Article
Polymer Science
Tong Hoang Lin, Phan Thi Danh Toai, Ninh Thi Tinh, La Nam Phat, Le Minh Huong, Nguyen Duc Viet, Nguyen Minh Dat, Hoang Minh Nam, Mai Thanh Phong, Nguyen Huu Hieu
Summary: In this study, PDMS/TEOS hybrid materials with different TEOS ratios were synthesized and ceramic tube-supported membranes were fabricated. The results showed that the ceramic tube-supported PDMS/TEOS membranes exhibited good hydrophobicity and excellent thermal stability, and achieved high performance in the separation of furfural-water mixture by pervaporation.
JOURNAL OF APPLIED POLYMER SCIENCE
(2022)
Article
Engineering, Chemical
Qin Wu, Yan Sun, Wei Wang, Shuyao Tian, Mengjie Ouyang, Kangcheng Chen, Daxin Shi, Yaoyuan Zhang, Hansheng Li, Zhiping Zhao
Summary: A series of multiblock polydimethylsiloxane-b-polyimides copolymers were successfully prepared and their physicochemical properties, pervaporation properties, and thermal stability were studied. The results showed that the mechanical properties and swelling behavior of the membranes varied with different compositions of the copolymers.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Engineering, Chemical
Hee Min Park, Jun Yeong Lee, Ki Yong Jee, Shin-ichi Nakao, Yong Taek Lee
Summary: In this study, a silica membrane was prepared on a commercially available porous alumina support using CVD, and its selectivity for various hydrocarbons was evaluated. By extending the deposition time, the selectivity of the membrane was significantly improved.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Chemistry, Multidisciplinary
I. L. Borisov, E. A. Grushevenko, T. S. Anokhina, D. S. Bakhtin, I. S. Levin, G. N. Bondarenko, V. V. Volkov, A. V. Volkov
Summary: The physicochemical properties of comb-like polysiloxanes with different types of side-chain substituents were systematically investigated, revealing the impact on microphase assembly and hydrocarbon transport properties. The presence of side-chain microphase in polymers was found to significantly enhance the selectivity in hydrocarbon separation processes.
MATERIALS TODAY CHEMISTRY
(2021)
Article
Engineering, Environmental
Xueling Wang, Kuo Sun, Guoquan Zhang, Fenglin Yang, Shihong Lin, Yingchao Dong
Summary: The study reports a novel method of efficiently separating oil nano-emulsions using zirconia membranes with sub-100 nm pores and superoleophobic properties. The membrane fouling behavior is dominated by a combined model of intermediate pore blocking and cake filtration, with effective mitigation under high pH conditions. Overall, the zirconia membrane demonstrates high rejection efficiency for nano-sized oil droplets and consistent separation performance for real oily wastewaters.
Article
Thermodynamics
Hongming Fu, Kaili Xue, Zhaohao Li, Heng Zhang, Dan Gao, Haiping Chen
Summary: This paper investigates the differences in CO2 capture performance between ceramic and PTFE membranes and finds that ceramic membranes exhibit favorable CO2 capture performance under appropriate operating parameters.
Article
Environmental Sciences
Marat Nueraji, Zhexenbek Toktarbay, Aida Ardakkyzy, Deepak Sridhar, Hassan Algadi, Ben Bin Xu, Jalal T. Althakafy, Abdullah K. Alanazi, Hala M. Abo-Dief, Salimgerey Adilov, Zhanhu Guo
Summary: Mechanically-robust nanocomposite membranes for oil and water separation were developed through crosslinking chemistry and electro-spinning technique. The dispersed phase materials with high Young's modulus, such as graphene and multiwalled carbon nanotubes, were selected to enhance the stiffness of the membranes. Chemical modification and induced roughness of the dispersed phase materials were critical for achieving superhydrophobicity. Surface analytic tools were used to characterize the membranes, and AFM-based nanoindentation and TGA/DSC techniques were employed for stiffness measurement and confirmation of composition and formation, respectively. These membranes showed excellent oil/water separation and have potential application in water purification and remediation.
