期刊
DALTON TRANSACTIONS
卷 41, 期 20, 页码 6277-6282出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30120b
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资金
- Department of Energy (BES) [DE-FG02-08ER46519]
- National Science Foundation [CHE-0952370, DGE-1144086]
- U.S. Department of Energy (DOE) [DE-FG02-08ER46519] Funding Source: U.S. Department of Energy (DOE)
A series of highly porous University of Michigan Crystalline Material (UMCM-1) type Zn-based metal-organic frameworks (MOFs) were synthesized from mono-and bi-functionalized benzenedicarboxylate (BDC) ligands. In total, 16 new functionalized UMCM-1 derivatives were obtained by a combination of pre- and postsynthetic functionalization. Through postsynthetic modification (PSM), amino-halo bifunctional MOFs were converted into amide-halo materials via solid-state acylation reactions. A series of bifunctional MOFs containing Cl, Br, and I groups revealed that PSM conversion is not affected by the size of the halide, only by the steric bulk of the reagent used in these solid-state organic transformations.
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