期刊
DALTON TRANSACTIONS
卷 41, 期 14, 页码 3899-3901出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt12265k
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资金
- DFG [SPP 1362]
- Alexander von Humboldt foundation
Mesoporous amino-functionalized metal-organic framework thin films with the UiO-68 topology were grown in a highly oriented fashion on two different self-assembled monolayers on gold. The oriented MOF films were covalently modified with the fluorescent dye Rhodamine B inside the pore system, as demonstrated with size-selective fluorescence quenching studies. Our study suggests that mesoporous metal-organic frameworks are promising hosts for the covalent attachment of numerous functional moieties in a molecularly designed crystalline environment.
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