4.7 Article

Optimization of an azo dye batch adsorption parameters using Box-Behnken design

期刊

DESALINATION
卷 249, 期 3, 页码 1273-1279

出版社

ELSEVIER
DOI: 10.1016/j.desal.2009.03.010

关键词

Acid orange 52; Dye removal; Adsorption; Response surface methodology; pH effect; Box-Behnken design

向作者/读者索取更多资源

Dye removal using adsorption requires a proper process parametric study to determine its optimal performance characteristics. In this study, response surface methodology was employed for the removal of methyl orange (MO) from aqueous solution using activated carbon-commercial grade (ACC) as an adsorbent. Experiments were carried out as per Box-Behnken surface statistical design with four input parameters namely adsorbent dose (w: 5-20 g/l), contact time (t: 2-6 h), temperature (T: 25-55 degrees C) and pH (pH: 2-8). Initial MO concentration (C-0 = 100 mg/l) was taken as a fixed input parameter. Regression analysis showed good fit of the experimental data to the second-order polynomial model with coefficient of determination (R-2) value of 0.9114 and 10.28. Optimization of w (15.75 g/l), t (4 h), T (40 degrees C) and pH (2) gave a maximum of 99.11% MO removal by ACC. (C) 2009 Published by Elsevier B.V.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Environmental Sciences

Synthesis of Sn-doped ZnO catalysts by solution combustion method for photocatalytic activity: a parametric study

P. R. Potti, V. C. Srivastava, P. Kumar, S. Das, N. Kumar, U. L. Stangar

Summary: This study synthesized Sn-doped ZnO photocatalysts using the solution combustion synthesis method and investigated the effects of different experimental parameters on the properties and degradation efficiency. The results showed that BET surface area and bandgap energy are the key factors influencing the degradation of dyes by Sn-doped ZnO.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY (2023)

Article Polymer Science

Identifying the Point of Attachment in the Hypercrosslinking of Benzene for the Synthesis of a Nanoporous Polymer as a Superior Adsorbent for High-Pressure CO2 Capture Application

Anuj Rawat, Raeesh Muhammad, Vimal Chandra Srivastava, Paritosh Mohanty

Summary: The hypercrosslinking of benzene using formaldehyde dimethyl acetal as the crosslinker, anhydrous ferric chloride as the catalyst, and 1,2 dichloroethane as the solvent for the synthesis of poly-benz is reported. Microwave-assisted synthesis resulted in the formation of nanoporous poly-benz with a specific surface area of 1168 m2 g-1 within 60 minutes. Thorough analysis using NMR and XPS revealed the hypercrosslinking at the meta position of the benzene ring. The synthesized poly-benz showed a high CO2 capture capacity of 65.3 wt % at 298 K and 30 bar, and different adsorption isotherm models were fitted to represent the equilibrium CO2 adsorption data at various temperatures.

MACROMOLECULES (2023)

Article Chemistry, Physical

Efficient Propylene Carbonate Synthesis from Urea and Propylene Glycol over Calcium Oxide-Magnesium Oxide Catalysts

Kavisha Dang, Navneet Kumar, Vimal Chandra Srivastava, Jinsub Park, Mu. Naushad

Summary: A series of CaO-MgO catalysts were prepared using different precipitating agents and Mg/Ca ratios. The physiochemical characteristics of the catalysts were analyzed using various techniques. The catalysts were tested for propylene carbonate synthesis and the effects of composition, dose, temperature, and contact time were investigated. The best catalyst achieved a high PC yield with good selectivity and reusability, showing potential for the synthesis of organic carbonates.

MATERIALS (2023)

Article Green & Sustainable Science & Technology

Synthesis of bio-based materials from agricultural residues for treatment of petrochemical wastewater

Mohammad Nasir, Praveen Kumar, Vimal Chandra Srivastava, Shilpi Verma, Ramanpreet Kaur, Indra Deo Mall, Urska Lavrencic Stangar

Summary: The adsorptive removal of 4-CBA using bagasse fly ash (BFA) was studied and compared with granular activated carbon (GAC). The optimum treatment conditions for BFA were found to be pH = 4, m = 9 g/L, Co = 100 mg/L, and t = 7.5 h, with a removal efficiency of 79% and adsorption uptake of 9.9 mg/g. BFA was determined to be a cost-effective adsorbent with high adsorption capacity and fast kinetics.