ENVIRONMENTAL RESEARCH
(2023)
Article
Chemistry, Physical
Hao Yang, Yi Wang, Shang Fang, Gang Wang, Lijing Zhu, Zhixiang Zeng, Linghui Wang
Summary: A simple and low-cost nanocasting/NIPS strategy was reported for the preparation of superhydrophobic and underwater oleophobic Janus membrane, which showed excellent separation performance for both O/W and W/O emulsions.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2021)
Article
Chemistry, Physical
Yingnan Ma, Na Liu, Shaohua Tang, Xingyan He, Jiachen Chu, Lelin Zeng, Panliang Zhang, Kewen Tang
Summary: A novel thin film nanocomposite (TFN) membrane consisting of polyetherimide (PEI) and metal-organic framework (MOFs) was developed for efficient CO2 separation. The MOFs in the TFN membrane increased the diffusion coefficient and selectivity for CO2, while the ultra-thin functional layer minimized the CO2 transport resistance. The PEI@MOFs TFN membranes exhibited high CO2 permeance and enhanced CO2 separation performance close to the Robeson upper bound, and also showed good thermal and operation stability.
APPLIED SURFACE SCIENCE
(2023)
Article
Engineering, Chemical
Xinsheng Luo, Chuyang Y. Tang, Xuewu Zhu, Daliang Xu, Jiajian Xing, Dachao Lin, Yatao Liu, Liu Yang, Jialin Song, Zhendong Gan, Guibai Li, Heng Liang
Summary: Hierarchical isoporous alumina ceramic membranes (IAMs) were prepared through self-assembly of polystyrene-b-polyethylene oxide (PS-b-PEO) block copolymer, allowing for control over pore size and increased water permeability. The practicality and versatility of this method pave the way for high-performance isoporous ceramic membranes fabrication.
JOURNAL OF MEMBRANE SCIENCE
(2021)
Article
Chemistry, Applied
Juanjuan Wen, Minghui Qiu, Xianfu Chen, Xiaowei Da, Yiqun Fan
Summary: A co-sintering technique is used to fabricate ZrO2 dual-layer ceramic mesoporous membranes with high separation precision and water permeance. The thickness of the sublayer can be controlled to adjust the permeance, and co-sintering reduces the fabrication cost and time. Additionally, the membrane has a high rejection rate towards SiO2 nanoparticles.
MICROPOROUS AND MESOPOROUS MATERIALS
(2022)
Article
Materials Science, Ceramics
Yusuf Olabode Raji, Mohd Hafiz Dzarfan Othman, Nik Abdul Hadi Sapiaa Md Nordin, Mohd Ridhwan Adam, Khairul Anwar Mohd Said, Ahmed Fauzi Ismail, Mukhlis A. Rahman, Juhana Jaafar, Twibi Mohamed Farag, Sabeer Abdulhamid Alftessi
Summary: The study fabricated a superoleophobic membrane surface using the sol-gel technique, effectively addressing the challenges in oily wastewater treatment. By examining the effects of coating cycles on surface structure and chemical properties, the research achieved efficient oil-water separation results.
