New catalysts with unsymmetrical N-heterocyclic carbene ligands

Asymmetric catalysts for stereocontrolled olefin metathesis reactions

(2012) Steffen Kress et al.   CHEMICAL SOCIETY REVIEWS

Z-Selectivity in Olefin Metathesis with Chelated Ru Catalysts: Computational Studies of Mechanism and Selectivity

(2012) Peng Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site- and Enantioselective Formation of Allene-Bearing Tertiary or Quaternary Carbon Stereogenic Centers through NHC–Cu-Catalyzed Allylic Substitution

(2012) Byunghyuck Jung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient One-Pot Synthesis of Unsymmetrical Gold(I) N-Heterocyclic Carbene Complexes and Their Use as Catalysts

(2012) A. Stephen K. Hashmi et al.   ORGANOMETALLICS

Six-Membered, Chiral NHCs Derived from Camphor: Structure–Reactivity Relationship in Asymmetric Oxindole Synthesis

(2012) Markus J. Spallek et al.   ORGANOMETALLICS

Cyclometalated N-Heterocyclic Carbene-Platinum Catalysts for the Enantioselective Cycloisomerization of Nitrogen-Tethered 1,6-Enynes

(2011) Hélène Jullien et al.   ADVANCED SYNTHESIS & CATALYSIS

A Novel Ligand for the Enantioselective Ruthenium-Catalyzed Olefin Metathesis

(2011) Axel Kannenberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed 1,4-Addition of Organoboronates to Alkylidene Cyanoacetates: Mechanistic Insight and Application to Asymmetric Catalysis

(2011) Keishi Takatsu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NHC-Cu-Catalyzed Enantioselective Hydroboration of Acyclic and Exocyclic 1,1-Disubstituted Aryl Alkenes

(2011) Rosa Corberán et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Aryl- and Alkenylboronates

(2011) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rigid pyridyl substituted NHC ligands, their Pd(0) complexes and their application in selective transfer semihydrogenation of alkynes

(2011) Stefan Warsink et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Abnormal N-heterocyclic carbene palladium complex: living catalyst for activation of aryl chlorides in Suzuki–Miyaura cross coupling

(2011) Samaresh Chandra Sau et al.   CHEMICAL COMMUNICATIONS

Organic Synthesis Involving Iridium-Catalyzed Oxidation

(2011) Takeyuki Suzuki   CHEMICAL REVIEWS

N-Heterocyclic carbene (NHC) ligands and palladium in homogeneous cross-coupling catalysis: a perfect union

(2011) George C. Fortman et al.   CHEMICAL SOCIETY REVIEWS

Stability and Electronic Properties of Imidazole-Based Mesoionic Carbenes

(2011) Gaël Ung et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium and iridium complexes of an asymmetric bicyclic NHC bearing secondary pyridyl donors

(2011) Paul D. Newman et al.   DALTON TRANSACTIONS

Copper(I) Complexes of Normal and Abnormal Carbenes and Their Use as Catalysts for the Huisgen [3+2] Cycloaddition between Azides and Alkynes

(2011) Stephan Hohloch et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Short Synthesis of Chiral 4-Substituted (S)-Imidazolinium Salts Bearing Sulfonates and Their Use in γ-Selective Reactions of Allylic Halides with Grignard Reagents

(2011) Christopher M. Latham et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Transfer Hydrogenation of Aromatic Ketones Using Rhodium Complexes of Chiral N-Heterocyclic Carbenes Derived from (S)-Pyroglutamic Acid

(2011) Audrey Aupoix et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Platinum complexes with pyrimidine-functionalized N-heterocyclic carbene ligands – Synthesis and solid state structures

(2011) Dirk Meyer et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Improved Ruthenium Catalysts for Z-Selective Olefin Metathesis

(2011) Benjamin K. Keitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chelated Ruthenium Catalysts forZ-Selective Olefin Metathesis

(2011) Koji Endo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Ruthenium Metathesis Catalysts for Ethenolysis

(2011) Renee M. Thomas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Homoallylic Amines through Reactions of (Pinacolato)allylborons with Aryl-, Heteroaryl-, Alkyl-, or Alkene-Substituted Aldimines Catalyzed by ChiralC1-Symmetric NHC−Cu Complexes

(2011) Erika M. Vieira et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoconvergent Synthesis of Chiral Allylboronates from anE/ZMixture of Allylic Aryl Ethers Using a 6-NHC−Cu(I) Catalyst