CLEAN TECHNOLOGIES AND ENVIRONMENTAL POLICY (2023)

Editorial Material Energy & Fuels

Virtual Special Issue on New Energy Developments at IIT Roorkee, India

Vimal Chandra Srivastava, Hari Prakash Veluswamy, Deepak Kumar Ojha

ENERGY & FUELS (2023)

Article Engineering, Chemical

Production of Dimethyl Carbonate Using a Zirconium-Praseodymium-Based Catalyst from Methanol and Propylene Carbonate: An Experimental and DFT Study

Surbhi Dahiya, Pankaj Kumar, Vimal Chandra Srivastava, Vimal Kumar

Summary: In the presence of specific catalysts made using the coprecipitation approach, methanol and propylene carbonate react to yield dimethyl carbonate and propylene glycol through the transesterification process. The catalytic activity of mixed Zr1-xPrxO2 was investigated towards the formation of DMC and PG, and the catalysts were characterized using SEM, FTIR spectroscopy, and CO2-TPD. DFT calculations were performed to understand the effect of combining praseodymium and zirconium on the yield and selectivity of DMC. Zr0.96Pr0.04O2 showed the highest PC conversion (95.9%), with a yield of 52.5% and selectivity of 54.7% at specific reaction conditions.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2023)

Article Green & Sustainable Science & Technology

Co-pyrolysis of petroleum coke and wood pellet blend: Kinetic and Thermodynamic Evaluation using Thermogravimetric Analysis

Tanveer Rasool, Vimal Chandra Srivastava, Pratik Toshniwal, Ishfaq Najar, Vikash Singh

Summary: This study evaluated the kinetic and thermodynamic parameters of co-pyrolysis of wood pellets and petroleum coke blends. It was found that the reaction order increases with increasing heating rate, and the average activation energy was calculated to be 119.6 kJ mol-1 (OFW) and 126.2 kJ mol-1 (KAS). The values for ΔH, ΔG, and ΔS were consistent with previous studies, and ΔG was observed to be around 182 kJ mol-1. The study also identified the mechanisms of diffusion and chemical reaction during the thermal degradation process.

SUSTAINABLE ENERGY TECHNOLOGIES AND ASSESSMENTS (2023)

Article Materials Science, Multidisciplinary

Ellipsoid-shaped copper oxide as an effective peroxymonosulfate activator for perfluorooctanoic acid decomposition

Seema Singh, Ritesh Patidar, Vimal Chandra Srivastava, Praveen Kumar, Ajay Singh, Shang-Lien Lo

Summary: In this study, ellipsoid-shaped cupric oxide (CuO) nanoparticles were synthesized using a simple hydrothermal method and subsequent heat treatment. The catalysts showed excellent peroxymonosulfate (PMS) activation ability for the degradation of perfluorooctanoic acid (PFOA). Various operating parameters were investigated, and it was found that singlet oxygen (1O2) played a key role in the oxidative-reductive mechanism of PFOA degradation. Additionally, a two-step pseudo-first-order kinetic model was proposed and minimal metal leaching was observed after repeated use.

MATERIALS TODAY COMMUNICATIONS (2023)

Article Green & Sustainable Science & Technology

Adsorptive desulphurization of fuels by hypercrosslinked nanoporous polymers derived from polycyclic aromatic hydrocarbons

Anuj Rawat, Raeesh Muhammad, Raj K. Singh, Pratiksha Rashmi, Pratiksha Joshi, Om P. Khatri, Vimal Chandra Srivastava, Paritosh Mohanty

Summary: A sustainable method using high surface area nanoporous adsorbents synthesized from polycyclic aromatic hydrocarbons (PAHs) effectively removes polycyclic aromatic sulphur heterocycles (PASHs) from fuels. By hypercrosslinking PAHs through a microwave assisted method, nanoporous polymeric materials with high surface area (SABET of 620-1565 m2 g-1) are synthesized. The adsorbent poly-naph (highest SABET, i.e., 1565 m2 g-1) demonstrates excellent desulphurization performance from batch to fixed bed column mode. The adsorption mechanism is attributed to the π-electron density in the polymeric framework and the high surface area. This approach requires technological advancement, financial assistance and governmental regulation to sustain the control of carcinogenic aromatic pollutants.

JOURNAL OF CLEANER PRODUCTION (2023)

Article Green & Sustainable Science & Technology

Investigation of co-combustion characteristics of distillery sludge and sugar mill waste: kinetics, synergy, and ash characterization

Vikash Singh, Seon Yeong Park, Eun Seo Lee, Jun Ho Choi, Chang Gyun Kim, Vimal Chandra Srivastava

Summary: The co-combustion characteristics and synergy of distillery effluent sludge (DES) and sugar mill waste (SMW) were studied by thermogravimetric analysis. The blend of 25% DES and 75% SMW exhibited optimal combustion parameters and the presence of Fe, Ca, and Mg in DES facilitated effective combustion. The ash from the combustion process can be considered as a possible supplementary cementing material.