CERAMICS INTERNATIONAL
(2021)
Article
Engineering, Environmental
Pedro H. Presumido, Lucrecio F. dos Santos, Teresa Neuparth, Miguel M. Santos, Manuel Feliciano, Ana Primo, Hermenegildo Garcia, Maja B-Dolic, Vitor J. P. Vilar
Summary: This study demonstrated the successful removal of contaminants of emerging concern using a ceramic tubular membrane coated with graphene-TiO2 nanocomposite thin-film in a single-pass flow-through operation. Membranes coated with different methods showed higher removal efficiency under UVA light irradiation. The membranes were characterized and evaluated for their properties and contaminant removal performance using various techniques.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Yuxin Yang, Xinzhong Li, Xiao Liang, Ruirun Chen, Jingjie Guo, Hengzhi Fu, Dongmei Liu
Summary: Thin Pd membranes with a thickness of about 2 μm were prepared by a two-step electroless plating method on porous ceramic supports. The membranes exhibited stable and high hydrogen permeation flux and selectivity under different operating conditions. The effect of gas mixtures on the hydrogen permeation flux was studied, and the membranes also showed good resistance to attrition.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Engineering, Environmental
Huihui Deng, Jing Huang, Cunqi Qin, Tianhui Xu, Huagang Ni, Peng Ye
Summary: Graphene-based membranes, especially the composite membrane of hydroxylated graphene (GOH) and graphene oxide (GO), exhibit high water permeability and effective molecule retention, making them suitable for separation applications.
JOURNAL OF WATER PROCESS ENGINEERING
(2021)
Article
Energy & Fuels
S. Jamshidi, A. A. Babaluo
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION
(2020)
Article
Chemistry, Physical
Davood Tahmasbi, Siamak Hossainpour, Ali Akbar Babaluo, Mashallah Rezakazemi, Seyyed Sajad Mousavi Nejad Souq, Mohammad Younas
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2020)
Article
Materials Science, Characterization & Testing
H. Rostami, F. Abbasi, K. Jalili, E. Mehravar, M. Najafpour
Summary: Core-shell particles were synthesized using seeded suspension polymerization, with a structure consisting of a core-inner shell-outer shell. The size and concentration of PMMA domains decreased from the outer shell towards the core, with particle morphology mainly controlled by the diffusion of MMA through the polymer particle.
POLYMERS & POLYMER COMPOSITES
(2021)
Article
Engineering, Chemical
Mahdi Elyasi Kojabad, AliAkbar Babaluo, Akram Tavakoli
Summary: The addition of aniline molecules as carriers in facilitated transport membranes can greatly improve CO2 separation performance by enhancing permeability and selectivity simultaneously. This innovative approach surpasses the Robeson upper bound line, leading to high-performance industrial membranes.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Energy & Fuels
Roghayeh Ebadi, Hafez Maghsoudi, Ali Akbar Babaluo
Summary: This study investigates the performance of polymeric membranes in CO2 separation from CH4 by using mixed matrix membrane (MMMs) technology, analyzing the distribution of fillers, structural characteristics, and interaction between fillers and polymers. Compared to neat polymeric membranes, MMMs show significant improvements in CO2 permeability and CO2/CH4 ideal selectivity.
JOURNAL OF NATURAL GAS SCIENCE AND ENGINEERING
(2021)
Article
Engineering, Environmental
Mahdi Elyasi Kojabad, AliAkbar Babaluo, Akram Tavakoli, Haniyeh Golizadeh Kahnamouei
Summary: The study prepared facilitated transport membranes (FTMs) with aniline and ionic liquid modified alumina (M-Al) particles, achieving improved CO2 permeability and selectivity. The presence of water enhanced the performance of the membranes by facilitating the transport mechanism. Molecular simulation and experiments confirmed the effectiveness of the combined hopping-vehicle mechanism in the membrane structure.
PROCESS SAFETY AND ENVIRONMENTAL PROTECTION
(2021)
Article
Engineering, Electrical & Electronic
Samira Vafaei, Mohammad Hossein Hekmatshoar, Farhang Abbasi
Summary: In this study, the optical, morphological, and photovoltaic properties of CH3NH3PbI3 perovskite solar cells were investigated by embedding multi-walled carbon nanotubes grafted with poly(3-dodecylthiophene) (MWCNT-g-PDDT) and pure MWCNT into the active layer. It was found that the addition of 0.01% MWCNT-g-PDDT improved the photoresponse of the perovskite structure in the wavelength range of 400-800 nm. Field emission scanning electron microscopy revealed that the addition of 0.01% MWCNT-g-PDDT reduced pin-holes and empty spaces, while enhancing the J(sc) and PCE through a reduction in series resistance and improved charge transfer.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2022)
Article
Polymer Science
Sina Hajibabazadeh, Hakimeh Ghaleh, Farhang Abbasi, Kamran Foroutani
Summary: The objective of this study was to fabricate cell sheets using a newly designed thermo-responsive polymer. Thermo-responsive diblock copolymers of PNIPAM-bPS with different ratios were synthesized and characterized. The PNIPAM-b-PS coatings showed a temperature-triggered phase transition in water due to the reversible hydration of PNIPAM segments. Human dermal fibroblasts were able to adhere to and detach from the coatings by adjusting the ratio of PNIPAM to PS segments.
