期刊
DALTON TRANSACTIONS
卷 42, 期 11, 页码 3767-3770出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt32317f
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资金
- Swedish Nuclear Fuel and Waste Management Company (SKB)
- European Union project ACSEPT [211267]
- Swedish Research Council
- Knut och Alice Wallenbergs Stiftelse
The structure of the [Eu(CyMe4-BTBP)(2)(NO3)(n)]((3-n)+) complex in 1-octanol solution and solid state has been determined by EXAFS and X-ray crystallography. The crystal structure shows that 1-octanol binds only to the europium(III)-coordinated BTBP molecules through weak van der Waals forces, making it the first indication of the role of the extraction solvent.
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