期刊
DALTON TRANSACTIONS
卷 42, 期 45, 页码 15826-15834出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt51689j
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [22108508, 22685005]
- Grants-in-Aid for Scientific Research [23550046, 22685005] Funding Source: KAKEN
Azobenzenes are constituents of the commonly and widely used azo dyes. Many dyes, except for the azo dyes, have been utilized for fluorescent materials. However, there are only a few fluorescent azobenzene derivatives and their fluorescence efficiencies are quite low. The current perspective provides an account of the fluorescent azobenzenes and aromatic aldimines featuring an N-B interaction. Incorporation of the intramolecular N-B interaction by using the bis(pentafluorophenyl) boryl group makes the azobenzenes and aromatic aldimines fluorescent with a range of colours. Some of them fluoresce with extraordinarily high fluorescence quantum yields. Their synthesis, structures, fluorescence properties, and applications are discussed.
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