EUROPEAN POLYMER JOURNAL
(2023)
Article
Engineering, Electrical & Electronic
Samira Vafaei, Mohammad Hossein Hekmatshoar, Farhang Abbasi
Summary: In this study, the effects of adding MWCNT-g-PDDT and pure MWCNT in the perovskite active layer were investigated. The addition of MWCNT-g-PDDT led to a smooth and dense surface, increased photo-response, and improved photovoltaic performance. The modified devices showed reduced charge transfer resistance and compact surface, resulting in improved photovoltaic parameters.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2023)
Article
Chemistry, Multidisciplinary
Aliyeh Ghamkhari, Hossein Ahmadi Tafti, Shahram Rabbani, Marjan Ghorbani, Mohammad Adel Ghiass, Fariborz Akbarzadeh, Farhang Abbasi
Summary: Myocardial infarction (MI) is a major cardiovascular disease that causes extensive cell death. The development of ultrasound-mediated microbubble destruction has led to increased interest in MI therapeutics, targeted drug delivery, and biomedical imaging. This study describes a novel ultrasound system for delivering microstructures containing bFGF to the MI region.
Article
Thermodynamics
Zahra Khoubi-Arani, Mina Alizadehaghdam, Farhang Abbasi
Summary: Melting point depression is a common method for determining equilibrium heat of fusion (& UDelta; H0m) and interaction parameter (& chi;) in polymer-diluent systems. Using melting temperatures of dried crystals from polymers with different dilution levels (dry melting temperature, DMT) helps to reduce errors caused by using non-equilibrium temperatures. However, DMT measurement is challenging as it requires specific diluents and increases the number of experiments. The study found that the difference between normal melting temperature (NMT) and DMT depended on the cooling rate (CR) during crystallization.
THERMAL SCIENCE AND ENGINEERING PROGRESS
(2023)
Article
Engineering, Environmental
Mahdi Elyasi Kojabad, AliAkbar Babaluo, Akram Tavakoli, Reza Lotfi Mayan Sofla, Haniyeh Golizadeh Kahnamouei
Summary: The study focused on using acidic and basic ionic liquids to modify gamma-Al2O3 particles for improving the performance and mechanical strength of composite membranes. The acidic IL showed better dispersion effect on particles and enhanced CO2 permeability and CO2/N-2 selectivity in the membranes. Molecular simulations confirmed the experimental results and showed that ILs had different effects on diffusivity and solubility coefficients of CO2 molecules in the membranes.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Engineering, Chemical
P. Mardani, S. Jamshidi, A. A. Babaluo
Summary: A thin dense Pd composite membrane was prepared using electroless plating method, with a model for hydrogen transport and resistance analysis established. The diffusion resistance in the porous support was identified as the main contributor to mass transfer resistance. Adjusting the thickness of the Pd layer and the structure of the alumina support layer can enhance hydrogen gas flux.
THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING
(2021)
Article
Engineering, Multidisciplinary
B. Bayati, C. Algieri, A. A. Babaluo, M. Haghighi, A. Ghorbani, E. Drioli
Article
Engineering, Multidisciplinary
A. Jabbari Gargari, F. Assa, A. A. Babaluo, K. Ghasemzadeh
Article
Engineering, Chemical
Arvin Sohrabi, Mousa Meratizaman, Shuli Liu
Summary: This paper simulates and discusses possible solutions to improve the economic and technical performances of a battery-less renewable energy-powered BWRO system under real climate conditions. The study finds that the photovoltaic-based system performs better in terms of specific energy consumption and unused energy ratio.