ENVIRONMENT DEVELOPMENT AND SUSTAINABILITY (2023)

Article Engineering, Environmental

Catalytic oxidation of Bisphenol A with Co3+ rich spinel Co3O4: Performance evaluation with peroxymonosulfate activation and mineralization mechanism

Seema Singh, Praveen Kumar, Ritesh Patidar, Vimal Chandra Srivastava, Shang-Lien Lo, Urska Lavrencic Stangar

Summary: In this study, Co3O4 nanospheres with excellent surface properties were synthesized and used for the degradation of BPA. The nano-Co3O4/PMS system effectively degraded BPA (approximately 92%) at neutral pH with low cobalt leaching and good recyclability. Chemical quenching studies confirmed the involvement of hydroxyl radicals and sulfate radicals in BPA oxidation.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2023)

Article Environmental Sciences

Peroxymonosulfate activation with an α-MnO2/Mn2O3/Mn3O4 hybrid system: parametric optimization and oxidative degradation of organic dye

Seema Singh, Ritesh Patidar, Vimal Chandra Srivastava, Qicheng Qiao, Praveen Kumar, Ajay Singh, Shang-Lien Lo

Summary: This study synthesized low-toxicity and eco-friendly spherically shaped manganese oxides (alpha-MnO2, Mn2O3, and Mn3O4) using the chemical precipitation method. The variable oxidation states and diverse structures of manganese-based materials have a strong impact on electron transfer reactions. The as-prepared manganese oxides (MnOx) exhibited excellent catalytic activity for the degradation of rhodamine B (RhB) organic pollutant in the presence of peroxymonosulfate (PMS) under acidic conditions. The different oxidation states of MnOx promote oxidative-reductive reactions and the higher surface area provides ample absorption sites for pollutant interactions.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2023)

Article Chemistry, Multidisciplinary

Ethane and Propane Dehydrogenation on Small Platinum Clusters Supported on Silica: An Ab Initio Molecular Dynamics and DFT Study

Pankaj Kumar, Vimal Chandra Srivastava

Summary: The size-dependent activity of catalysts has been investigated in catalysis for a long time. Positively charged small Pt clusters exhibit higher catalytic activity compared to larger clusters and bulk for propane dehydrogenation. Computational studies were performed on small Pt clusters adsorbed on silica support, revealing their planar structures and the formation of directional bonds with the support. Ethane and propane molecules undergo dehydrogenation reactions with different activation energies depending on the size of the Pt clusters and the mechanism followed.

CHEMPLUSCHEM (2023)

Review Engineering, Environmental

A critical review on the degradation mechanism of textile effluent during electrocatalytic oxidation: Removal optimization and degradation pathways

Seema Singh, Ritesh Patidar, Vimal Chandra Srivastava, Shang-Lien Lo, P. V. Nidheesh

Summary: This review presents the recent advancements in the electrochemical oxidation (EO) treatment of dyes, including the basic principles, the influence of operating parameters on treatment performance, the advantages and disadvantages of various anode materials, and the degradation mechanisms of dyes. The article also discusses the scale-up application, techno-economic issues, and future research challenges.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2023)

Article Thermodynamics

Comparative assessment of different grades of coal for methanol production: Simulation, optimization, environmental and economic analysis

Shailesh Pandey, Vimal Chandra Srivastava, Vimal Kumar

Summary: This study models and simulates the production of methanol from coal gasification using three coal samples with different ash percentages. The study analyzes the effect of input parameters such as steam-to-coal ratio and gasification temperature on performance parameters and optimizes these parameters for maximum methanol yield and minimum greenhouse gas emissions. Economic investigation reveals that high-ash coal performs better in terms of profitability and production costs. The findings of this study are important for countries with substantial low-grade high-ash coal reserves to achieve sustainable methanol production through coal diversification.

ENERGY (2023)

Article Engineering, Chemical

Comparative analysis of integrating standalone renewable energy sources with brackish water reverse osmosis plants: Technical and economic perspectives

Arvin Sohrabi, Mousa Meratizaman, Shuli Liu

Summary: This paper simulates and discusses possible solutions to improve the economic and technical performances of a battery-less renewable energy-powered BWRO system under real climate conditions. The study finds that the photovoltaic-based system performs better in terms of specific energy consumption and unused energy ratio.

