期刊
DALTON TRANSACTIONS
卷 42, 期 14, 页码 4903-4907出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt33027c
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Halide-templated tert-butylethynide Ag-14 complexes undergo reversible exchange with copper(I) to afford a series of mixed Ag14-nCun (n = 1-6) species. Up to six silver atoms in the cluster can be replaced with copper(I) to give a core structure featuring a Ag8Cu6 rhombic dodecahedron. These clusters are useful models for investigating the chemical reactivity and photoluminescence of heterometallic d(10)-d(10) systems.
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