Review
Chemistry, Multidisciplinary
Mohammed Benjelloun, Youssef Miyah, Gulsun Akdemir Evrendilek, Farid Zerrouq, Sanae Lairini
Summary: The increased environmental awareness and tighter regulatory standards have led various industries to seek appropriate wastewater treatment technologies for colored wastewater. This review provides detailed information on dyes, their classification, the environmental impact of water pollution, and the use of adsorption technology as a sustainable solution for dye removal. Studies evaluating the effectiveness of different adsorbents, particularly low-cost ones, in removing dyes from aqueous solutions are highlighted.
ARABIAN JOURNAL OF CHEMISTRY
(2021)
Article
Engineering, Environmental
Ali Akbari, Elham Akbari, Amirreza Azadmehr, Ardeshir Hezarkhani
Summary: The study successfully prevented the production of acidic effluent by preparing Pyrite@Silica on the surface of natural pyrite, showing significant adsorption capacity. Under optimal conditions, the adsorption capacities for the dyes were 349 mg g(-1) and 97 mg g(-1), respectively.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Environmental Sciences
Adnan Adnan, Muhammad Omer, Behramand Khan, Inkisar Khan, Muhammad Alamzeb, Farah Muhammad Zada, Ihsan Ullah, Rahim Shah, Mohammed Alqarni, Jesus Simal-Gandara
Summary: This study successfully synthesized cost-effective carbonized pistachio shell magnetic nanoparticles with fine particles and a large surface area. These nanoparticles showed excellent adsorption efficiency as adsorbents for the removal of Metanil Yellow dye. The study demonstrates that these nanoparticles can be used as a special adsorbent for the removal of dye pollutants in wastewater.
Article
Environmental Sciences
Ali Riza Kul, Huelya Koyuncu, Aysenur Turan, Adnan Aldemir
Summary: In this study, AC obtained from apple peel was used to remove NR from aqueous solutions. The AC was characterized using BET, FTIR, XRD, and SEM/EDX analyses. Isotherm, kinetic, and thermodynamic parameters were determined and the Langmuir isotherm and PSO kinetic models showed the best fit to the experimental data. The removal percentage of NR dye reached up to 87.20% at 318 K. The research demonstrated the effectiveness of biomass-derived AC for wastewater treatment through adsorption technique.
WATER AIR AND SOIL POLLUTION
(2023)
Article
Environmental Sciences
A. Aldemir, A. Turan, A. R. Kul, H. Koyuncu
Summary: In this study, the performance of pinecone sawdust (PCS) as an adsorbent for Basic Red 46 (BR 46) dye removal was investigated. PCS exhibited effective adsorption capacity for BR 46 dye under alkaline conditions. The adsorption process was found to be spontaneous and favorable.
INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY
(2023)
Article
Chemistry, Physical
Ahmed Shahat, Khadiza Tul Kubra, Adel El-marghany
Summary: A high-potential nanoadsorbent was synthesized and characterized for its efficiency in adsorbing triclosan (TCS) from aqueous solutions. The adsorption equilibrium was found to be influenced by the pH of the solution. The adsorption process followed a chemisorption technique, as evidenced by fitting the adsorption isotherm models to a Langmuir model. The synthesized MCNS adsorbent showed remarkable reusability and renderability, making it suitable for water filtration and industrial wastewater treatment.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Engineering, Environmental
Hai Nguyen Tran, Eder C. Lima, Ruey-Shin Juang, Jean-Claude Bollinger, Huan-Ping Chao
Summary: The study investigated the effects of different adsorption isotherm models on thermodynamic parameters, indicating the importance of selecting the appropriate model, unit, and equilibrium constant for calculating thermodynamic parameters. Using commercial activated carbon to adsorb methylene green dye, the study compared various models and found that certain equilibrium constants were more suitable for calculating thermodynamic parameters.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Chemistry, Physical
Tariq A. Altalhi, Mohamed M. Ibrahim, Gaber A. M. Mersal, M. H. H. Mahmoud, Tushar Kumeria, Mohamed G. El-Desouky, Ashraf A. El-Bindary, Mohamed A. El-Bindary
Summary: In this study, mango seeds activated carbon (MSAC) nanoparticles were prepared with high biocompatibility for potential use as drug carriers. The experimental results showed that the nanocomposite significantly enhanced the adsorption performance of the anti-cancer drug DOX, indicating its potential in drug delivery applications.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Polymer Science
Amina Abbaz, Sihem Arris, Gianluca Viscusi, Asma Ayat, Halima Aissaoui, Yasser Boumezough
Summary: Water pollution is a pressing issue that requires immediate attention. This study developed hydrogel beads made from sodium alginate and pomegranate fruit peels for the purpose of adsorbing Safranin O dye in aqueous solutions. The results showed that the synthesized beads had favorable adsorption properties, with maximum adsorption capacity reaching 30.769 mg/g at 293 K. The study also provided insights into the adsorption kinetics, concentration dependence, and thermodynamics of the dye adsorption process.
