Mixed-valence [FeIFeII] hydrogenase active site model complexes stabilized by a bidentate carborane bis-phosphine ligand

The role of the bridging ligand in photocatalytic supramolecular assemblies for the reduction of protons and carbon dioxide

(2012) Martin Schulz et al.   COORDINATION CHEMISTRY REVIEWS

A Model of the [FeFe] Hydrogenase Active Site with a Biologically Relevant Azadithiolate Bridge: A Spectroscopic and Theoretical Investigation

(2011) Özlen F. Erdem et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Splitting Water with Cobalt

(2011) Vincent Artero et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photo-hydrogen-evolving molecular devices driving visible-light-induced water reduction into molecular hydrogen: structure–activity relationship and reaction mechanism

(2011) Hironobu Ozawa et al.   CHEMICAL COMMUNICATIONS

Isolation, observation, and computational modeling of proposed intermediates in catalyticprotonreductions with the hydrogenase mimic Fe2(CO)6S2C6H4

(2011) Robert J. Wright et al.   DALTON TRANSACTIONS

Spectroscopically characterized intermediates of catalytic H2 formation by [FeFe] hydrogenase models

(2011) Stefanie Tschierlei et al.   Energy & Environmental Science

Comparing the Reactivity of Benzenedithiolate- versus Alkyldithiolate-Bridged Fe2(CO)6 Complexes with Competing Ligands

(2011) Daniel Streich et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A tunable general purpose Q-band resonator for CW and pulse EPR/ENDOR experiments with large sample access and optical excitation

(2011) Edward Reijerse et al.   JOURNAL OF MAGNETIC RESONANCE

Paramagnetic Bridging Hydrides of Relevance to Catalytic Hydrogen Evolution at Metallosulfur Centers

(2011) Aušra Jablonskytė et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ironing Out Hydrogen Storage

(2011) S. Ott   SCIENCE

Efficient Dehydrogenation of Formic Acid Using an Iron Catalyst

(2011) A. Boddien et al.   SCIENCE

A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s-1 for H2 Production

(2011) M. L. Helm et al.   SCIENCE

Catalytic Hydrogen Evolution from Mononuclear Iron(II) Carbonyl Complexes as Minimal Functional Models of the [FeFe] Hydrogenase Active Site

(2010) Sandeep Kaur-Ghumaan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Directing protonation in [FeFe] hydrogenase active site models by modifications in their second coordination sphere

(2010) Salah Ezzaher et al.   CHEMICAL COMMUNICATIONS

Diiron species containing a cyclic PPh2NPh2diphosphine related to the [FeFe]H2ases active site

(2010) Sondès Lounissi et al.   CHEMICAL COMMUNICATIONS

Solar Energy Supply and Storage for the Legacy and Nonlegacy Worlds

(2010) Timothy R. Cook et al.   CHEMICAL REVIEWS

Electrocatalytic dihydrogen evolution mechanism of [Fe2(CO)4(κ2-Ph2PCH2CH2PPh2)(μ-S(CH2)3S)] and related models of the [FeFe]-hydrogenases active site: a DFT investigation

(2010) Claudio Greco et al.   DALTON TRANSACTIONS

Models for the Active Site in [FeFe] Hydrogenase with Iron-Bound Ligands Derived from Bis-, Tris-, and Tetrakis(mercaptomethyl)silanes

(2010) Ulf-Peter Apfel et al.   INORGANIC CHEMISTRY

Non-innocent bma ligand in a dissymetrically disubstituted diiron dithiolate related to the active site of the [FeFe] hydrogenases

(2010) Youtao Si et al.   JOURNAL OF INORGANIC BIOCHEMISTRY

Role of the Azadithiolate Cofactor in Models for [FeFe]-Hydrogenase: Novel Structures and Catalytic Implications

(2010) Matthew T. Olsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Biomimetic and Microbial Approaches to Solar Fuel Generation

(2009) Ann Magnuson et al.   ACCOUNTS OF CHEMICAL RESEARCH

Boron Atoms as Spin Carriers in Two- and Three-Dimensional Systems

(2009) Wolfgang Kaim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Light-Driven Hydrogen Generation: Efficient Iron-Based Water Reduction Catalysts