(2011) Jin Kyoon Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I) 1,2,3-Triazol-5-ylidene Complexes as Efficient Catalysts for Click Reactions of Azides with Alkynes

(2011) Tatsuhito Nakamura et al.   ORGANIC LETTERS

From Isonitriles to Carbenes: Synthesis of New NAC− and NHC−Palladium(II) Compounds and Their Catalytic Activity

(2011) A. Stephen K. Hashmi et al.   ORGANOMETALLICS

Ligand design for dual enantioselective control in Cu-catalyzed asymmetric conjugate addition of R2Zn to cyclic enone

(2011) Misato Yoshimura et al.   TETRAHEDRON

Carbenes Made Easy: Formation of Unsymmetrically Substituted N-Heterocyclic Carbene Complexes of Palladium(II), Platinum(II) and Gold(I) from Coordinated Isonitriles and their Catalytic Activity

(2010) A. Stephen K. Hashmi et al.   ADVANCED SYNTHESIS & CATALYSIS

Quaternary Carbon Stereogenic Centers through Copper-Catalyzed Enantioselective Allylic Substitutions with Readily Accessible Aryl- or Heteroaryllithium Reagents and Aluminum Chlorides

(2010) Fang Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Free Asymmetric Allylic Alkylation with Grignard Reagents

(2010) Olivier Jackowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Active Chiral Ruthenium-Based Metathesis Catalysts through a Monosubstitution in the N-Heterocyclic Carbene

(2010) Sascha Tiede et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed asymmetric addition of arylboronates to isatins: a catalytic cycle involving alkoxocopper intermediates

(2010) Ryo Shintani et al.   CHEMICAL COMMUNICATIONS

Triazole-Functionalized N-Heterocyclic Carbene Complexes of Palladium and Platinum and Efficient Aqueous Suzuki-Miyaura Coupling Reaction

(2010) Shaojin Gu et al.   Chemistry-An Asian Journal

N-Heterocyclic carbene–rhodium complexes as catalysts for hydroformylation and related reactions

(2010) W. Gil et al.   COORDINATION CHEMISTRY REVIEWS

Bulky Picolyl Substituted NHC Ligands and Their Pd0 Complexes

(2010) Stefan Warsink et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Reversal of Stereoselectivity in the Cu-Catalyzed Conjugate Addition Reaction of Dialkylzinc to Cyclic Enone in the Presence of a Chiral Azolium Compound

(2010) Naoatsu Shibata et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Synthesis of Allylboronates Bearing a Tertiary or Quaternary B-Substituted Stereogenic Carbon by NHC-Cu-Catalyzed Substitution Reactions

(2010) Aikomari Guzman-Martinez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Quaternary Carbon Stereogenic Centers through Enantioselective Cu-Catalyzed Allylic Substitutions with Vinylaluminum Reagents

(2010) Fang Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphine-free chiral metal catalysts for highly effective asymmetric catalytic hydrogenation

(2010) Yan-Mei He et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Desymmetrizations Forming Tetrasubstituted Olefins Using Enantioselective Olefin Metathesis

(2010) Brice Stenne et al.   ORGANIC LETTERS

A Chiral 6-MemberedN-Heterocyclic Carbene Copper(I) Complex That Induces High Stereoselectivity

(2010) Jin Kyoon Park et al.   ORGANIC LETTERS

Modular Synthesis of Bidentate Triazolyl-Functionalized N-Heterocyclic Carbenes and Their Palladium Complexes

(2010) Stefan Warsink et al.   ORGANOMETALLICS

NHC Ligands with a Secondary Pyrimidyl Donor for Electron-Rich Palladium(0) Complexes

(2010) Stefan Warsink et al.   ORGANOMETALLICS

Dinuclear and Tetranuclear Palladium(II) Complexes of a Thiolato-Functionalized, Benzannulated N-Heterocyclic Carbene Ligand and Their Activities toward Suzuki−Miyaura Coupling

(2010) Dan Yuan et al.   ORGANOMETALLICS

Improved Chiral Olefin Metathesis Catalysts: Increasing the Thermal and Solution StabilityviaModification of aC1-Symmetrical N-Heterocyclic Carbene Ligand