Article
Chemistry, Physical
Qing Ye, Gongming Qian, Lulu Liu, Fu Yang, Wei Liu
Summary: Hydroxyapatite (HAP) has excellent adsorption ability for Fe(III) and can effectively hinder the migration of Fe(III) under certain conditions. The transformation efficiency of Fe(III) is significantly influenced by the initial pH value and reaction temperature, and the adsorption kinetics of Fe(III) on HAP follows a pseudo second order kinetic model.
Article
Materials Science, Textiles
Bin Tang, Xi Lu, Jinfeng Wang, Hao Yu, Yanchao Zhu, Steven E. Atkinson, Xungai Wang
Summary: The gas adsorption properties of key natural fibers, wool and cotton, were investigated through time-resolved infrared spectroscopy monitoring the adsorption process of ammonia. The Langmuir isotherm model best described the adsorption process, with monolayer adsorption onto the fibers. The study also found differences in adsorption capacity and activation energy values between wool and cotton.
JOURNAL OF THE TEXTILE INSTITUTE
(2021)
Article
Engineering, Chemical
Murali Pujari, P. Rohinikumar, Sudharshan Reddy Manyam, Adarsh Kumar Arya
Summary: The effectiveness of low-cost fly ash geopolymer adsorbents synthesized from biomass fly ash in lead removal from aqueous solution was studied. The results showed that the synthesized adsorbent had high removal efficiency and uptake, and could be applied under different operating conditions.
CHEMICAL ENGINEERING & TECHNOLOGY
(2023)
Article
Chemistry, Physical
Mohammad Saood Manzar, Gulraiz Khan, Pollyanna Vanessa dos Santos Lins, Mukarram Zubair, Saif Ullah Khan, Rangabhashiyam Selvasembian, Lucas Meili, Nawaf Blaisi, Muhammad Nawaz, Hamidi Abdul Aziz, T. S. Kayed
Summary: Waste from the steel industries can be disposed of in landfills or used in construction and soil improvement, while also serving as adsorbents for water pollutants. By studying Alrhaji (AL) and Arab (AR) materials, it was found that they exhibit promising performance in removing Eriochrome Black T dye, with high adsorption values compared to other reported adsorbents.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Polymer Science
Arej S. Al-Gorair, Asmaa Sayed, Ghada A. Mahmoud
Summary: Cellulose nanocrystals (CNCs) were produced from pea peels and used to form a nanocomposite with pectin and acrylic acid (AAc). The nanocomposite showed improved adsorption and swelling properties, making it suitable for wastewater treatment.
Article
Biochemistry & Molecular Biology
Hemant Mittal, Ali Al Alili, Pranay P. Morajkar, Saeed M. Alhassan
Summary: The study synthesized graphene oxide crosslinked nanocomposites hydrogels of chitosan and carboxymethyl cellulose as versatile adsorbents for both cationic and anionic dyes contaminated wastewater. The adsorption process was well explained using pseudo-second-order and Langmuir models, with excellent regeneration capacity demonstrated for continuous cycles of adsorption-desorption. The synthesized CS/CMC-NCH showed great potential for effective treatment of dye-contaminated wastewater.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2021)
Article
Engineering, Chemical
Arvin Sohrabi, Mousa Meratizaman, Shuli Liu
Summary: This paper simulates and discusses possible solutions to improve the economic and technical performances of a battery-less renewable energy-powered BWRO system under real climate conditions. The study finds that the photovoltaic-based system performs better in terms of specific energy consumption and unused energy ratio.