DESALINATION (2024)

Article Engineering, Chemical

An innovative process design of seawater desalination toward hydrogen liquefaction applied to a ship's engine: An economic analysis and intelligent data-driven learning study/optimization

Chunlan Pan, Xiaoyin Hu, Vishal Goyal, Theyab R. Alsenani, Salem Alkhalaf, Tamim Alkhalifah, Fahad Alturise, Hamad Almujibah, H. Elhosiny Ali

Summary: This paper introduces a novel waste heat recovery method using the hot flue gas from a ship's engine to produce liquefied hydrogen while meeting the ship's air-conditioning requirement. A comprehensive feasibility assessment is conducted and an artificial neural network with a multiobjective grey wolf optimization method is used for optimization. The findings indicate the highest mean sensitivity index of the flash temperature and the best optimization scenario for exergy efficiency, CO2 emission reduction, and liquefied hydrogen cost.

DESALINATION (2024)

Article Engineering, Chemical

Selective separation of nitrate from chloride using PVDF-based anion-exchange membranes

Daniele Chinello, Jan Post, Louis C. P. M. de Smet

Summary: In this study, PVDF-based anion-exchange membranes were designed to selectively separate nitrate from chloride. Experimental data showed that increasing the concentration of PVDF enhanced nitrate transport but also increased the membrane electrical resistance. The selectivity of nitrate was found to be independent of the membrane thickness and mainly driven by the increased affinity between the anion and the membrane.

DESALINATION (2024)

Article Engineering, Chemical

Functionalized carbon 1D/2D nanomaterials for effective water desalination: Synthesis, applications and cost issues. An overview

Umar Noor, Muhammad Fayyaz Farid, Ammara Sharif, Amna Saleem, Zubair Nabi, Muhammad Furqan Mughal, Kiran Abbas, Toheed Ahmed

Summary: Global water scarcity is increasing, and water desalination is an important solution. Multifunctional advanced materials, such as membrane materials and solar-driven desalination, play a crucial role in water desalination. Additionally, these materials can be used for water purification, wastewater treatment, and pollutant elimination.

DESALINATION (2024)

Article Engineering, Chemical

sCO2 power cycle/reverse osmosis distillation system for water-electricity cogeneration in nuclear powered ships and submarines

Emrah Gumus

Summary: With growing global concerns about climate change and environmental impacts, the use of nuclear energy in naval vessels offers a cleaner and more efficient solution to reduce emissions and address water and energy supply challenges. This study explores a novel system that combines a nuclear-driven supercritical carbon dioxide power cycle with reverse osmosis cogeneration to meet the water and electricity demands in maritime operations, enhancing the sustainability, efficiency, and self-sufficiency of naval vessels. The results indicate that the system has the potential to be a viable and effective solution for naval operations.

DESALINATION (2024)

Article Engineering, Chemical

Zwitterionic material for construction of an antifouling polyamide thin film composite membrane

Dao Thi Thanh Huyen, Saikat Sinha Ray, Young -Nam Kwon

Summary: This study focuses on the modification of a commercially available polyamide thin-film composite membrane with a zwitterionic material to enhance its fouling resistance. The modified membrane shows improved salt rejection and reduced permeability compared to the pristine membrane. Fouling tests demonstrate that the modified membrane has a lower fouling ratio and higher recovery ratio. The enhanced antifouling characteristics are attributed to the improved hydrophilicity resulting from the zwitterionic brushes and the salting-in effect.

DESALINATION (2024)

Article Engineering, Chemical

Towards pilot scale flow-electrode capacitive deionization

Niklas Koeller, Lukas Mankertz, Selina Finger, Christian J. Linnartz, Matthias Wessling

Summary: This study presents a methodology to scale up Flow-electrode Capacitive Deionization (FCDI) technology from lab-scale to pilot-scale systems. By increasing membrane area and using a stacking approach, the FCDI modules were successfully scaled up and achieved a salt transfer rate comparable to lab-scale systems. This provides a foundation for future assessments of energy demand and economics.

DESALINATION (2024)

Article Engineering, Chemical

Efficient lithium recovery from simulated brine using a hybrid system: Direct contact membrane distillation (DCMD) and electrically switched ion exchange (ESIX)

Mona Gulied, Sifani Zavahir, Tasneem Elmakki, Hyunwoong Park, Guillermo Hijos Gago, Ho Kyong Shon, Dong Suk Han

Summary: This study introduces a novel hybrid system that combines direct contact membrane distillation (DCMD) and electrically switched ion exchange (ESIX) to facilitate seawater reverse osmosis (SWRO) brine enrichment and selective lithium recovery.

