期刊
DALTON TRANSACTIONS
卷 41, 期 11, 页码 3130-3133出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt12355j
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资金
- CNRS
We have structurally and spectroscopically investigated a rare example of a mononuclear aliphatic dithiolate Cu-II complex characterized by a reversible Cu-II/Cu-I redox couple. By DFT, we have shown that this system has a lower reorganization energy than its previously described bis(mu-thiolato) dicopper parent complex, which reversibly cycles between the (CuCu1.5)-Cu-1.5 and (CuCuI)-Cu-I redox states.
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