Article
Engineering, Chemical
Chunlan Pan, Xiaoyin Hu, Vishal Goyal, Theyab R. Alsenani, Salem Alkhalaf, Tamim Alkhalifah, Fahad Alturise, Hamad Almujibah, H. Elhosiny Ali
Summary: This paper introduces a novel waste heat recovery method using the hot flue gas from a ship's engine to produce liquefied hydrogen while meeting the ship's air-conditioning requirement. A comprehensive feasibility assessment is conducted and an artificial neural network with a multiobjective grey wolf optimization method is used for optimization. The findings indicate the highest mean sensitivity index of the flash temperature and the best optimization scenario for exergy efficiency, CO2 emission reduction, and liquefied hydrogen cost.
Article
Engineering, Chemical
Daniele Chinello, Jan Post, Louis C. P. M. de Smet
Summary: In this study, PVDF-based anion-exchange membranes were designed to selectively separate nitrate from chloride. Experimental data showed that increasing the concentration of PVDF enhanced nitrate transport but also increased the membrane electrical resistance. The selectivity of nitrate was found to be independent of the membrane thickness and mainly driven by the increased affinity between the anion and the membrane.
Article
Engineering, Chemical
Umar Noor, Muhammad Fayyaz Farid, Ammara Sharif, Amna Saleem, Zubair Nabi, Muhammad Furqan Mughal, Kiran Abbas, Toheed Ahmed
Summary: Global water scarcity is increasing, and water desalination is an important solution. Multifunctional advanced materials, such as membrane materials and solar-driven desalination, play a crucial role in water desalination. Additionally, these materials can be used for water purification, wastewater treatment, and pollutant elimination.
Article
Engineering, Chemical
Emrah Gumus
Summary: With growing global concerns about climate change and environmental impacts, the use of nuclear energy in naval vessels offers a cleaner and more efficient solution to reduce emissions and address water and energy supply challenges. This study explores a novel system that combines a nuclear-driven supercritical carbon dioxide power cycle with reverse osmosis cogeneration to meet the water and electricity demands in maritime operations, enhancing the sustainability, efficiency, and self-sufficiency of naval vessels. The results indicate that the system has the potential to be a viable and effective solution for naval operations.
Article
Engineering, Chemical
Dao Thi Thanh Huyen, Saikat Sinha Ray, Young -Nam Kwon
Summary: This study focuses on the modification of a commercially available polyamide thin-film composite membrane with a zwitterionic material to enhance its fouling resistance. The modified membrane shows improved salt rejection and reduced permeability compared to the pristine membrane. Fouling tests demonstrate that the modified membrane has a lower fouling ratio and higher recovery ratio. The enhanced antifouling characteristics are attributed to the improved hydrophilicity resulting from the zwitterionic brushes and the salting-in effect.
Article
Engineering, Chemical
Niklas Koeller, Lukas Mankertz, Selina Finger, Christian J. Linnartz, Matthias Wessling
Summary: This study presents a methodology to scale up Flow-electrode Capacitive Deionization (FCDI) technology from lab-scale to pilot-scale systems. By increasing membrane area and using a stacking approach, the FCDI modules were successfully scaled up and achieved a salt transfer rate comparable to lab-scale systems. This provides a foundation for future assessments of energy demand and economics.
Article
Engineering, Chemical
Mona Gulied, Sifani Zavahir, Tasneem Elmakki, Hyunwoong Park, Guillermo Hijos Gago, Ho Kyong Shon, Dong Suk Han
Summary: This study introduces a novel hybrid system that combines direct contact membrane distillation (DCMD) and electrically switched ion exchange (ESIX) to facilitate seawater reverse osmosis (SWRO) brine enrichment and selective lithium recovery.