DESALINATION (2024)

Article Engineering, Chemical

Enhanced ammonia recovery from strong ammonia wastewater via a transmembrane electro-chemisorption system with authigenic acid and base

Zhiqiang Zhang, Ruifeng Deng, Jiao Zhang, Lu She, Guangfeng Wei, Renyong Jia, Pengyu Xiang, Siqing Xia

Summary: A transmembrane electro-chemisorption system with authigenic acid and base was developed for enhancing ammonia recovery from strong ammonia wastewater. The system efficiently transformed ammonium into free ammonia, which was then adsorbed and recovered through transmembrane chemisorption. This system yielded pure (NH4)2SO4 product and produced valuable byproducts of pure hydrogen and oxygen. Higher applied voltage resulted in better ammonia recovery.

DESALINATION (2024)

Article Engineering, Chemical

Development of high-integrity reverse osmosis membranes for enhanced removal of microorganisms

Alena Popova, Sandrine Boivin, Takuji Shintani, Takahiro Fujioka

Summary: This study aimed to produce a high-integrity RO membrane by forming a polyamide skin layer on a TE support layer, in order to enhance the integrity of the membrane and improve the microbiological safety of potable water reuse.

DESALINATION (2024)

Article Engineering, Chemical

Reducing the specific energy use of seawater desalination with thermally enhanced reverse osmosis

Sanjana Yagnambhatt, Saber Khanmohammadi, Jonathan Maisonneuve

Summary: This study investigates the concept of using heat to enhance reverse osmosis (RO) desalination. The effect of temperature on water permeate flux, specific energy, permeate quality, and applied operating pressures is evaluated using an analytical model. The results suggest that under specific conditions, the tradeoff between savings in mechanical pump work and thermal energy input in thermally-enhanced RO can be favorable, leading to overall energy savings.

DESALINATION (2024)

Article Engineering, Chemical

Selective membrane capacitive deionization for superior lithium recovery

Jiangju Si, Chenrui Xue, Shun Li, Linchao Yang, Weiwei Li, Jie Yang, Jihong Lan, Ningbo Sun

Summary: To meet the huge demand for lithium resources, there is an urgent need to develop a new efficient technology for lithium recovery from salt-lake brines. In this study, a selective membrane capacitive deionization system is reported, which achieves high lithium recovery capacity and rate through the use of materials with efficient intercalated pseudo-capacitance and a high specific area porous carbon. The use of a modified thin-coated membrane allows for selective Li+ recovery, and adjusting the concentrations of Li+ and Mg2+ in the feed solution enables higher Li+/Mg2+ selectivity.

DESALINATION (2024)

Article Engineering, Chemical

Augmentation of solar still distillation performance using waste heat energy and guiding vanes: A field study

Mohamed R. Salem, R. Y. Sakr, Ghazy M. R. Assassa, Omar A. Aly

Summary: This research proposes a new method of using wasted thermal energies as an additional heating source for solar still distillation units (SSDUs) to increase productivity and reduce pollution and global warming. By testing two SSDUs, the study shows that heating airflow can raise temperatures, enhance freshwater production, and improve system thermal efficiency.

DESALINATION (2024)

Article Engineering, Chemical

Novel fabric-based 3D photothermal evaporator with advanced light-harvesting and thermal management design

Qimeng Sun, Miao Sun, Linyan Yang, Yuan Gao, Xinghai Zhou, Lihua Lyu, Chunyan Wei

Summary: This study presents an innovative design and fabrication of a fabric-based conical roll (FCR) evaporator, which enables low-temperature evaporation and achieves high evaporation efficiency with excellent thermal management ability. The evaporator has demonstrated advanced light-harvesting capability and can produce freshwater that meets drinking water standards, showing great potential for applications in desalination and sewage treatment.

DESALINATION (2024)

Article Engineering, Chemical

A dual-functional lignin containing pulp foam for solar evaporation and contaminant adsorption

Yidong Zhang, Wangfang Deng, Meiyan Wu, Chao Liu, Guang Yu, Qiu Cui, Pedram Fatehi, Chunlin Xu, Bin Li

Summary: In this study, a novel polydopamine-functionalized lignin-containing pulp foam evaporator with high-efficiency desalination and multi-contaminant adsorption capabilities was designed. The foam evaporator showed excellent light absorption, water absorption, thermal conductivity, and chelation abilities, allowing for solar evaporation and contaminant adsorption synergistically. It also exhibited potential applications in metal ion concentration and contaminated seawater treatments, and demonstrated superior biodegradability compared to poly-styrene foam. This foam material holds promise for developing multifunctional photo-thermal systems for solar-driven water purification.

DESALINATION (2024)