(2009) Felix Gärtner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structural and Functional Analogues of the Active Sites of the [Fe]-, [NiFe]-, and [FeFe]-Hydrogenases†

(2009) Cédric Tard et al.   CHEMICAL REVIEWS

Isomerization of the hydride complexes [HFe2(SR)2(PR3)x(CO)6−x]+(x = 2, 3, 4) relevant to the active site models for the [FeFe]-hydrogenases

(2009) Bryan E. Barton et al.   DALTON TRANSACTIONS

Hydrogen Activation by Biomimetic Diiron Dithiolates

(2009) Matthew T. Olsen et al.   INORGANIC CHEMISTRY

Preparation, Facile Deprotonation, and Rapid H/D Exchange of the μ-Hydride Diiron Model Complexes of the [FeFe]-Hydrogenase Containing a Pendant Amine in a Chelating Diphosphine Ligand

(2009) Ning Wang et al.   INORGANIC CHEMISTRY

Review of electrochemical studies of complexes containing the Fe2S2 core characteristic of [FeFe]-hydrogenases including catalysis by these complexes of the reduction of acids to form dihydrogen

(2009) Greg A.N. Felton et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Structure–function relationships of anaerobic gas-processing metalloenzymes

(2009) Juan C. Fontecilla-Camps et al.   NATURE

14N HYSCORE investigation of the H-cluster of [FeFe] hydrogenase: evidence for a nitrogen in the dithiol bridge

(2009) Alexey Silakov et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Synthetic Support of De Novo Design: Sterically Bulky [FeFe]-Hydrogenase Models

(2008) Michael L. Singleton et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A proton–hydride diiron complex with a base-containing diphosphine ligand relevant to the [FeFe]-hydrogenase active site

(2008) Ning Wang et al.   CHEMICAL COMMUNICATIONS

Small molecule mimics of hydrogenases: hydrides and redox

(2008) Frédéric Gloaguen et al.   CHEMICAL SOCIETY REVIEWS

Models of the iron-only hydrogenase: Synthesis and protonation of bridge and chelate complexes [Fe2(CO)4{Ph2P(CH2)nPPh2}(μ-pdt)] (n=2–4) – evidence for a terminal hydride intermediate

(2008) Fatima I. Adam et al.   COMPTES RENDUS CHIMIE

Diiron chelate complexes relevant to the active site of the iron-only hydrogenase

(2008) Salah Ezzaher et al.   COMPTES RENDUS CHIMIE

Tuning the electronic properties of Fe2(μ-arenedithiolate)(CO)6−n(PMe3)n (n=0, 2) complexes related to the [Fe–Fe]-hydrogenase active site

(2008) Lennart Schwartz et al.   COMPTES RENDUS CHIMIE

Electron and proton transfers at diiron dithiolate sites relevant to the catalysis of proton reduction by the [FeFe]-hydrogenases

(2008) Jean-François Capon et al.   COORDINATION CHEMISTRY REVIEWS

Influence of an electron-deficient bridging o-carborane on the electronic properties of an [FeFe] hydrogenase active site model

(2008) Lennart Schwartz et al.   DALTON TRANSACTIONS

Solar water-splitting into H2 and O2: design principles of photosystem II and hydrogenases

(2008) Wolfgang Lubitz et al.   Energy & Environmental Science

CO-Migration in the Ligand Substitution Process of the Chelating Diphosphite Diiron Complex (μ-pdt)[Fe(CO)3][Fe(CO){(EtO)2PN(Me)P(OEt)2}]

(2008) Ning Wang et al.   INORGANIC CHEMISTRY

Redox and Structural Properties of Mixed-Valence Models for the Active Site of the [FeFe]-Hydrogenase: Progress and Challenges

(2008) Aaron K. Justice et al.   INORGANIC CHEMISTRY

Influence of a Pendant Amine in the Second Coordination Sphere on Proton Transfer at a Dissymmetrically Disubstituted Diiron System Related to the [2Fe]HSubsite of [FeFe]H2ase

(2008) Salah Ezzaher et al.   INORGANIC CHEMISTRY

The Crystal Structure of [Fe]-Hydrogenase Reveals the Geometry of the Active Site

(2008) S. Shima et al.   SCIENCE

Photochemical Conversion of Solar Energy

(2007) Vincenzo Balzani et al.   ChemSusChem