Article
Engineering, Chemical
Zhiqiang Zhang, Ruifeng Deng, Jiao Zhang, Lu She, Guangfeng Wei, Renyong Jia, Pengyu Xiang, Siqing Xia
Summary: A transmembrane electro-chemisorption system with authigenic acid and base was developed for enhancing ammonia recovery from strong ammonia wastewater. The system efficiently transformed ammonium into free ammonia, which was then adsorbed and recovered through transmembrane chemisorption. This system yielded pure (NH4)2SO4 product and produced valuable byproducts of pure hydrogen and oxygen. Higher applied voltage resulted in better ammonia recovery.
Article
Engineering, Chemical
Alena Popova, Sandrine Boivin, Takuji Shintani, Takahiro Fujioka
Summary: This study aimed to produce a high-integrity RO membrane by forming a polyamide skin layer on a TE support layer, in order to enhance the integrity of the membrane and improve the microbiological safety of potable water reuse.
Article
Engineering, Chemical
Sanjana Yagnambhatt, Saber Khanmohammadi, Jonathan Maisonneuve
Summary: This study investigates the concept of using heat to enhance reverse osmosis (RO) desalination. The effect of temperature on water permeate flux, specific energy, permeate quality, and applied operating pressures is evaluated using an analytical model. The results suggest that under specific conditions, the tradeoff between savings in mechanical pump work and thermal energy input in thermally-enhanced RO can be favorable, leading to overall energy savings.
Article
Engineering, Chemical
Jiangju Si, Chenrui Xue, Shun Li, Linchao Yang, Weiwei Li, Jie Yang, Jihong Lan, Ningbo Sun
Summary: To meet the huge demand for lithium resources, there is an urgent need to develop a new efficient technology for lithium recovery from salt-lake brines. In this study, a selective membrane capacitive deionization system is reported, which achieves high lithium recovery capacity and rate through the use of materials with efficient intercalated pseudo-capacitance and a high specific area porous carbon. The use of a modified thin-coated membrane allows for selective Li+ recovery, and adjusting the concentrations of Li+ and Mg2+ in the feed solution enables higher Li+/Mg2+ selectivity.
Article
Engineering, Chemical
Mohamed R. Salem, R. Y. Sakr, Ghazy M. R. Assassa, Omar A. Aly
Summary: This research proposes a new method of using wasted thermal energies as an additional heating source for solar still distillation units (SSDUs) to increase productivity and reduce pollution and global warming. By testing two SSDUs, the study shows that heating airflow can raise temperatures, enhance freshwater production, and improve system thermal efficiency.
Article
Engineering, Chemical
Qimeng Sun, Miao Sun, Linyan Yang, Yuan Gao, Xinghai Zhou, Lihua Lyu, Chunyan Wei
Summary: This study presents an innovative design and fabrication of a fabric-based conical roll (FCR) evaporator, which enables low-temperature evaporation and achieves high evaporation efficiency with excellent thermal management ability. The evaporator has demonstrated advanced light-harvesting capability and can produce freshwater that meets drinking water standards, showing great potential for applications in desalination and sewage treatment.
Article
Engineering, Chemical
Yidong Zhang, Wangfang Deng, Meiyan Wu, Chao Liu, Guang Yu, Qiu Cui, Pedram Fatehi, Chunlin Xu, Bin Li
Summary: In this study, a novel polydopamine-functionalized lignin-containing pulp foam evaporator with high-efficiency desalination and multi-contaminant adsorption capabilities was designed. The foam evaporator showed excellent light absorption, water absorption, thermal conductivity, and chelation abilities, allowing for solar evaporation and contaminant adsorption synergistically. It also exhibited potential applications in metal ion concentration and contaminated seawater treatments, and demonstrated superior biodegradability compared to poly-styrene foam. This foam material holds promise for developing multifunctional photo-thermal systems for solar-driven water purification.