期刊
DALTON TRANSACTIONS
卷 43, 期 42, 页码 15785-15790出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt01808g
关键词
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资金
- 973 Program [2012CB821701]
- NSFC [21273007, 21350110212, 91222201]
- Program for New Century Excellent Talents in University [NCET-13-0615]
- NSF of Guangdong [S2013030013474]
- Fundamental Research Funds for the Central Universities [14lgpy05]
A tetraphenylethylene-based phosphine, 1,1,2,2-tetrakis((4-diphenyiphosphino)phenypethylene (TPE-P4), was synthesized and showed novel aggregation-induced and mechano-responsive emission. A mixture of TPE-P4 and Ag+ could fix atmospheric CO2 in situ as carbonate ions in neutral solution to yield a rare 3D metal-organic framework with zeolite-like SOD topology, [Ag-2(TPE-P-4)CO3](x), superset of nH(2)O (Ag-TPE-P4). Ag-TPE-P4 showed turn-on luminescence of TPE-P4, emitting bright bluish green light in the solid state.
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