery capacity and rate through the use of materials with efficient intercalated pseudo-capacitance and a high specific area porous carbon. The use of a modified thin-coated membrane allows for selective Li+ recovery, and adjusting the concentrations of Li+ and Mg2+ in the feed solution enables higher Li+/Mg2+ selectivity.

DESALINATION (2024)

Article Engineering, Chemical

Augmentation of solar still distillation performance using waste heat energy and guiding vanes: A field study

Mohamed R. Salem, R. Y. Sakr, Ghazy M. R. Assassa, Omar A. Aly

Summary: This research proposes a new method of using wasted thermal energies as an additional heating source for solar still distillation units (SSDUs) to increase productivity and reduce pollution and global warming. By testing two SSDUs, the study shows that heating airflow can raise temperatures, enhance freshwater production, and improve system thermal efficiency.

DESALINATION (2024)

Article Engineering, Chemical

Novel fabric-based 3D photothermal evaporator with advanced light-harvesting and thermal management design

Qimeng Sun, Miao Sun, Linyan Yang, Yuan Gao, Xinghai Zhou, Lihua Lyu, Chunyan Wei

Summary: This study presents an innovative design and fabrication of a fabric-based conical roll (FCR) evaporator, which enables low-temperature evaporation and achieves high evaporation efficiency with excellent thermal management ability. The evaporator has demonstrated advanced light-harvesting capability and can produce freshwater that meets drinking water standards, showing great potential for applications in desalination and sewage treatment.

DESALINATION (2024)

Article Engineering, Chemical

A dual-functional lignin containing pulp foam for solar evaporation and contaminant adsorption

Yidong Zhang, Wangfang Deng, Meiyan Wu, Chao Liu, Guang Yu, Qiu Cui, Pedram Fatehi, Chunlin Xu, Bin Li

Summary: In this study, a novel polydopamine-functionalized lignin-containing pulp foam evaporator with high-efficiency desalination and multi-contaminant adsorption capabilities was designed. The foam evaporator showed excellent light absorption, water absorption, thermal conductivity, and chelation abilities, allowing for solar evaporation and contaminant adsorption synergistically. It also exhibited potential applications in metal ion concentration and contaminated seawater treatments, and demonstrated superior biodegradability compared to poly-styrene foam. This foam material holds promise for developing multifunctional photo-thermal systems for solar-driven water purification.

DESALINATION (2024)