(2009) Jolaine Savoie et al.   ADVANCED SYNTHESIS & CATALYSIS

Stereoisomerically Pure Trisubstituted Vinylaluminum Reagents and their Utility in Copper-Catalyzed Enantioselective Synthesis of 1,4-Dienes Containing Z or E Alkenes

(2009) Katsuhiro Akiyama et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(0) pre-catalysts with heteroditopic NHC-amine ligands by transmetallation from their silver(I) complexes

(2009) Stefan Warsink et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Ruthenium-Based Olefin Metathesis Catalysts BearingN-Heterocyclic Carbene Ligands

(2009) Cezary Samojłowicz et al.   CHEMICAL REVIEWS

Complexes with Poly(N-heterocyclic carbene) Ligands: Structural Features and Catalytic Applications

(2009) Macarena Poyatos et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

Ruthenium-Based Heterocyclic Carbene-Coordinated Olefin Metathesis Catalysts†

(2009) Georgios C. Vougioukalakis et al.   CHEMICAL REVIEWS

On the Electronic Impact of Abnormal C4-Bonding in N-Heterocyclic Carbene Complexes

(2009) Marion Heckenroth et al.   CHEMISTRY-A EUROPEAN JOURNAL

Expanded ring and functionalised expanded ring N-heterocyclic carbenes as ligands in catalysis

(2009) Abeer Binobaid et al.   DALTON TRANSACTIONS

Design of Chiral Hydroxyalkyl- and Hydroxyarylazolinium Salts as New Chelating Diaminocarbene Ligand Precursors Devoted to Asymmetric Copper-Catalyzed Conjugate Addition

(2009) Diane Rix et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Fluoride-Free Hiyama and Copper- and Amine-Free Sonogashira Coupling in Air in a Mixed Aqueous Medium by a Series of PEPPSI-Themed Precatalysts

(2009) Chandrakanta Dash et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Monodentate Non-C2-symmetric ChiralN-Heterocyclic Carbene Complexes for Enantioselective Synthesis. Cu-Catalyzed Conjugate Additions of Aryl- and Alkenylsilylfluorides to Cyclic Enones

(2009) Kang-sang Lee et al.   JOURNAL OF ORGANIC CHEMISTRY

Six- and seven-membered ring carbenes: Rational synthesis of amidinium salts, generation of carbenes, synthesis of Ag(I) and Cu(I) complexes

(2009) Eugene L. Kolychev et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Stereogenic-at-Metal Zn- and Al-Based N-Heterocyclic Carbene (NHC) Complexes as Bifunctional Catalysts in Cu-Free Enantioselective Allylic Alkylations

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Vicinal Diboronates in High Enantiomeric Purity through Tandem Site-Selective NHC−Cu-Catalyzed Boron−Copper Additions to Terminal Alkynes

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Platinum(II) Catalysts for Highly Enantioselective 1,6-Enyne Cycloisomerizations. Synthetic, Structural, and Catalytic Studies

(2009) Delphine Brissy et al.   ORGANIC LETTERS

N-Heterocyclic Carbene-Based Nickel Complexes: Synthesis and Catalysis in Cross-Couplings of Aryl Chlorides with ArMX (M = Mg or Zn)

(2009) Cheng Zhang et al.   ORGANOMETALLICS

Palladium Complexes with Pyrimidine-Functionalized N-Heterocyclic Carbene Ligands: Synthesis, Structure and Catalytic Activity

(2009) Dirk Meyer et al.   ORGANOMETALLICS

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Donor-Functionalised N-Heterocyclic Carbene Complexes of Group 9 and 10 Metals in Catalysis: Trends and Directions

(2008) Adrien T. Normand et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

N-Heterocyclic Carbene Complexes of Rh:  Reaction with Dioxygen without Oxidation

(2008) Jeremy M. Praetorius et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Olefin Metathesis Catalyst: Stabilization Effect of Backbone Substitutions of N-Heterocyclic Carbene

(2008) Cheol K. Chung et al.   ORGANIC LETTERS

Highlycis-Selective Cyclopropanations with Ethyl Diazoacetate Using a Novel Rh(I) Catalyst with a Chelating N-Heterocyclic Iminocarbene Ligand

(2008) Marianne Lenes Rosenberg et al.   ORGANIC LETTERS

Platinum(II) Complexes Featuring Chiral Diphosphines and N-Heterocyclic Carbene Ligands: Synthesis and Evaluation as Cycloisomerization Catalysts

(2008) Delphine Brissy et al.   ORGANOMETALLICS