Article
Engineering, Chemical
Chunlan Pan, Xiaoyin Hu, Vishal Goyal, Theyab R. Alsenani, Salem Alkhalaf, Tamim Alkhalifah, Fahad Alturise, Hamad Almujibah, H. Elhosiny Ali
Summary: This paper introduces a novel waste heat recovery method using the hot flue gas from a ship's engine to produce liquefied hydrogen while meeting the ship's air-conditioning requirement. A comprehensive feasibility assessment is conducted and an artificial neural network with a multiobjective grey wolf optimization method is used for optimization. The findings indicate the highest mean sensitivity index of the flash temperature and the best optimization scenario for exergy efficiency, CO2 emission reduction, and liquefied hydrogen cost.
Article
Engineering, Chemical
Daniele Chinello, Jan Post, Louis C. P. M. de Smet
Summary: In this study, PVDF-based anion-exchange membranes were designed to selectively separate nitrate from chloride. Experimental data showed that increasing the concentration of PVDF enhanced nitrate transport but also increased the membrane electrical resistance. The selectivity of nitrate was found to be independent of the membrane thickness and mainly driven by the increased affinity between the anion and the membrane.
Article
Engineering, Chemical
Umar Noor, Muhammad Fayyaz Farid, Ammara Sharif, Amna Saleem, Zubair Nabi, Muhammad Furqan Mughal, Kiran Abbas, Toheed Ahmed
Summary: Global water scarcity is increasing, and water desalination is an important solution. Multifunctional advanced materials, such as membrane materials and solar-driven desalination, play a crucial role in water desalination. Additionally, these materials can be used for water purification, wastewater treatment, and pollutant elimination.
Article
Engineering, Chemical
Emrah Gumus
Summary: With growing global concerns about climate change and environmental impacts, the use of nuclear energy in naval vessels offers a cleaner and more efficient solution to reduce emissions and address water and energy supply challenges. This study explores a novel system that combines a nuclear-driven supercritical carbon dioxide power cycle with reverse osmosis cogeneration to meet the water and electricity demands in maritime operations, enhancing the sustainability, efficiency, and self-sufficiency of naval vessels. The results indicate that the system has the potential to be a viable and effective solution for naval operations.
Article
Engineering, Chemical
Dao Thi Thanh Huyen, Saikat Sinha Ray, Young -Nam Kwon
Summary: This study focuses on the modification of a commercially available polyamide thin-film composite membrane with a zwitterionic material to enhance its fouling resistance. The modified membrane shows improved salt rejection and reduced permeability compared to the pristine membrane. Fouling tests demonstrate that the modified membrane has a lower fouling ratio and higher recovery ratio. The enhanced antifouling characteristics are attributed to the improved hydrophilicity resulting from the zwitterionic brushes and the salting-in effect.
Article
Engineering, Chemical
Niklas Koeller, Lukas Mankertz, Selina Finger, Christian J. Linnartz, Matthias Wessling
Summary: This study presents a methodology to scale up Flow-electrode Capacitive Deionization (FCDI) technology from lab-scale to pilot-scale systems. By increasing membrane area and using a stacking approach, the FCDI modules were successfully scaled up and achieved a salt transfer rate comparable to lab-scale systems. This provides a foundation for future assessments of energy demand and economics.
Article
Engineering, Chemical
Mona Gulied, Sifani Zavahir, Tasneem Elmakki, Hyunwoong Park, Guillermo Hijos Gago, Ho Kyong Shon, Dong Suk Han
Summary: This study introduces a novel hybrid system that combines direct contact membrane distillation (DCMD) and electrically switched ion exchange (ESIX) to facilitate seawater reverse osmosis (SWRO) brine enrichment and selective lithium recovery.
