期刊
DALTON TRANSACTIONS
卷 41, 期 30, 页码 9073-9082出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30195d
关键词
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资金
- Fonds der Chemischen Industrie
- European Research Council (ERC) [277963]
The synthesis of several electron poor allenes bearing electron withdrawing substituents is described and their use as Lewis acids in the field of frustrated Lewis pair (FLP) chemistry reported. At room temperature the combination of N-heterocyclic carbenes (NHC) with the allenes under study invariably afforded the corresponding Lewis adducts; however, at -78 degrees C this reaction is in most of the cases inhibited and kinetically induced organic FLPs are formed. Under these conditions the activation of S-S bonds in disulfides has been achieved in excellent yields.
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