Article
Engineering, Chemical
Zhiqiang Zhang, Ruifeng Deng, Jiao Zhang, Lu She, Guangfeng Wei, Renyong Jia, Pengyu Xiang, Siqing Xia
Summary: A transmembrane electro-chemisorption system with authigenic acid and base was developed for enhancing ammonia recovery from strong ammonia wastewater. The system efficiently transformed ammonium into free ammonia, which was then adsorbed and recovered through transmembrane chemisorption. This system yielded pure (NH4)2SO4 product and produced valuable byproducts of pure hydrogen and oxygen. Higher applied voltage resulted in better ammonia recovery.
Article
Engineering, Chemical
Alena Popova, Sandrine Boivin, Takuji Shintani, Takahiro Fujioka
Summary: This study aimed to produce a high-integrity RO membrane by forming a polyamide skin layer on a TE support layer, in order to enhance the integrity of the membrane and improve the microbiological safety of potable water reuse.
Article
Engineering, Chemical
Sanjana Yagnambhatt, Saber Khanmohammadi, Jonathan Maisonneuve
Summary: This study investigates the concept of using heat to enhance reverse osmosis (RO) desalination. The effect of temperature on water permeate flux, specific energy, permeate quality, and applied operating pressures is evaluated using an analytical model. The results suggest that under specific conditions, the tradeoff between savings in mechanical pump work and thermal energy input in thermally-enhanced RO can be favorable, leading to overall energy savings.
Article
Engineering, Chemical
Jiangju Si, Chenrui Xue, Shun Li, Linchao Yang, Weiwei Li, Jie Yang, Jihong Lan, Ningbo Sun
Summary: To meet the huge demand for lithium resources, there is an urgent need to develop a new efficient technology for lithium recovery from salt-lake brines. In this study, a selective membrane capacitive deionization system is reported, which achieves high lithium recovery capacity and rate through the use of materials with efficient intercalated pseudo-capacitance and a high specific area porous carbon. The use of a modified thin-coated membrane allows for selective Li+ recovery, and adjusting the concentrations of Li+ and Mg2+ in the feed solution enables higher Li+/Mg2+ selectivity.
Article
Engineering, Chemical
Mohamed R. Salem, R. Y. Sakr, Ghazy M. R. Assassa, Omar A. Aly
Summary: This research proposes a new method of using wasted thermal energies as an additional heating source for solar still distillation units (SSDUs) to increase productivity and reduce pollution and global warming. By testing two SSDUs, the study shows that heating airflow can raise temperatures, enhance freshwater production, and improve system thermal efficiency.
Article
Engineering, Chemical
Qimeng Sun, Miao Sun, Linyan Yang, Yuan Gao, Xinghai Zhou, Lihua Lyu, Chunyan Wei
Summary: This study presents an innovative design and fabrication of a fabric-based conical roll (FCR) evaporator, which enables low-temperature evaporation and achieves high evaporation efficiency with excellent thermal management ability. The evaporator has demonstrated advanced light-harvesting capability and can produce freshwater that meets drinking water standards, showing great potential for applications in desalination and sewage treatment.
Article
Engineering, Chemical
Yidong Zhang, Wangfang Deng, Meiyan Wu, Chao Liu, Guang Yu, Qiu Cui, Pedram Fatehi, Chunlin Xu, Bin Li
Summary: In this study, a novel polydopamine-functionalized lignin-containing pulp foam evaporator with high-efficiency desalination and multi-contaminant adsorption capabilities was designed. The foam evaporator showed excellent light absorption, water absorption, thermal conductivity, and chelation abilities, allowing for solar evaporation and contaminant adsorption synergistically. It also exhibited potential applications in metal ion concentration and contaminated seawater treatments, and demonstrated superior biodegradability compared to poly-styrene foam. This foam material holds promise for developing multifunctional photo-thermal systems for solar-driven water purification.